Related papers: General Two-Parameter Model of Alpha-Relaxation in…
On approaching the glass transition, the microscopic kinetic unit spends increasing time rattling in the cage of the first neighbours whereas its average escape time, the structural relaxation time $\tau_\alpha$, increases from a few…
We first review the phenomenology of viscous liquids and the standard models used for explaining the non-Arrhenius average relaxation time. Then the focus is turned to the so-called elastic models, arguing that these models are all…
Molecular-dynamics simulations are presented for two correlation functions formed with the partial density fluctuations of binary hard-sphere mixtures in order to explore the effects of mixing on the evolution of glassy dynamics upon…
The principal theme of this paper is that anomalously slow, super-Arrhenius relaxations in glassy materials may be activated processes involving chains of molecular displacements. As pointed out in a preceding paper with A. Lemaitre, the…
We have performed a detailed dielectric investigation of the relaxational dynamics of glass-forming benzophenone. Our measurements cover a broad frequency range of 0.1 Hz to 120 GHz and temperatures from far below the glass temperature well…
The aim of this paper is to discuss some basic notions regarding generic glass forming systems composed of particles interacting via soft potentials. Excluding explicitly hard-core interaction we discuss the so called `glass transition' in…
The $\alpha$-process (segmental motion) of thin polystyrene films supported on glass substrate has been investigated in a wider frequency range from 10$^{-3}$ Hz to 10$^4$ Hz using dielectric relaxation spectroscopy and thermal expansion…
Specific heat and linear thermal expansivity are fundamental thermal dynamics and have been proven as interesting relaxing quantities to investigate in glass transition and glassy state. However, their possibility has much less been…
To study relaxation dynamics of the two-dimensional XY gauge glass, we integrate directly the equations of motion and investigate the energy function. As usual, it decays exponentially at high temperatures; at low but non-zero temperatures,…
A theory is developed to calculate values of the potential energy barriers to structural relaxation in molecular glass formers from the data of static pair correlation function. The barrier height is shown to increase due to increase in…
We study the high temperature regime within the glass phase of an elastic object with short ranged disorder. In that regime we argue that the scaling functions of any observable are described by a continuum model with a $\delta$-correlated…
Strong changes in bulk properties, such as modulus and viscosity, are observed near the glass transition temperature, T_{g}, of amorphous materials. For more than a century, intense efforts have been made to define a microscopic origin for…
We present Molecular Dynamics simulations of the thermal glass transition in a dense model polymer liquid. We performed a comparative study of both constant volume and constant pressure cooling of the polymer melt. Great emphasis was laid…
Building on the elastically collective nonlinear Langevin equation theory developed for hard spheres in the preceding paper I, we propose and implement a quasi-universal theory for the alpha relaxation of thermal liquids based on mapping…
Glasses feature a broad distribution of relaxation times and activation energies without an obvious characteristic scale. At the same time, macroscopic quantities such as Newtonian viscosity and nonlinear plastic deformation, are…
A recently proposed expression to describe the temperature and volume dependences of the structural (or alpha) relaxation time is discussed. This equation satisfies the scaling law for the relaxation times, tau = f(TV^g), where T is…
We presented that the relaxation of n coupling molecules in a molecular string exhibits n individual relaxation modes (RMs), each mode being characterized by a definite relaxation time and amplitude according to the string model. The n RMs…
We review the recently proposed elastic approach to glass transition. This approach is based on a simple and a physically transparent idea of elastic interactions between local relaxation events in a liquid. Central to this picture is the…
We report an investigation of the heterogeneity in super-cooled liquids and glasses using the non-Gaussianity parameter. We simulate selenium and a binary Lennard-Jones system by molecular dynamics. In the non-Gaussianity three time domains…
Several theories of the glass transition propose that the structural relaxation time {\tau}{\alpha} is controlled by a growing static length scale {\xi} that is determined by the free energy landscape but not by the local dynamical rules…