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Hafnia-based ferroelectrics hold promise for nonvolatile ferroelectric memory devices. However, the high coercive field required for polarization switching remains a prime obstacle to their practical applications. A notable reduction in…

Materials Science · Physics 2025-02-11 Tianyuan Zhu , Liyang Ma , Xu Duan , Shi Liu

The recent observation of ferroelectricity in the metastable phases of binary metal oxides, such as HfO2, ZrO2, Hf0.5Zr0.5O2, and Ga2O3, has garnered a lot of attention. These metastable ferroelectric phases are typically stabilized through…

Materials Science · Physics 2023-03-02 Tengfei Cao , Guodong Ren , Ding-Fu Shao , Evgeny Y. Tsymbal , Rohan Mishra

In the realm of ferroelectric memories, HfO2-based ferroelectrics stand out because of their exceptional CMOS compatibility and scalability. Nevertheless, their switchable polarization and switching speed are not on par with those of…

Although dopants have been extensively employed to promote ferroelectricity in hafnia films, their role in stabilizing the responsible ferroelectric non-equilibrium Pca21 phase is not well understood. In this work, using first principles…

Materials Science · Physics 2017-07-14 Rohit Batra , Tran Doan Huan , George A. Rossetti, , Rampi Ramprasad

Magnetic interfaces and the phenomena arising from them drive both the design of modern spintronics and fundamental research. Recently, it was revealed that through designing magnetic frustration in configurationally complex entropy…

Films of all-important compound hafnia (HfO2) can be prepared in an orthorhombic ferroelectric (FE) state that is ideal for applications, e.g. in memories or negative-capacitance field-effect transistors. The origin of this FE state remains…

Materials Science · Physics 2020-07-15 Sangita Dutta , Hugo Aramberri , Tony Schenk , Jorge Íñiguez

Ferroelectric HfO2 is a promising candidate for next-generation memory devices due to its CMOS compatibility and ability to retain polarization at nanometer scales. However, the polar orthorhombic phase (Pca2_1) responsible for…

Materials Science · Physics 2026-03-27 Jian Huang , Gwan Yeong Jung , Pravan Omprakash , Guodong Ren , Xin Li , Du Li , Xiaoshan Xu , Li Yang , Rohan Mishra

The ferroelectric properties of nanoscale silicon doped HfO$_2$ promise a multitude of applications ranging from ferroelectric memory to energy-related applications. The reason for the unexpected behavior has not been clearly proven and…

Materials Science · Physics 2018-01-03 Christopher Künneth , Robin Materlik , Max Falkowski , Alfred Kersch

Ferroelectric field-effect doping has emerged as a powerful approach to manipulate the ground state of correlated oxides, opening the door to a new class of field-effect devices. However, this potential is not fully exploited so far, since…

Doping of strongly layered ionic oxides is an established paradigm for creating novel electronic behavior. This is nowhere more apparent than in superconductivity, where doping gives rise to high temperature superconductivity in cuprates…

Superconductivity · Physics 2013-07-17 E. R. Ylvisaker , W. E. Pickett

Two-dimensional (2D) multiferroics attract intensive investigations because of underlying science and their potential applications. Although many 2D systems have been observed/predicted to be ferroelectric or ferromagnetic, 2D materials…

Materials Science · Physics 2021-03-17 Chang Liu , Bing Wang , Guanwei Jia , Pengyu Liu , Huabing Yin , Shan Guan , Zhenxiang Cheng

The results of a previous work, where it was considered the effect of hole doping on a simple model of the CuO2 planes in La2CuO4, are extended. The parameters are adjusted with the objective to fix the known values of the gap of 2 eV for…

Superconductivity · Physics 2014-10-08 Yoandri Vielza de la Cruz , Alejandro Cabo Montes de Oca

We have systematically grown large single crystals of layered compound beta-PdBi2, both the hole-doped PdBi2-xPbx and the electron-doped NaxPdBi2, and studied their magnetic and transport properties. Hall-effect measurement on PdBi2,…

Superconductivity · Physics 2016-02-16 Kui Zhao , Bing Lv , Yu-Yi Xue , Xi-Yu Zhu , Liangzi Deng , Zheng Wu , C. W. Chu

We address the problem of the percolative phase separation in polycrystalline samples of Pr$_{0.5-\delta}$Ca$_{0.2+\delta}$Sr$_{0.3}$MnO$_3$ for $-0.04\leq \delta \leq 0.04$ (hole doping $n$ between 0.46 and 0.54). We perform measurements…

Strongly Correlated Electrons · Physics 2009-11-07 Dario G. Niebieskikwiat , Rodolfo D. Sanchez , Liliana Morales , Boris Maiorov

Phase stabilization continues to be a critical issue in hafnium oxide (HfO$_2$) due to the interdependence of various contributing factors. Using first-principles calculations, we analyze the effects of strain and doping on stabilizing the…

Materials Science · Physics 2025-01-03 Adedamola D. Aladese , Xiao Shen

We performed density functional theory (DFT) calculations on epitaxially strained hafnia. We demonstrate the stabilization of the ferroelectric ($Pca2_{1}$) phase from the antiferroelectric ($Pbcn$) in bulk hafnia in the presence of…

Materials Science · Physics 2023-02-07 Aldo Raeliarijaona , R. E. Cohen

Measurements of the low-frequency (f<= 100 kHz) permittivity at T<= 160 K and dc resistivity (T<= 430 K) are reported for La(1-x)Ca(x)MnO(3) (0<= x<= 0.15). Static dielectric constants are determined from the low-T limiting behavior of the…

Strongly Correlated Electrons · Physics 2009-11-11 K. P. Neupane , J. L. Cohn , H. Terashita , J. J. Neumeier

Electron- and hole-doped La$_2$CoMnO$_6$(LCMO) are investigated using first principles DFT calculations. Hole and electron doping are achieved respectively by introducing Sr$^{2+}$ at La$^{3+}$ sites and by inducing O-site vacancies in…

Materials Science · Physics 2021-09-02 Anasua Khan , Swastika Chatterjee , T. K. Nath , A. Taraphder

As a typical hole-doped cuprate superconductor, Bi 2 Sr 2 CaCu 2 O 8+{\delta} (Bi2212) carrier doping is mostly determined by its oxygen content. Traditional doping methods can regulate its doping level within the range of hole doping. Here…

The experimental realization of high-temperature superconductivity in compressed hydrides H$_3$S and LaH$_{10}$ at high pressures over 150 GPa has aroused great interest in reducing the stabilization pressure of superconducting hydrides.…

Superconductivity · Physics 2021-07-21 Chongze Wang , Shuyuan Liu , Hyunsoo Jeon , Seho Yi , Yunkyu Bang , Jun-Hyung Cho
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