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Electron transmission through chiral molecules induced by circularly polarized light can be very different for mirror-image structures, a peculiar fact given that the electronic energy spectra of the systems are identical. We propose that…

Chemical Physics · Physics 2009-11-13 Spiros S. Skourtis , David N. Beratan , Ron Naaman , Abraham Nitzan , David H. Waldeck

Photoelectron circular dichroism results from one-photon ionization of chiral molecules by circularly polarized light and manifests itself in forward-backward asymmetry of electron emission in the direction orthogonal to the light…

Atomic Physics · Physics 2019-04-24 Andres F. Ordonez , Olga Smirnova

We study angular momentum radiation from electrically-biased chiral single molecular junctions using the nonequilibrium Green's function method. Using single helical chains as examples, we make connections between the ability of a chiral…

Mesoscale and Nanoscale Physics · Physics 2024-06-13 Bing-Zhong Hu , Zu-Quan Zhang , Lei-Lei Nian , Jing-Tao Lü

Chiral light-matter interactions can enable polarization to control the direction of light emission in a photonic device. Most realizations of chiral light-matter interactions require external magnetic fields to break time-reversal symmetry…

Optics · Physics 2019-07-19 Zhili Yang , Shahriar Aghaeimeibodi , Edo Waks

We consider several fundamental optical phenomena involving single molecules in biased metal-molecule-metal junctions. The molecule is represented by its highest occupied and lowest unoccupied molecular orbitals, and the analysis involves…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Abraham Nitzan

Recent experiments have demonstrated the efficacy of chiral helically shaped molecules in polarizing the scattered electron spin, an effect termed as chiral-induced spin selectivity (CISS). Here we solve a simple tight-binding model for…

Mesoscale and Nanoscale Physics · Physics 2016-02-03 Shlomi Matityahu , Yasuhiro Utsumi , Amnon Aharony , Ora Entin-Wohlman , Carlos A. Balseiro

The interaction of metal-molecule-metal junctions with light is considered within a simple generic model. We show, for the first time, that light induced current in unbiased junctions can take place when the bridging molecule is…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Abraham Nitzan

A theory for light-induced current by strong optical pulses in molecular-tunneling junctions is described. We consider a molecular bridge represented by its highest occupied and lowest unoccupied levels, HOMO and LUMO, respectively. We take…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 B. D. Fainberg , M. Jouravlev , A. Nitzan

Chiral circularly polarized (CP) light is central to many photonic technologies, from optical communication of spin information to novel display and imaging technologies. As such, there has been significant effort in the development of…

Materials Science · Physics 2023-07-25 Li Wan , Yizhou Liu , Matthew J. Fuchter , Binghai Yan

It has been long recognized that the spatial polarization of the electronic clouds in molecules, and the spatial arrangements of atoms into chiral molecular structures, play crucial roles in physics, chemistry and biology. However, these…

Optics · Physics 2020-04-14 David Ayuso , Andres Ordonez , Piero Decleva , Misha Ivanov , Olga Smirnova

Chiral-induced spin selectivity (CISS) is a phenomenon in which electron spins are polarized as they are transported through chiral molecules, and the spin polarization depends on the handedness of the chiral molecule. In this study, we…

Mesoscale and Nanoscale Physics · Physics 2023-02-09 Nguyen Thanh Phuc

Chiral induced spin selectivity is a phenomenon that has been attributed to chirality, spin-orbit interactions, and non-equilibrium conditions, while the role of electron exchange and correlations have been investigated only marginally…

Mesoscale and Nanoscale Physics · Physics 2021-04-28 J. Fransson

We show how a spin polarization can be generated through the photo-induced electron transfer of an achiral donor-acceptor complex following chiral light excitation. In particular, we illustrate the basic energetic and symmetry requirements…

Chemical Physics · Physics 2026-03-10 Sindhana Pannir-Sivajothi , David T. Limmer

We investigate theoretically the polarization properties of the quantum dot's optical emission from chiral photonic crystal structures made of achiral materials in the absence of external magnetic field at room temperature. The mirror…

Propagation of light through a thin flat metallic screen containing a hole of twisted shape is sensitive to whether the incident wave is left or right circularly polarized. The transmitted light accrues a component with handedness opposite…

Materials Science · Physics 2007-05-23 A. V. Krasavin , A. S. Schwanecke , M. Reichelt , T. Stroucken , S. W. Koch , E. M. Wright , N. I. Zheludev

Chirality causes symmetry breaks in a large variety of natural phenomena ranging from particle physics to biochemistry. We investigate one of the simplest conceivable chiral systems, a laser-excited, oriented, effective one-electron Li…

We propose a new type of a chiral metamaterial based on an ensemble of artificial molecules formed by three identical quantum-dots in a triangular arrangement. A static magnetic field oriented perpendicular to the plane breaks mirror…

Mesoscale and Nanoscale Physics · Physics 2014-12-04 Panagiotis Kotetes , Pei-Qing Jin , Michael Marthaler , Gerd Schön

Chirality plays a crucial role in a broad range of processes including light-matter interactions in physics, chemistry and biology, which opens up new applications in nanophotonics, quantum technologies and photochemistry. Quantum…

Optics · Physics 2026-04-10 Yuanyang Xie , Alexey V. Krasavin , Anatoly V. Zayats

Unidirectional (chiral) emission of light from a circular dipole emitter into a waveguide is only possible at points of perfect circular polarisation (C points), with elliptical polarisations yielding a lower directional contrast. However,…

Chirality-induced spin selectivity (CISS) refers to the fact that electrons get spin polarized after passing through organic chiral molecules in a nanoscale device. In CISS, chiral molecules are commonly believed to be a spin filter through…

Mesoscale and Nanoscale Physics · Physics 2022-12-06 Yotam Wolf , Yizhou Liu , Jiewen Xiao , Noejung Park , Binghai Yan
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