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Difference of degeneracy of the low-spin (LS) and high-spin (HS) states causes interesting entropy effects on spin-crossover phase transitions and charge transfer phase transitions in materials composed of the spin-crossover atoms.…

Classical transition state theory (TST) is the cornerstone of reaction rate theory. It postulates a partition of phase space into reactant and product regions, which are separated by a dividing surface that reactive trajectories must cross.…

Statistical Mechanics · Physics 2007-05-23 Thomas Bartsch , Rigoberto Hernandez , T. Uzer

Recently, the possibility of exploiting the phenomenon of spin transition (ST) has been intensively investigated, therefore, it is particularly important to study the behavior of ST under various stimuli. Here, the shape and content of the…

The study of charge and spin transport through semiconductor quantum dots is experiencing a renaissance due to recent advances in nano-fabrication and the realization of quantum dots as candidates for quantum computing. In this work, we…

Mesoscale and Nanoscale Physics · Physics 2021-02-17 John P. Philbin , Amikam Levy , Prineha Narang , Wenjie Dou

We investigate a specific limit of the one-dimensional non-Hermitian Hubbard Hamiltonian with complex interactions. In this framework, fermions with different spin quantum numbers are mapped onto two distinct spin species, resulting in two…

Statistical Mechanics · Physics 2024-12-30 Doru Sticlet , Cătălin Paşcu Moca , Balázs Dóra

After the discovery of the phenomena of light-induced excited spin state trapping (LIESST), the functional properties of metal complexes have been studied intensively. Among them, cooperative phenomena involving low spin-high spin…

Materials Science · Physics 2009-11-11 Kamel Boukheddaden , Masamichi Nishino , Seiji Miyashita , Francois Varret

Angular momentum changing collisions can be suppressed in atoms whose valence electrons are submerged beneath filled shells of higher principle quantum number. To determine whether spin-exchange collisions are suppressed in these "submerged…

Atomic Physics · Physics 2009-11-13 J. G. E. Harris , S. V. Nguyen , S. C. Doret , W. Ketterle , J. M. Doyle

We consider the spin-exchange in ultracold collisions of hydrogen ($H$) and antihydrogen ($\bar{H}$) atoms. The cross sections for transitions between various hyperfine states are calculated. We show that the process of spin exchange in…

Atomic Physics · Physics 2015-05-13 A. Yu. Voronin , P. Froelich

This dissertation unifies one of the central methods of classical rate calculation, `Transition-State Theory' (TST), with quantum mechanics, thereby deriving a rigorous `Quantum Transition-State Theory' (QTST). The resulting QTST is…

Chemical Physics · Physics 2014-08-06 Timothy J. H. Hele

We study the origin of the cooperative nature of spin crossover (SC) between low spin (LS) and high spin (HS) states from the view point of elastic interactions among molecules. As the size of each molecule changes depending on its spin…

Strongly Correlated Electrons · Physics 2009-11-13 Masamichi Nishino , Kamel Boukheddaden , Yusuké Konishi , Seiji Miyashita

We present the linear spin wave theory calculation of the superfluid phase of a hard-core boson $J$-$K$ model with nearest neighbour exchange $J$ and four-particle ring-exchange $K$ at half filling on the triangular lattice, as well as the…

Strongly Correlated Electrons · Physics 2013-06-25 Solomon A. Owerre

In spin-transfer torque (STT) for technological applications, the miniaturization of the magnet may reach the stage of requiring a fully quantum-mechanical treatment. We present an STT theory which uses the quantum macrospin ground and…

Mesoscale and Nanoscale Physics · Physics 2013-05-10 Tiamhock Tay , L. J. Sham

The standard spin-transfer torque (STT)---where spin-polarized current drives dynamics of magnetization viewed as a classical vector---requires noncollinearity between electron spins carried by the current and magnetization of a…

Strongly Correlated Electrons · Physics 2019-03-22 Priyanka Mondal , Marko D. Petrovic , Petr Plechac , Branislav K. Nikolic

The inclusion of charging and spin-exchange interactions within the Universal Hamiltonian description of quantum dots is challenging as it leads to a non-Abelian action. Here we present an exact analytical solution of the probem, in…

Mesoscale and Nanoscale Physics · Physics 2012-04-13 I. S. Burmistrov , Yuval Gefen , M. N. Kiselev

The physics of interacting nuclear spins arranged in a crystalline lattice is typically described using a thermodynamic framework: a variety of experimental studies in bulk solid-state systems have proven the concept of a spin temperature…

Mesoscale and Nanoscale Physics · Physics 2009-07-21 P. Maletinsky , M. Kroner , A. Imamoglu

Recently has been observed for some one-dimensional models that exhibit unexpected pseudo-transitions and quasi-phases. This pseudo-transition resembles a first- and second-order phase transition simultaneously. One of those models is the…

Strongly Correlated Electrons · Physics 2018-06-18 I. M. Carvalho , J. Torrico , S. M. de Souza , M. Rojas , O. Rojas

A general semiclassical theory for the calculation of reaction rate constants is developed. The theory can be understood as a formal framework that encompasses existing semiclassical methods: instanton theory and semiclassical transition…

Chemical Physics · Physics 2025-10-09 Joseph E. Lawrence

The stability of high vs. low spin states of transition metal complexes has been interpreted by ligand field theory, which is a perturbation theory of the electron-electron interaction. The present first principles calculation of a series…

Chemical Physics · Physics 2012-10-01 Hannes Raebiger , Shuhei Fukutomi , Hiroshi Yasuhara

We consider the superconducting pairing induced by spin waves exchange in a ferromagnet with both conduction and localized electrons, the latter being described as spins. We use the microscopic Eliashberg theory to describe the pairing of…

Superconductivity · Physics 2019-03-27 Lev Bulaevskii , Ronivon Eneias , Alvaro Ferraz

Spin-transfer is a typical spintronics effect that allows a ferromagnetic layer to be switched by spin-injection. Most of the experimental results about spin transfer are described on the basis of the Landau-Lifshitz-Gilbert equation of the…

Materials Science · Physics 2015-06-25 J. -E. Wegrowe , C. Ciornei , H. -J. Drouhin
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