Related papers: Energy eigenvalues of quadratic, pure quartic and …
A novel general approximation scheme (NGAS) proposed earlier (ref.2-3) is applied to the problem of the quartic anharmonic (QAHO) and the double-well-oscillator (QDWO) in quantum theory by choosing the infinite square-well-potential in one…
Quartic eigenvalue problem $(\lambda^4 A + \lambda^3 B + \lambda^2C + \lambda D + E)x = \mathbf{0}$ naturally arises e.g. when solving the Orr-Sommerfeld equation in the analysis of the stability of the {Poiseuille} flow, in theoretical…
We discuss spectral properties of the family of quartic oscillators $\mathfrak h_{\mathcal M}(\alpha) =-\frac{d^2}{dt^2} +\Big(\frac{1}{2} t^{2} -\alpha\Big)^2$ on the real line, where $\alpha\in \mathbb{R}$ is a parameter. This operator…
We investigate the use of different variational principles in quantum Monte Carlo, namely energy and variance minimization, prompted by the interest in the robust and accurate estimate of electronic excited states. For two prototypical,…
The variational quantum eigensolver (or VQE) uses the variational principle to compute the ground state energy of a Hamiltonian, a problem that is central to quantum chemistry and condensed matter physics. Conventional computing methods are…
It is a fundamental problem to characterize the nonequilibrium processes. For a slowly moving one-dimensional potential, we explore the quasi adiabatic dynamics of the initial energy eigenstates for a confined quantum system interacting…
The hyperspherical harmonics (HH) provide a complete basis for the expansion of atomic wave functions, but even for two particles the number of harmonics for a given order is not trivial and, as the number of electrons increases, this…
In this contribution to Peter Suranyi Festschrift, we study the Halliday-Suranyi perturbation method for calculating the energy eigenvalues of the quartic anharmonic oscillator.
Quantum Monte Carlo (QMC) methods such as variational Monte Carlo and fixed node diffusion Monte Carlo depend heavily on the quality of the trial wave function. Although Slater-Jastrow wave functions are the most commonly used variational…
The iterative quantum phase estimation algorithm, applied to calculating the ground state energies of quantum chemical systems, is theoretically appealing in its wide scope of being able to handle both weakly and strongly correlated…
Two different methods are used to study the existence and stability of the (1+1)-dimensional $\Phi^4$ oscillon. The variational technique approximates it by a periodic function with a set of adiabatically changing parameters. An alternative…
The new perturbation theory for the problem of nonstationary anharmonic oscillator with polynomial nonstationary perturbation is proposed. As a zero order approximation the exact wave function of harmonic oscillator with variable frequency…
A new variational perturbation theory is developed based on the $q-$deformed oscillator. It is shown that the new variational perturbation method provides 200 or 10 times better accuracy for the ground state energy of anharmonic oscillator…
The variational procedure to construct compact and accurate wave functions for three-electron atoms and ions is developed. The procedure is based on the use of six-dimensional gaussoids written in the relative four-body coordinates $r_{12},…
The non-relativistic energy levels of ortho-positronium are calculated in the quadrupole and octupole approximations for the interaction potential. For this purpose, the RST eigenvalue problem of angular momentum is illustratively solved…
The calculation of excited state energies of electronic structure Hamiltonians has many important applications, such as the calculation of optical spectra and reaction rates. While low-depth quantum algorithms, such as the variational…
The energy gap between the first excited state and the ground state is calculated for the quantized anharmonic oscillator in the framework of the functional renormalization group method. The compactly supported smooth regulator is used…
This paper proposes a very simple perturbative technique to calculate the low-lying eigenvalues and eigenstates of a parity-symmetric quantum-mechanical potential. The technique is to solve the time-independent Schroedinger eigenvalue…
Recent developments in selected configuration interaction methods have led to increased interest in using multi-Slater trial wave functions in various quantum Monte Carlo (QMC) methods. Here we present an algorithm for calculating the local…
Atomic properties of the 24 low-lying ns, np, nd, nf, and ng states in Th IV ion are calculated using the high-precision relativistic all-order method where all single, double, and partial triple excitations of the Dirac-Fock wave functions…