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Layered two-dimensional (2D) semiconductors such as molybdenum disulfide (MoS2) have recently attracted remarkable attention because of their unique physical properties. Here, we use photoluminescence (PL) and Raman spectroscopy to study…

Charged excitons called trions play an important role in the fundamental valley dynamics in the newly emerging 2D semiconductor materials. We used ultrafast pump- probe spectroscopy to study the valley trion dynamics in a MoSe$_2$ monolayer…

Mesoscale and Nanoscale Physics · Physics 2016-12-13 Feng Gao , Yongji Gong , Michael Titze , Raybel Almeida , Pulickel M. Ajayan , Hebin Li

We report charged exciton (trion) formation dynamics in doped monolayer transition metal dichalcogenides (TMDs), specifically molybdenum diselenide (MoSe2), using resonant two-color pump-probe spectroscopy. When resonantly pumping the…

Monolayer transition metal dichalcogenides (TMDs) have the potential to unlock novel photonic and chemical technologies if their optoelectronic properties can be understood and controlled. Yet, recent work has offered contradictory…

Monolayer molybdenum disulfide (MoS$_2$) has emerged as an excellent 2D model system because of its two inequivalent, direct-gap valleys that lead to exotic bound and excited states. Here we focus on one such bound state, the negatively…

Materials Science · Physics 2016-06-01 Jason W. Christopher , Bennett B. Goldberg , Anna K. Swan

Trions, quasi-particles consisting of two electrons combined with one hole or of two holes with one electron, have recently been observed in transition metal dichalcogenides (TMDCs) and drawn increasing attention due to potential…

We report magneto-photoluminescence spectroscopy of gated MoS$_2$ monolayers in high magnetic fields to 28 T. At B = 0T and electron density $n_s\sim 10^{12}cm^-2$, we observe three trion resonances that cannot be explained within a…

The emerging field of valleytronics aims to exploit the valley pseudospin of electrons residing near Bloch band extrema as an information carrier. Recent experiments demonstrating optical generation and manipulation of exciton valley…

Mesoscale and Nanoscale Physics · Physics 2017-05-24 Kai Hao , Lixiang Xu , Fengcheng Wu , Philipp Nagler , Kha Tran , Xin Ma , Christian Schüller , Tobias Korn , Allan H. MacDonald , Galan Moody , Xiaoqin Li

Two-dimensional semiconductors exhibit pronounced many-body effects and intense optical responses due to strong coulombic interactions. Consequently, subtle differences in photoexcitation conditions can strongly influence how the material…

We propose a double channel mechanism for the formation of charged excitons (trions); they are formed through bi- and tri-molecular processes. This directly implies that both negatively and positively charged excitons coexist in a quantum…

Materials Science · Physics 2009-09-29 M. T. Portella-Oberli , J. Berney , L. Kappei , F. Morier-Genoud , J. Szczytko , B. Deveaud

Developments in optoelectronics and spin-optronics based on transition metal dichalcogenide monolayers (MLs) need materials with efficient optical emission and well-defined transition energies. In as-exfoliated MoS2 MLs the…

Two-dimensional materials such as transitional metal dichalcogenides exhibit unique optical and electrical properties. Here we report on the varying optical properties of CVD grown MoS2 monolayer flakes with different shapes. In particular,…

Applied Physics · Physics 2020-03-18 Siwei Luo , Conor P. Cullen , Gencai Guo , Jianxin Zhong , Georg S. Duesberg

Optical excitation typically enhances electrical conduction and low-frequency radiation absorption in semiconductors. We have, however, observed a pronounced transient decrease of conductivity in doped monolayer molybdenum disulfide (MoS2),…

Mesoscale and Nanoscale Physics · Physics 2014-10-22 C. H. Lui , A. J. Frenzel , D. V. Pilon , Y. -H. Lee , X. Ling , G. M. Akselrod , J. Kong , N. Gedik

Charge doping in transition metal dichalcogenide is currently a subject of high importance for future electronic and optoelectronic applications. Here we demonstrate chemical doping in CVD grown monolayer (1L) of WS2 by a few commonly used…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Anand P. S. Gaur , Adriana M. Rivera , Saroj P. Dash , Sandwip Dey , Ram S. Katiyar , Satyaprakash Sahoo

Transition metal dichalcogenide (TMD) monolayers are two-dimensional semiconductors with two valleys in their band structure that can be selectively addressed using circularly polarized light. Their photoluminescence spectrum is…

Mesoscale and Nanoscale Physics · Physics 2020-10-26 Joris J. Carmiggelt , Michael Borst , Toeno van der Sar

We measure the optical absorption spectra and optical conductivities of excitons and trions in monolayers of metal dichalcogenide MoS$_{2}$ and compare the results with theoretical models. Our results show that the Wannier-Mott model for…

Mesoscale and Nanoscale Physics · Physics 2014-06-04 Changjian Zhang , Haining Wang , Weimin Chan , Christina Manolatou , Farhan Rana

Unconventional emissions from exciton and trion in monolayer WS2 are studied by photoexcitation. Excited by 532nm laser beam, the carrier species in the monolayer WS2 are affected by the excess electrons escaping from photoionization of…

Mesoscale and Nanoscale Physics · Physics 2016-08-08 Ke Wei , Yu Liu , Hang Yang , Xiangai Cheng , Tian Jiang

Photoluminescence spectra, shows that monolayer Transition-metal dichalcogenides (MLTMDCs), possess charged exciton binding energies, conspicuously similar to the energy of optical phonons. This enigmatic coincidence has offered…

Mesoscale and Nanoscale Physics · Physics 2020-09-16 Sabrine Ayari , Sihem Jaziri , Robson Ferreira , Gerald Bastard

Two-dimensional (2D) atomic crystals, such as graphene and transition-metal dichalcogenides, have emerged as a new class of materials with remarkable physical properties. In contrast to graphene, monolayer MoS2 is a non-centrosymmetric…

Materials Science · Physics 2015-06-11 Kin Fai Mak , Keliang He , Changgu Lee , Gwan Hyoung Lee , James Hone , Tony F. Heinz , Jie Shan

We present experimental and theoretical results on the high-quality single-layer MoS$_{2}$ which reveal the fine structure of charged excitons, i.e., trions. In the emission spectra we resolve and identify two trion peaks, T$_{1}$ and…

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