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A rechargeable lithium metal battery (LMB), which uses metallic lithium at the anode, is among the most promising technologies for next generation electrochemical energy storage devices due to its high energy density, particularly when Li…

Materials Science · Physics 2016-04-15 Lin Ma , Mun Sek Kim , Lynden A. Archer

The path toward Li-ion batteries with higher energy-densities will likely involve use of thin lithium metal (Li) anode (<50 $\mu$m in thickness), whose cyclability today remains limited by dendrite formation and low Coulombic efficiency.…

Lithium-ion batteries (LIBs) have become essential in modern energy storage; however, their performance is often limited by the stability and efficiency of their components, particularly the cathode and electrolyte. Transition metal layered…

Materials Science · Physics 2025-07-15 M. D. Hashan C. Peiris , Michael Woodcox , Diana Liepinya , Robert Shepard , Hao Liu , Manuel Smeu

Passivating lithium ion battery electrode surfaces to prevent electrolyte decomposition is critical for battery operations. Recent work on conformal atomic layer deposition (ALD) coating of anodes and cathodes has shown significant…

The existence of passivating layers at the interfaces is a major factor enabling modern lithium-ion (Li-ion) batteries. Their properties determine the cycle life, performance, and safety of batteries. A special case is the solid electrolyte…

Chemical Physics · Physics 2021-06-07 Zeeshan Ahmad , Victor Venturi , Hasnain Hafiz , Venkatasubramanian Viswanathan

Understanding solid liquid interfaces at high spatial and chemical resolution is crucial for advancing electrochemical energy storage technologies, yet this remains a persistent challenge due to the lack of characterisation techniques that…

The Solid-Electrolyte Interphase, SEI, formed on a battery electrode has been a central area of research for decades. This thin, complex layer profoundly impacts the electrochemical deposition morphology and stability of the metal in…

Materials Science · Physics 2025-03-19 Stephen T. Fuller , J. -X. Kent Zheng

The solid electrolyte interphase SEI critically dictates the cyclability and Coulombic efficiency of sodium-metal batteries, yet its dynamic formation mechanisms and atomic-scale evolution during electrochemical cycling remain elusive due…

Materials Science · Physics 2026-04-09 Zhoulin Liu , Ziliang Wang , Zherui Chen , Jianchun Sha , Fengzijun Pan , Pingyang Zhang , Yinghe Zhang

Nonaqueous aluminum-ion batteries are an interesting emerging energy storage technology, offering a plethora of advantages over existing grid energy storage solutions. Carbonaceous and graphitic materials are an appealing cathode material…

Chemical Physics · Physics 2020-01-17 Nicolò Canever , Fraser R. Hughson , Thomas Nann

Solid electrolyte interphase (SEI), a thin layer that dynamically forms between active electrode and electrolyte during battery operation, critically governs the performance of rechargeable batteries1-5. An ideal SEI is expected to be…

Understanding and controlling the atomistic-level reactions governing the formation of the solid-electrolyte interphase (SEI) is crucial for the viability of next-generation solid state batteries. However, challenges persist due to…

Materials Science · Physics 2025-06-13 Jingxuan Ding , Laura Zichi , Matteo Carli , Menghang Wang , Albert Musaelian , Yu Xie , Boris Kozinsky

In solid-state batteries (SSBs), improving the physical contact at the electrode-electrolyte interface is essential for achieving better performance and durability. On the one hand, it is necessary to look for solid-state electrolytes…

Materials Science · Physics 2024-10-22 Qifan Yang , Jing Xu , Xiao Fu , Jingchen Lian , Liqi Wang , Xuhe Gong , Zibin Wang , Ruijuan Xiao , Hong Li

A crucial ingredient in lithium (Li) and sodium (Na)-ion batteries (LIBs and NIBs) is the electrolytes. The use of Li-metal (Na-metal) as anode in liquid electrolyte LIBs (NIBs) is constrained by several issues including thermal runway and…

Materials Science · Physics 2022-12-14 Juefan Wang , Abhishek A. Panchal , Gopalakrishnan Sai Gautam , Pieremanuele Canepa

Ion transport across solid solid interfaces is often slower than through the bulk of a material, impeding the charge and discharge rate of batteries. Designing highly conductive interfaces is challenging due to the need to probe ion…

In rechargeable batteries, electron transport properties of inorganics in the solid-electrolyte interphase (SEI) critically determine the safety, lifespan and capacity loss of batteries. However, the electron transport properties of…

Materials Science · Physics 2025-01-23 Xiangyi Zhou , Rongzhi Gao , Ziyang Hu , Weijun Zhou , YanHo Kwok , GuanHua Chen

Lithium-ion batteries (LIBs) are crucial for the green economy, powering portable electronics, electric vehicles, and renewable energy systems. The solid-electrolyte interphase (SEI) is vital for LIB operation, performance, and safety. SEI…

Materials Science · Physics 2025-10-01 Paolo De Angelis , Roberta Cappabianca , Matteo Fasano , Pietro Asinari , Eliodoro Chiavazzo

Interfacial deposition stability between Li metal and a solid electrolyte (SE) is important in preventing interfacial contact loss, mechanical fracture, and dendrite growth in Li-metal solid-state batteries (SSB). In this work, we…

Applied Physics · Physics 2020-06-08 Qingsong Tu , Luis Barroso-Luque , Tan Shi , Gerbrand Ceder

Future lithium-based batteries are expected to use solid electrolytes to achieve higher energy density and fast charge capabilities. The majority of solid electrolytes are thermodynamically unstable against layered oxide cathodes. Here, the…

Charging a Li ion battery requires Li ion transport between the cathode and the anode. This Li ion transport is dependent upon (among other factors) the electrostatic environment the ion encounters within the Solid Electrolyte Interphase…

Materials Science · Physics 2024-06-06 Quinn T. Campbell

Prelithiation as a facile and effective method to compensate the lithium inventory loss in the initial cycle has progressed considerably both on anode and cathode sides. However, much less research has been devoted to the prelithiation…

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