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In this work, the MMC-TDGL equation, a stochastic Cahn-Hilliard equation is solved numerically by using the finite difference method in combination with a convex splitting technique of the energy functional. For the non-stochastic case, we…

Numerical Analysis · Mathematics 2016-08-24 Xiao Li , Zhonghua Qiao , Hui Zhang

The exchange-correlation energy in Kohn-Sham density functional theory is expressed as a functional of the electronic density and the Kohn-Sham orbitals. An alternative to Kohn-Sham theory is to express the energy as a functional of the…

Computational Physics · Physics 2009-10-31 S. Goedecker , C. Umrigar

Partial Differential Equations (PDE) are fundamental to model different phenomena in science and engineering mathematically. Solving them is a crucial step towards a precise knowledge of the behaviour of natural and engineered systems. In…

We introduce a non-equilibrium density-functional theory of local temperature and associated local energy density that is suited for the study of thermoelectric phenomena. The theory rests on a local temperature field coupled to the…

Strongly Correlated Electrons · Physics 2014-05-16 F. G. Eich , M. Di Ventra , G. Vignale

We present a fully iterative adaptive algorithm for the numerical minimization of strongly convex energy functionals in Hilbert spaces. The proposed approach, which we first present in abstract form, generates a hierarchical sequence of…

Numerical Analysis · Mathematics 2026-02-26 Raphael Leu , Thomas P. Wihler

Two related numerical schemes for the realization of the Mortensen observer or minimum energy estimator for the state reconstruction of non-linear dynamical systems subject to deterministic disturbances are proposed and compared. Both…

Optimization and Control · Mathematics 2023-11-09 Tobias Breiten , Karl Kunisch , Jesper Schröder

We investigate a functional limit theorem (homogenization) for Reflected Stochastic Differential Equations on a half-plane with stationary coefficients when it is necessary to analyze both the effective Brownian motion and the effective…

Probability · Mathematics 2009-09-18 Remi Rhodes

We introduce a new approach to density functional theory based on kinetic theory, showing that the Kohn-Sham equations can be derived as a macroscopic limit of a suitable Boltzmann kinetic equation in the limit of small mean free path…

Chemical Physics · Physics 2015-06-15 M. Mendoza , S. Succi , H. J. Herrmann

To sidestep the curse of dimensionality when computing solutions to Hamilton-Jacobi-Bellman partial differential equations (HJB PDE), we propose an algorithm that leverages a neural network to approximate the value function. We show that…

Machine Learning · Computer Science 2017-03-28 Frank Jiang , Glen Chou , Mo Chen , Claire J. Tomlin

We consider a nonlinear convex stochastic homogenization problem, in a stationary setting. In practice, the deterministic homogenized energy density can only be approximated by a random apparent energy density, obtained by solving the…

Numerical Analysis · Mathematics 2013-02-04 Frederic Legoll , William Minvielle

We propose a new data-driven approach for learning the fundamental solutions (Green's functions) of various linear partial differential equations (PDEs) given sample pairs of input-output functions. Building off the theory of functional…

Statistics Theory · Mathematics 2023-04-11 George Stepaniants

We propose a way to improve energy density functionals (EDFs) in the density functional theory based on the combination of the inverse Kohn--Sham method and the density functional perturbation theory. Difference between the known EDF and…

Chemical Physics · Physics 2019-11-22 Tomoya Naito , Daisuke Ohashi , Haozhao Liang

The elastic energy functional of a system of discrete dislocation lines is well known from dislocation theory. In this paper we demonstrate how the discrete functional can be used to systematically derive approximations which express the…

Materials Science · Physics 2015-12-02 Michael Zaiser

We focus on the numerical approximation of the Cahn-Hilliard type equations, and present a family of second-order unconditionally energy-stable schemes. By reformulating the equation into an equivalent system employing a scalar auxiliary…

Fluid Dynamics · Physics 2018-03-19 Suchuan Dong , Zhiguo Yang , Lianlei Lin

In this work we focus on the preconditioning of a Galerkin space-time isogeometric discretization of the heat equation. Exploiting the tensor product structure of the basis functions in the parametric domain, we propose a preconditioner…

Numerical Analysis · Mathematics 2020-11-03 Gabriele Loli , Monica Montardini , Giancarlo Sangalli , Mattia Tani

A new method for constructing a Hamiltonian for configuration interaction calculations with constraints to energies of spherical configurations obtained with energy-density-functional (EDF) methods is presented. This results in a unified…

Nuclear Theory · Physics 2011-01-04 B. Alex Brown , Angelo Signoracci , Morten Hjorth-Jensen

We present a method to compute high-order derivatives of the total energy which can be used in the framework of density functional theory. We provide a proof of the $2n+1$ theorem for a general class of energy functionals in which the…

Condensed Matter · Physics 2007-05-23 Andrea Dal Corso , Francesco Mauri

We introduce what we call the second-order Boltzmann-Gibbs principle, which allows to replace local functionals of a conservative, one-dimensional stochastic process by a possibly nonlinear function of the conserved quantity. This…

Probability · Mathematics 2015-06-17 Patricia Gonçalves , Milton Jara

Feedback control problems involving autonomous polynomial systems are prevalent, yet there are limited algorithms and software for approximating their solution. This paper represents a step forward by considering the special case of the…

Optimization and Control · Mathematics 2020-09-24 Jeff Borggaard , Lizette Zietsman

We present a method for approximating solutions of Stochastic Differential Equations (SDEs) with arbitrary rates. This approximation is derived for bounded and measurable test functions. Specifically, we demonstrate that, leveraging the…

Probability · Mathematics 2024-03-27 Clément Rey
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