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Sum-frequency generation (SFG) is a powerful second-order nonlinear spectroscopic technique that provides detailed insights into molecular structures and absolute orientations at surfaces and interfaces. However, conventional SFG based on…

Sum-frequency generation (SFG) is a second-order nonlinear process widely used for characterizing surfaces and interfaces with monolayer sensitivity. Recently, optical field enhancement in plasmonic nanocavities has enabled SFG with…

Much work over the last 25 years has demonstrated that the interface-specific, alloptical technique, vibrational sum frequency generation (v-SFG) spectroscopy, is often uniquely capable of characterizing the structure and dynamics of…

Optics · Physics 2018-11-14 Martin Thämer , R. Kramer Campen , Martin Wolf

We propose a computational framework to extract non-linear response functions from real-time simulations in the presence of more than one external field. We apply this approach to the calculation of sum frequency generation (SFG) and…

Materials Science · Physics 2025-11-19 Mike N. Pionteck , Myrta Grüning , Simone Sanna , Claudio Attaccalite

Moving the detection wavelength in vibrational sum-frequency generation (VSFG) spectroscopy to the near-infrared (> 700 nm) can potentially enable the study of molecular interfaces absorbing in the visible and give access to buried…

Optics · Physics 2024-05-10 Zsuzsanna Heiner , Valentin Petrov , Mark Mero

Sum-frequency generation (SFG) spectroscopy provides a versatile method for the investigation of non-centrosymmetric media and interfaces. Here, using tunable picosecond infrared (IR) pulses from a free-electron laser, the nonlinear optical…

Materials Science · Physics 2023-08-01 Riko Kiessling , Martin Wolf , Alexander Paarmann

Sum-frequency generation (SFG) allows for coherent upconversion of an electromagnetic signal and has applications in mid-infrared vibrational spectroscopy of molecules. Recent experimental and theoretical studies have shown that plasmonic…

Plasmonic nanostructures that support surface plasmon (SP) resonance potentially provide a route for the development of nanoengineered nonlinear optical devices. In this work, second-order nonlinear light scattering, specifically…

Computational Physics · Physics 2016-12-20 Xiaoyan Y. Z. Xiong , Li Jun Jiang , Wei E. I. Sha , Yat Hei Lo , Weng Cho Chew

Sum frequency generation (SFG) has multiple applications, from optical sources to imaging, where efficient conversion requires either long interaction distances or large field concentrations in a quadratic nonlinear material. Metasurfaces…

Optics · Physics 2024-08-22 Neuton Li , Jihua Zhang , Dragomir N. Neshev , Andrey A. Sukhorukov

Vibrational sum frequency generation (SFG) spectroscopy is a powerful technique for investigating molecular structures, orientations, and dynamics at surfaces. However, its spatial resolution is fundamentally restricted to the micrometer…

Vibrational sum frequency generation (SFG) is a nonlinear spectroscopic technique widely used to study the molecular structure and dynamics of surface systems. However, the spatial resolution achieved by far-field observations is…

We present a 100 kHz broadband vibrational sum-frequency generation (VSFG) spectrometer operating in the 5.5-10.5 $\mu$m (950-1750 cm$^{-1}$) wavelength range. The mid-infrared beam of the system is obtained from a collinear, type-I…

Instrumentation and Detectors · Physics 2019-06-26 Zsuzsanna Heiner , Li Wang , Valentin Petrov , Mark Mero

Nonlinear-optical microscopy and spectroscopy provide detailed spatial and spectroscopic contrast, specifically sensitive to structural symmetry and order. Ferroics, in particular, have been widely studied using second harmonic generation…

Plasmonic metasurfaces provide an effective way to increase the efficiency of several nonlinear processes while maintaining nanoscale dimensions. In this work, nonlinear metasurfaces based on film-coupled silver nanostripes loaded with Kerr…

Optics · Physics 2016-07-11 Boyuan Jin , Christos Argyropoulos

Mid-infrared (MIR) spectrometers are invaluable tools for molecular fingerprinting and hyper-spectral imaging. Among the available spectroscopic approaches, GHz MIR dual-comb absorption spectrometers have the potential to simultaneously…

Infrared and Visible Image Fusion (IVIF) has shown promise in visual tasks under challenging environments, but fusion under unregistered conditions faces inherent misalignments. Current studies to solve them either predict the deformation…

Computer Vision and Pattern Recognition · Computer Science 2026-05-14 Xingyuan Li , Haoyuan Xu , Xingyue Zhu , Jun Ma , Yang Zou , Zhiying Jiang , Jinyuan Liu

Recent developments in surface-enhanced Raman scattering (SERS) enable observation of single-bond vibrations in real-time at room temperature. By contrast, mid-infrared (MIR) vibrational spectroscopy is limited to inefficient slow…

We applied a tabletop, ultrafast, high-harmonic generation (HHG) source to measure the element-specific ferromagnetic resonance (FMR) in ultra-thin magnetic alloys and multilayers on an opaque Si substrate. We demonstrate a continuous wave…

Materials Science · Physics 2024-04-25 Michael Tanksalvala , Anthony Kos , Jacob Wisser , Scott Diddams , Hans T. Nembach , Justin M. Shaw

There is an active demand to develop efficient nanoscale nonlinear sources for applications in photonic circuitry, quantum optics and biosensing. To this end, plasmonic systems have been utilized to boost the nonlinear signal generation,…

Optics · Physics 2019-06-26 Feng Wang , Manoj Manjare , Robert Lemasters , Chentao Li , Hayk Harutyunyan

Reconfigurable photonic circuits have applications ranging from next-generation computer architectures to quantum networks, coherent radar and optical metamaterials. However, complete reconfigurability is only currently practical on…

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