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We review our recent development of a first-principles lattice dynamics method that can treat anharmonic effects nonperturbatively. The method is based on the self-consistent phonon theory and temperature-dependent phonon frequencies can be…

Materials Science · Physics 2018-01-29 Terumasa Tadano , Shinji Tsuneyuki

An accurate and easily extendable method to deal with lattice dynamics of solids is offered. It is based on first-principles molecular dynamics simulations and provides a consistent way to extract the best possible harmonic - or higher…

Materials Science · Physics 2013-10-14 Olle Hellman , I. A. Abrikosov , S. I. Simak

We apply standard, first-principles calculations to a complete treatment of lattice dynamics in the harmonic approximation. The algorithm makes use of the straightforward ``frozen-phonon'' approach to the calculation of vibrational spectra…

Materials Science · Physics 2007-05-23 Hadley M. Lawler , Eric K. Chang , Eric L. Shirley

A new method for extracting force constants (FC) from first principles is introduced. It requires small supercells but very accurate forces. In principle, provided that forces are accurate enough, it can extract harmonic as well as…

Materials Science · Physics 2007-10-31 Keivan Esfarjani , Harold T. Stokes

First principles predictions of lattice dynamics are of vital importance for a broad range of topics in materials science and condensed matter physics. The large-scale nature of lattice dynamics calculations and the desire to design novel…

Materials Science · Physics 2023-01-23 Jinliang Ning , James W. Furness , Jianwei Sun

Solving Peierls-Boltzmann transport equation with interatomic force constants (IFCs) from first-principles calculations has been a widely used method for predicting lattice thermal conductivity of three-dimensional materials. With the…

Materials Science · Physics 2026-05-28 Han Xie , Xiaokun Gu , Hua Bao

Au-Fe alloys are of immense interest due to their biocompatibility, anomalous hall conductivity, and applications in various medical treatment. However, irrespective of the method of preparation, they often exhibit a high-level of disorder,…

Materials Science · Physics 2017-09-27 Jiban Kangsabanik , Rajiv K. Chouhan , D. D. Johnson , Aftab Alam

We present a scheme to construct model potentials, with parameters computed from first principles, for large-scale lattice-dynamical simulations of materials. Our method mimics the traditional solid-state approach to the investigation of…

Materials Science · Physics 2013-12-04 Jacek C. Wojdeł , Patrick Hermet , Mathias P. Ljungberg , Philippe Ghosez , Jorge Íñiguez

Knowledge of lattice anharmonicity is essential to elucidate distinctive thermal properties in crystalline solids. Yet, accurate \textit{ab initio} investigations of lattice anharmonicity encounter difficulties owing to the cumbersome…

Materials Science · Physics 2022-04-13 Zhen Zhang , Dong-Bo Zhang , Tao Sun , Renata M. Wentzcovitch

Phonon lifetime calculations from first principles usually rely on time consuming molecular dynamics calculations, or density functional perturbation theory (DFPT) where the zero temperature crystal structure is assumed to be dynamically…

Statistical Mechanics · Physics 2015-05-27 Petros Souvatzis

The lattice dynamics of LaFeAsO_{1-x}F_{x} (x=0, 0.1) and PrFeAsO_{1-y} (y~0.1) are investigated using inelastic x-ray scattering and ab-initio calculation. Measurements of powder samples provide an approximation to the phonon DOS, while…

We present a fully automated framework for extracting interatomic force constants (IFCs) directly from X-ray thermal diffuse scattering (TDS) data. By formulating scattering intensity as a differentiable function of a symmetry-reduced IFC…

Computational Physics · Physics 2026-03-31 Klara Suchan , Shaswat Mohanty , Hanfeng Zhai , Wei Cai

Phonon plays essential roles in dynamical behaviors and thermal properties, which are central topics in fundamental issues of materials science. The importance of first principles phonon calculations cannot be overly emphasized. Phonopy is…

Materials Science · Physics 2015-06-30 Atsushi Togo , Isao Tanaka

Phonons, quantized vibrations of the atomic lattice, are fundamental to understanding thermal transport, structural stability, and phase behavior in crystalline solids. Despite advances in computational materials science, most predictions…

Materials Science · Physics 2026-01-15 Huiju Lee , Zhi Li , Jiangang he , Yi Xia

The lattice dynamics in substitutional disordered alloys with constituents having large size differences is driven by strong disorder in masses, inter-atomic force constants and local environments. In this letter, a new first-principles…

Materials Science · Physics 2016-08-14 Oscar Grånäs , Biswanath Dutta , Subhradip Ghosh , Biplab Sanyal

First-principles phonon calculations have been widely performed for studying vibrational properties of condensed matter, where the dynamical matrix is commonly constructed via supercell force-constant calculations or the linear response…

Materials Science · Physics 2020-11-11 Chi-Cheng Lee , Chin-En Hsu , Hung-Chung Hsueh

We start from the polynomic interatomic potentials introduced by Wojde{\l} et al. [J. Phys. Condens. Matt. 25, 305401(2013)] and take advantage of one of their key features -- namely, the linear dependence of the energy on the potential's…

Materials Science · Physics 2017-03-22 Carlos Escorihuela-Sayalero , Jacek C. Wojdeł , Jorge Íñiguez

Phonon interactions from lattice anharmonicity govern thermal properties and heat transport in materials. These interactions are described by n-th order interatomic force constants (n-IFCs), which can be viewed as high-dimensional tensors…

Materials Science · Physics 2025-08-12 Yao Luo , Dhruv Mangtani , Shiyu Peng , Jia Yao , Sergei Kliavinek , Marco Bernardi

The phonon dispersion relations of crystal lattices can often be well-described with the harmonic approximation. However, when the potential energy landscape exhibits more anharmonicity, for instance, in case of a weakly bonded crystal or…

Materials Science · Physics 2022-01-19 Jonathan Lahnsteiner , Menno Bokdam

Understanding and predicting lattice dynamics in strongly anharmonic crystals is one of the long-standing challenges in condensed matter physics. Here we propose a first-principles method that gives accurate quasiparticle (QP) peaks of the…

Materials Science · Physics 2022-11-09 Terumasa Tadano , Wissam A. Saidi
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