Related papers: Revising the Theory of Cross Phenomena
Cross phenomena, representing responses of a system to external stimuli, are ubiquitous from quantum to macro scale. The Onsager theorem is often used to describe them, stating that the coefficient matrix of cross phenomena connecting the…
We present Onsager formalism applied to random networks with arbitrary degree distribution. Using the well-known methods of non-equilibrium thermodynamics we identify thermodynamic forces and their conjugated flows induced in networks as a…
A new formulation of the thermodynamic field theory (TFT) is presented. In this new version, one of the basic restriction in the old theory, namely a closed-form solution for the thermodynamic field strength, has been removed. In addition,…
A decade ago, a macroscopic theory for closure relations has been proposed for systems out of Onsager's region. This theory is referred to as the "Thermodynamic Field Theory" (TFT). The aim of the work was to determine the nonlinear…
The concept of {\it equivalent systems} from the thermodynamic point of view, originally introduced by Th. De Donder and I. Prigogine, is deeply investigated and revised. From our point of view, two systems are thermodynamically equivalent…
The Trajectory Class Fluctuation Theorem (TCFT) substantially strengthens the Second Law of Thermodynamics -- that, in point of fact, can be a rather weak bound on resource fluxes. Practically, it improves empirical estimates of free…
The special composition question (SCQ), which asks under which conditions objects compose a further object, establishes a central debate in modern metaphysics. Recent successes of inductive metaphysics, which studies the implications of the…
The objective of this work is to determine the nonlinear flux-force relations for systems out of Onsager's region that respect the existing thermodynamic theorems for systems far from equilibrium. To this aim, a thermodynamic theory for…
In a thermodynamical process, the dissipation or production of entropy can only be positive or zero according to the second law of thermodynamics. However the laws of thermodynamics are applicable to large systems in the thermodynamic…
The deep problems caused from the limitations of theoretical framework itself can only be clarified by extending and reconstructing of the theoretical framework, we extend classical theoretical framework of thermodynamics, break through the…
First, Second and Combined Laws of Thermodynamics are revised in terms of entropy change, partial entropy, partial volume, and chemical potential.
Thermodynamics is usually developed starting from entropy and the maximum entropy principle. We investigate here to what extent one can replace entropy with relative entropy which has several advantages, for example in the context of local…
We consider viscous, heat conducting mixtures of molecularly miscible chemical species forming a fluid in which the constituents can undergo chemical reactions. Assuming a common temperature for all components, we derive a closed system of…
This review presents a thermodynamic perspective on quantum coupled transport processes in nanoscale systems. Our analysis is formulated within the framework of entropy production rate, the central quantity governing non-equilibrium…
Today's thermodynamics is largely based on the combined law for equilibrium systems and statistical mechanics derived by Gibbs in 1873 and 1901, respectively, while irreversible thermodynamics for nonequilibrium systems resides essentially…
Thermodynamics is a science concerning the state of a system, whether it is stable, metastable, or unstable. The combined law of thermodynamics derived by Gibbs about 150 years ago laid the foundation of thermodynamics. In Gibbs combined…
Since their discovery in 1822, supercritical fluids have been of enduring interest, and have started to be deployed in many important applications. Theoretical understanding of the supercritical state is lacking, and is seen to limit…
This paper is a non-technical, informal presentation of our theory of the second law of thermodynamics as a law that is independent of statistical mechanics and that is derivable solely from certain simple assumptions about adiabatic…
The combined law of thermodynamics derived by Gibbs laid the foundation of thermodynamics though only applicable to systems without internal processes. Gibbs further derived the classical statistical thermodynamics in terms of the…
We present a new derivation of the proof for the TCP/CPT Theorem using the Dynamical Principle and Variation of Action methods first defined by Schwinger in 1951. This new proof will significantly extend the TCP Theorem beyond the original…