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The ab-initio computational treatment of electrochemical systems requires an appropriate treatment of the solid/liquid interfaces. A fully quantum mechanical treatment of the interface is computationally demanding due to the large number of…

We present a local formulation for 2D Discrete Exterior Calculus (DEC) similar to that of the Finite Element Method (FEM), which allows a natural treatment of material heterogeneity (element by element). It also allows us to deduce, in a…

Numerical Analysis · Mathematics 2018-12-31 Humberto Esqueda , Rafael Herrera , Salvador Botello , Carlos Valero

In this article, we analyse a stabilised equal-order finite element approximation for the Stokes equations on anisotropic meshes. In particular, we allow arbitrary anisotropies in a sub-domain, for example along the boundary of the domain,…

Numerical Analysis · Mathematics 2018-10-12 Stefan Frei

We propose a new nonconforming \(P_1\) finite element method for elliptic interface problems. The method is constructed on a locally anisotropic mixed mesh, which is generated by fitting the interface through a simple connection of…

Numerical Analysis · Mathematics 2025-10-08 Chenchen Geng , Hua Wang , Qichen Zhang

An Integral Equation (IE) based field solver to compute the scattered fields from spatially dispersive metasurfaces is proposed and numerically confirmed using various examples involving physical unit cells. The work is a continuation of…

Applied Physics · Physics 2021-09-21 Tom J. Smy , João G. Nizer Rahmeier , Jordan Dugan , Shulabh Gupta

Within a dipolar Poisson-Boltzmann theory including electrostatic correlations, we consider the effect of explicit solvent structure on solvent and ion partition confined to charged nanopores. We develop a relaxation scheme for the solution…

Soft Condensed Matter · Physics 2015-10-28 Sahin Buyukdagli

A new finite element method (FEM) using meshes that do not necessarily align with the interface is developed for two- and three-dimensional anisotropic elliptic interface problems with nonhomogeneous jump conditions. The degrees of freedom…

Numerical Analysis · Mathematics 2025-05-20 Haifeng Ji , Zhilin Li

An Integral Equation (IE) based electromagnetic field solver using metasurface susceptibility tensors is proposed and validated using variety of numerical examples in 2D. The proposed method solves for fields generated by the metasurface…

Computational Physics · Physics 2022-06-29 Tom. J. Smy , Ville Tiukuvaara , Shulabh Gupta

In this paper we develop a methodology for the mesoscale simulation of strong electrolytes. The methodology is an extension of the Fluctuating Immersed Boundary (FIB) approach that treats a solute as discrete Lagrangian particles that…

The interface stresses at of the solid-melt interface are, in general, anisotropic. The anisotropy in the interfacial stress can be evaluated using molecular dynamics (MD) and phase field crystal (PFC) models. In this paper, we report our…

Materials Science · Physics 2021-06-01 Sushil Kumar , Ming-Wei Liu , Kuo-An Wu , M P Gururajan

This work presents an open-source interface that couples the viscoplastic self-consistent (VPSC) model capable of simulating anisotropic creep and irradiation growth in polycrystalline materials with the finite element solver Code_Aster.…

We present a diffuse-interface model for the solid-state dewetting problem with anisotropic surface energies in ${\mathbb R}^d$ for $d\in\{2,3\}$. The introduced model consists of the anisotropic Cahn--Hilliard equation, with either a…

Analysis of PDEs · Mathematics 2023-02-15 Harald Garcke , Patrik Knopf , Robert Nürnberg , Quan Zhao

Reliable first-principles calculations of electrochemical processes require accurate prediction of the interfacial capacitance, a challenge for current computationally-efficient continuum solvation methodologies. We develop a model for the…

Chemical Physics · Physics 2018-04-12 Ravishankar Sundararaman , Kendra Letchworth-Weaver , Kathleen Schwarz

Recently, a nonlinear Poisson equation has been introduced to model nonlinear and nonlocal hyperpolarization effects in electrostatic solute-solvent interaction for biomolecular solvation analysis. Due to a strong nonlinearity associated…

Numerical Analysis · Mathematics 2018-01-17 Wufeng Tian

Tasker type III polar terminations of ionic crystals carry a net surface charge as well as a dipole moment and are fundamentally unstable. In contact with electrolytes, such polar surfaces can be stabilized by adsorption of counter ions…

Chemical Physics · Physics 2019-03-22 Thomas Sayer , Michiel Sprik , Chao Zhang

We extend the simplex-in-cell (SIC) technique recently introduced in the context of collisionless dark matter fluids (Abel et al. 2012; Hahn et al. 2012) to the case of collisionless plasmas. The six-dimensional phase space distribution…

Computational Physics · Physics 2015-06-25 Julian Kates-Harbeck , Samuel Totorica , Jonathan Zrake , Tom Abel

In this thesis, the electrostatic interaction between two chemically identical colloids, both carrying constant surface potential is studied in the limit of short inter-particle separation at the interface of two immiscible fluids. Using an…

Soft Condensed Matter · Physics 2020-01-01 Rick Bebon

A common approach for generating an anisotropic mesh is the M-uniform mesh approach where an adaptive mesh is generated as a uniform one in the metric specified by a given tensor M. A key component is the determination of an appropriate…

Numerical Analysis · Mathematics 2012-10-11 Lennard Kamenski

Continuum electrolyte models represent a practical tool to account for the presence of the diffuse layer at electrochemical interfaces. However, despite the increasing popularity of these in the field of materials science it remains unclear…

Computational Physics · Physics 2019-01-18 Francesco Nattino , Matthew Truscott , Nicola Marzari , Oliviero Andreussi

In multi-phase fluid flow, fluid-structure interaction, and other applications, partial differential equations (PDEs) often arise with discontinuous coefficients and singular sources (e.g., Dirac delta functions). These complexities arise…

Numerical Analysis · Mathematics 2019-07-24 Chung-Nan Tzou , Samuel Stechmann