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Photocatalytic hydrogen (H2) production and carbon dioxide (CO2) conversion to methane (CH4) are considered promising solutions for reducing CO2 emissions. However, the development of highly active photocatalysts is essential to efficiently…

Materials Science · Physics 2025-10-23 Jacqueline Hidalgo-Jimenez , Taner Akbay , Tatsumi Ishihara , Kaveh Edalati

Achieving both broad solar-spectrum absorption and strong redox capability is critical for semiconductor photocatalysts in environmental remediation and energy conversion. Herein, an S-scheme heterojunction photocatalyst is constructed by…

Materials Science · Physics 2026-03-31 Xiaoyi Zhou , Min Zhang , Qiushi Wang , Shiwen Du , Xuedong Jing , Zhenyi Zhang

High-entropy oxides (HEOs), as multi-component ceramics with high configurational entropy, have been of recent interest due to their attractive properties including photocatalytic activity for H2 production and CO2 conversion. However, the…

High-entropy oxides (HEOs), containing at least five principal cations, have recently emerged as promising photocatalysts for hydrogen production via water splitting. Despite their high potential, the impact of the cation mixtures on…

Materials Science · Physics 2024-05-31 Jacqueline Hidalgo-Jimenez , Taner Akbay , Tatsumi Ishihara , Kaveh Edalati

Methane (CH4) formation from photocatalytic carbon dioxide (CO2) conversion in water is currently of interest because methane is a fuel, and it can also be transformed into other useful hydrocarbons. However, achieving high selectivity to…

Materials Science · Physics 2025-03-21 Jacqueline Hidalgo-Jiménez , Taner Akbay , Xavier Sauvage , Tatsumi Ishihara , Kaveh Edalati

Methane (CH4) and nitrous oxide (N2O) are potent greenhouse gases that represent substantial chemical energy. Conversion of these abundant waste gases to high-value chemicals typically requires high temperatures up to 1000 C, producing…

Simultaneous catalytic hydrogen (H2) production and plastic waste degradation under light, known as photoreforming, is a novel approach to green fuel production and efficient waste management. Here, we use a high-entropy oxide (HEO), a new…

Materials Science · Physics 2024-12-03 Thanh Tam Nguyen , Kaveh Edalati

High-entropy oxides (HEOs), as a new family of materials with five or more principal cations, have shown promising properties for various applications. In this work and inspired by inherent defective and strained structure of HEOs,…

To enhance the activity of photocatalysts for hydrogen production and CO2 conversion, noble metal cocatalysts as electron traps and/or acceptors such as platinum or gold are usually utilized. This study hypothesizes that mixing elements…

Materials Science · Physics 2025-01-17 Jacqueline Hidalgo-Jiménez , Taner Akbay , Xavier Sauvage , Tatsumi Ishihara , Kaveh Edalati

The catalytic CO2 photoreduction to CO is significantly hindered by the pervasive kinetic bottleneck of *CO-desorption and inefficient charge separation. Surpassing the conventional single photocatalytic strategy, herein, a multi-synergetic…

Materials Science · Physics 2025-11-11 Muneeb ur Rahman

Ammonia, a critical chemical fertilizer and a potential hydrogen carrier, can be sustainably synthesized from atmospheric nitrogen and water under ambient conditions through photocatalysis. In this study, high-entropy oxides with d0 and…

Chemical Physics · Physics 2025-08-19 Thanh Tam Nguyen , Jacqueline Hidalgo-Jimenez , Kaveh Edalati

Photocatalytic water splitting has greatly stimulated as an ideal technique for producing hydrogen (H$_{2}$) fuel by employing two renewable sources, i.e., water and solar energy. Here, we have adopted a facile hydrothermal approach for the…

Chemical Physics · Physics 2022-01-04 Fahmida Sharmin , Dayal Chandra Roy , M. A. Basith

The photoconversion of CO$_2$ to hydrocarbons is a sustainable route to its transformation into value-added compounds and, thereby, crucial to mitigating the energy and climate crises. CuPt nanoparticles on TiO$_2$ surfaces have been…

Efficient artificial photosynthesis systems are currently realized as catalyst- and surfacefunctionalized photovoltaic tandem- and triple-junction devices, enabling photoelectrochemical (PEC) water oxidation while simultaneously recycling…

The persistent existence of plastic waste causes serious problems for the environment, directly and indirectly affecting the health of organisms and humans. Photoreforming is a nature-friendly method that only uses solar energy to convert…

Materials Science · Physics 2024-12-30 Ho Truong Nam Hai , Thanh Tam Nguyen , Maiko Nishibori , Tatsumi Ishihara , Kaveh Edalati

The high recombination rate of photogenerated carriers is the bottleneck of photocatalysis, severely limiting the photocatalytic efficiency. Here, we develop a dipole-scheme (D-scheme for short) photocatalytic model and materials…

Materials Science · Physics 2022-07-13 Xu Gao , Yanqing Shen , Jiajia Liu , Lingling Lv , Min Zhou , Zhongxiang Zhou , Yuan Ping Feng , Lei Shen

The production of hydrogen from water using only a catalyst and solar energy is one of the most challenging and promising outlets for the generation of clean and renewable energy. Semiconductor photocatalysts for solar hydrogen production…

Two-dimensional (2D) layered nanomaterials heterostructures, arising from the combination of 2D materials with other low-dimensional species, feature large surface area to volume ratio, which provides a high density of active sites for…

Materials Science · Physics 2025-02-19 Mengjiao Wang , Michal Langer , Roberto Altieri , Matteo Crisci , Silvio Osella , Teresa Gatti

High-entropy materials have emerged as a promising class of catalysts, driven by their high configurational entropy originating from structural disorder in single-phase multicomponent systems. Despite their potential, the catalytic…

Materials Science · Physics 2025-12-23 Anjali Varshney , Aishwery J. Verma , Ritesh Dubey , Sushil Kumar , Tapas Goswami , Samar Layek

Solar redox flow batteries (SRFB) have received much attention as an alternative integrated technology for simultaneous conversion and storage of solar energy. Yet, the photocatalytic efficiency of semiconductor-based single photoelectrode,…

Chemical Physics · Physics 2024-08-02 Jiaming Ma , Milad Sabzehparvar , Ziyan Pan , Giulia Tagliabue
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