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One of the fundamental applications for monolayer-thick 2D materials is their use as protective layers of metal surfaces and in-situ intercalated reactive materials in ambient conditions. Here we investigate the structural, electronic, and…

Large hexagonal boron nitride (hBN) single-layer islands of high crystalline quality were grown on Ir(111) via chemical vapor deposition (CVD) and have been studied with low-energy electron microscopy (LEEM). Two types of hBN islands have…

Mesoscale and Nanoscale Physics · Physics 2017-06-02 Marin Petrović , Ulrich Hagemann , Michael Horn-von Hoegen , Frank-J. Meyer zu Heringdorf

Hexagonal boron nitride (h-BN) is a prominent member in the growing family of two-dimensional materials with potential applications ranging from being an atomically smooth support for other 2D materials to templating growth of molecular…

The intercalation of Eu underneath Gr on Ir(111) is comprehensively investigated by microscopic, magnetic, and spectroscopic measurements, as well as by density functional theory. Depending on the coverage, the intercalated Eu atoms form…

The growth of monolayer hexagonal boron nitride (h-BN) on Ir(110) through low-pressure chemical vapor deposition is investigated using low energy electron diffraction and scanning tunneling microscopy. We find that the growth of aligned…

Materials Science · Physics 2024-02-16 Thomas Michely , Jason Bergelt , Affan Safeer , Alexander Bäder , Tobias Hartl , Jeison Fischer

Large, high-quality layers of hexagonal boron nitride (hBN) are a prerequisite for further advancement in scientific investigation and technological utilization of this exceptional 2D material. Here we address this demand by investigating…

Mesoscale and Nanoscale Physics · Physics 2019-12-23 Marin Petrović , Michael Horn-von Hoegen , Frank-J. Meyer zu Heringdorf

Metal nanostructures confined between sp2 hybridized 2D materials and solid supports are attracting attention for their potential application in new nanotechnologies. Model studies under well-defined conditions are valuable for…

Monolayer hBN has attracted interest as a potentially weakly interacting 2D insulating layer in heterostructures. Recently, wafer-scale hBN growth on Cu(111) has been demonstrated for semiconductor chip fabrication processes and transistor…

We report on a two-step ultrahigh vacuum chemical vapor deposition synthesis of a vertical Ir(111)/borophene/hexagonal boron nitride heterostructure, using borazine as a single-source precursor. The process takes advantage of the finite…

Stepwise deposition of Li atoms onto hexagonal boron nitride (hBN) monolayer on Ir(111) is investigated by means of angle-resolved photoemission spectroscopy and low-energy electron diffraction. Sequential Li deposition progressively shifts…

Mesoscale and Nanoscale Physics · Physics 2020-12-23 Marin Petrović

Hexagonal boron nitride (BN) is widely used as a substrate and gate insulator for two-dimensional (2D) electronic devices. The studies on insulating properties and electrical reliability of BN itself, however, are quite limited. Here, we…

Materials Science · Physics 2015-10-08 Y. Hattori , K. Watanabe , T. Taniguchi , K. Nagashio

The thickness and interfacial geometry of hexagonal boron nitride (hBN) films grown by chemical vapor deposition on polycrystalline nickel foils is studied using low-energy electron microscopy (LEEM). The reflectivity of the electrons,…

Mesoscale and Nanoscale Physics · Physics 2017-09-22 P. C. Mende , Q. Gao , A. Ismach , H. Chou , M. Widom , R. Ruoff , L. Colombo , R. M. Feenstra

Submonolayer h-BN was grown on Ni foil in ultra-high vacuum by the diffusion and precipitation method and the growth process was studied by x-ray photoelectron spectroscopy. Formation of h-BN started to be observed at 600 C. All through the…

Mesoscale and Nanoscale Physics · Physics 2019-07-03 Satoru Suzuki , Yuichi Haruyama

Improving the film quality in the synthesis of large-area hexagonal boron nitride films (h-BN) for two-dimensional material devices remains a great challenge. The measurement of electrical breakdown dielectric strength (EBD) is one of the…

Materials Science · Physics 2017-01-04 Yoshiaki Hattori , Takashi Taniguchi , Kenji Watanabe , Kosuke Nagashio

We report the design, synthesis, crystal structure, and physical properties of a layered intergrowth compound, Eu$_2$CuMn$_2$P$_3$. The structure of Eu$_2$CuMn$_2$P$_3$ features an alternating arrangement of hexagonal EuCuP block layers and…

Materials Science · Physics 2025-06-03 Xiyu Chen , Ziwen Wang , Wuzhang Yang , Jia-Yi Lu , Zhiyu Zhou , Zhi Ren , Guang-Han Cao , Shuai Dong , Zhi-Cheng Wang

Moire superlattices (MSLs) are an emerging class of two-dimensional functional materials whose electronic states can be tuned by the twist angle between two van der Waals layers and/or the relative placement of the layers. The intriguing…

Materials Science · Physics 2025-02-06 Rina Mishima , Takuro Nagai , Hiroyo Segawa , Masahiro Ehara , Takashi Uchino

Van der Waals heterostructures are at the forefront in materials heterostructure engineering, offering the ultimate control in layer selectivity and capability to combine virtually any material. Hexagonal boron nitride (hBN), the most…

Integration of individual two-dimensional materials into heterostructures is a crucial step which enables development of new and technologically interesting functional systems of reduced dimensionality. Here, well-defined lateral…

Mesoscale and Nanoscale Physics · Physics 2018-06-19 Marin Petrović , Michael Horn-von Hoegen , Frank-J. Meyer zu Heringdorf

The electronic structure of monolayer hexagonal boron nitride grown on Ni by the diffusion and precipitation method was studied by x-ray absorption spectroscopy, emission spectroscopy, x-ray photoelectron spectroscopy and micro-ultraviolet…

This paper reports on the growth and characterization of hexagonal boron nitride (hBN) and its use for solid-state thermal neutron detection. The hBN epilayers were grown by metalorganic chemical vapor deposition on sapphire substrates at a…

Materials Science · Physics 2016-09-12 Kawser Ahmed , Rajendra Dahal , Adam Weltz , James J. -Q. Lu , Yaron Danon , Ishwara B. Bhat
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