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The projection of the eigenfunctions obtained in standard plane-wave first-principle electronic-structure calculations into atomic-orbital basis sets is proposed as a formal and practical link between the methods based on plane waves and…

Condensed Matter · Physics 2009-10-28 Daniel Sanchez-Portal , Emilio Artacho , Jose M. Soler

The electronic band structures of two-dimensional materials are significantly different from those of their bulk counterparts, due to quantum confinement and strong modifications of electronic screening. An accurate determination of…

Mesoscale and Nanoscale Physics · Physics 2020-07-08 Tomáš Rauch , Miguel A. L. Marques , Silvana Botti

The electronic ground state of a periodic system is usually described in terms of extended Bloch orbitals, but an alternative representation in terms of localized "Wannier functions" was introduced by Gregory Wannier in 1937. The connection…

Materials Science · Physics 2012-11-28 Nicola Marzari , Arash A. Mostofi , Jonathan R. Yates , Ivo Souza , David Vanderbilt

We investigate the electronic structure of over-coordinated defects in amorphous silicon via density-functional total-energy calculations, with the aim of understanding the relationship between topological and electronic properties on a…

Materials Science · Physics 2007-05-23 M. Fornari , N. Marzari , M. Peressi , A. Baldereschi

The tight binding model is a minimal electronic structure model for molecular modelling and simulation. We show that the total energy in this model can be decomposed into site energies, that is, into contributions from each atomic site…

Numerical Analysis · Mathematics 2015-06-19 Huajie Chen , Christoph Ortner

In this paper, we propose an extended plane wave framework to make the electronic structure calculations of the twisted bilayer 2D material systems practically feasible. Based on the foundation in [Y. Zhou, H. Chen, A. Zhou, J. Comput.…

Computational Physics · Physics 2023-01-05 Xiaoying Dai , Aihui Zhou , Yuzhi Zhou

The electronic properties of the twisted InSe bilayer are studied by large-scale density functional theory. Spectral Function Unfolding reveals that the electronic structure of the twisted system can be described in terms of a combination…

Materials Science · Physics 2022-02-28 Siow Mean Loh , Nicholas D. M. Hine

Complex molecules and mesoscopic structures are naturally described by general networks of elementary building blocks and tight-binding is one of the simplest quantum model suitable for studying the physical properties arising from the…

Condensed Matter · Physics 2009-11-07 P. Buonsante , R. Burioni , D. Cassi

We investigate the moir\'e band structures and the strong correlation effects in twisted bilayer MoTe$_2$ for a wide range of twist angles, employing a combination of various techniques. Using large-scale first principles calculations, we…

Strongly Correlated Electrons · Physics 2024-03-04 Cheng Xu , Jiangxu Li , Yong Xu , Zhen Bi , Yang Zhang

We present a first-principles method for deriving effective low-energy models of electrons in solids having entangled band structure. The procedure starts with dividing the Hilbert space into two subspaces, the low-energy part ("$d$…

Strongly Correlated Electrons · Physics 2010-10-20 Takashi Miyake , Ferdi Aryasetiawan , Masatoshi Imada

The tight binding model is a minimalistic electronic structure model for predicting properties of materials and molecules. For insulators at zero Fermi-temperature we show that the potential energy surface of this model can be decomposed…

Mathematical Physics · Physics 2020-04-21 Christoph Ortner , Jack Thomas , Huajie Chen

Twisted bilayer graphene (TBLG) has emerged as an important platform for studying correlated phenomena, including unconventional superconductivity, in two-dimensional systems. The complexity of the atomic-scale structures in TBLG has made…

Strongly Correlated Electrons · Physics 2019-11-07 Stephen Carr , Shiang Fang , Hoi Chun Po , Ashvin Vishwanath , Efthimios Kaxiras

We propose a unique scheme to construct fully optimized atomic basis sets for density-functional calculations. The shapes of the radial functions are optimized by minimizing the {\it spillage} of the wave functions between the atomic…

Materials Science · Physics 2015-05-19 Mohan Chen , G-C Guo , Lixin He

Tight-binding (TB) molecular dynamics (MD) has emerged as a powerful method for investigating the atomic-scale structure of materials --- in particular the interplay between structural and electronic properties --- bridging the gap between…

Materials Science · Physics 2007-05-23 Laurent J Lewis , Normand Mousseau

A model to describe electronic correlations in energy bands is considered. The model is a generalization of the conventional Hubbard model that allows for the fact that the wavefunction for two electrons occupying the same Wannier orbital…

Strongly Correlated Electrons · Physics 2009-11-07 J. E. Hirsch

We present TopoTB, a software package written in the Mathematica language, designed to compute electronic structures, topological properties, and phase diagrams based on tight-binding models. TopoTB is user-friendly, with an interactive…

Materials Science · Physics 2024-03-14 Xinliang Huang , Fawei Zheng , Ning Hao

In typical flat-band models, defined as nearest-neighbor tight-binding models, flat bands are usually pinned to the special energies, such as top or bottom of dispersive bands, or band-crossing points. In this paper, we propose a simple…

Strongly Correlated Electrons · Physics 2019-06-12 Tomonari Mizoguchi , Masafumi Udagawa

We discuss a method for determining the optimally-localized set of generalized Wannier functions associated with a set of Bloch bands in a crystalline solid. By ``generalized Wannier functions'' we mean a set of localized orthonormal…

Materials Science · Physics 2009-10-30 Nicola Marzari , David Vanderbilt

Predicting the fate of an interacting system in the limit where the electronic bandwidth is quenched is often highly non-trivial. The complex interplay between interactions and quantum fluctuations driven by the band geometry can drive…

Strongly Correlated Electrons · Physics 2023-06-02 Johannes S. Hofmann , Erez Berg , Debanjan Chowdhury

Hybrid density functional calculation is indispensable to accurate description of electronic structure, whereas the formidable computational cost restricts its broad application. Here we develop a deep equivariant neural network method…

Materials Science · Physics 2023-02-17 Zechen Tang , He Li , Peize Lin , Xiaoxun Gong , Gan Jin , Lixin He , Hong Jiang , Xinguo Ren , Wenhui Duan , Yong Xu
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