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We introduce several improvements to the penalty-based variational quantum Monte Carlo (VMC) algorithm for computing electronic excited states of Entwistle $\textit{et al.}$ [M. T. Entwistle $\textit{et al.}$, Nat. Commun. $\textbf{14}$,…

Chemical Physics · Physics 2024-09-23 P. Bernát Szabó , Zeno Schätzle , Mike T. Entwistle , Frank Noé

We introduce a variational manifold of simple tensor network states for the study of a family of constrained models that describe spin-1/2 systems as realized by Rydberg atom arrays. Our manifold permits analytical calculation via…

Quantum Physics · Physics 2024-05-13 Joey Li , Giuliano Giudici , Hannes Pichler

Preparing quantum many-body states on classical or quantum devices is a very challenging task that requires accounting for exponentially large Hilbert spaces. Although this complexity can be managed with exponential ans\"atze (such as in…

Quantum Physics · Physics 2024-11-13 Weillei Zeng , Jiaji Zhang , Lipeng Chen , Carlos L. Benavides-Riveros

Computing Gaussian ground states via variational optimization is challenging because the covariance matrices must satisfy the uncertainty principle, rendering constrained or Riemannian optimization costly, delicate, and thus difficult to…

Quantum Physics · Physics 2026-01-29 Christopher Willby , Tomohiro Hashizume , Jason Crain , Dieter Jaksch

We conduct experimental simulations of many body quantum systems using a \emph{hybrid} classical-quantum algorithm. In our setup, the wave function of the transverse field quantum Ising model is represented by a restricted Boltzmann…

Quantum Physics · Physics 2018-12-05 Bartłomiej Gardas , Marek M. Rams , Jacek Dziarmaga

Besides perturbation theory (which clearly requires the knowledge of the exact unperturbed solution), variational techniques represent the main tool for any investigation of the eigenvalue problem of some semibounded operator H in quantum…

High Energy Physics - Phenomenology · Physics 2009-10-31 Wolfgang Lucha , Franz F. Schoberl

Neural-network quantum states (NQS) employ artificial neural networks to encode many-body wave functions in second quantization through variational Monte Carlo (VMC). They have recently been applied to accurately describe electronic wave…

Chemical Physics · Physics 2023-11-27 Xiang Li , Jia-Cheng Huang , Guang-Ze Zhang , Hao-En Li , Chang-su Cao , Dingshun Lv , Han-Shi Hu

Variational quantum algorithms are poised to have significant impact on high-dimensional optimization, with applications in classical combinatorics, quantum chemistry, and condensed matter. Nevertheless, the optimization landscape of these…

Quantum Physics · Physics 2022-02-02 Taylor L. Patti , Omar Shehab , Khadijeh Najafi , Susanne F. Yelin

Attention is focused on antisymmetrized versions of quantum spaces that are of particular importance in physics, i.e. two-dimensional quantum plane, q-deformed Euclidean space in three or four dimensions as well as q-deformed Minkowski…

High Energy Physics - Theory · Physics 2014-11-18 Dzo Mikulovic , Alexander Schmidt , Hartmut Wachter

Neural network parametrizations have increasingly been used to represent the ground and excited states in variational Monte Carlo (VMC) with promising results. However, traditional VMC methods only optimize the wave function in regions of…

Computational Physics · Physics 2025-07-03 Huan Zhang , Robert J. Webber , Michael Lindsey , Timothy C. Berkelbach , Jonathan Weare

We reformulate the projected imaginary-time evolution of Full Configuration Interaction Quantum Monte Carlo in terms of a Lagrangian minimization. This naturally leads to the admission of polynomial complex wavefunction parameterizations,…

Strongly Correlated Electrons · Physics 2017-05-03 Lauretta R. Schwarz , A. Alavi , George H. Booth

Neural quantum states (NQSs) are powerful variational ans\"atze capable of representing highly entangled quantum many-body wavefunctions. While the average entanglement properties of ensembles of restricted Boltzmann machines are well…

Quantum Physics · Physics 2026-02-11 Andrew Jreissaty , Hang Zhang , Jairo C. Quijano , Juan Carrasquilla , Roeland Wiersema

An intrinsic measure of the quality of a variational wave function is given by its overlap with the ground state of the system. We derive a general formula to compute this overlap when quantum dynamics in imaginary time is accessible. The…

Statistical Mechanics · Physics 2007-07-26 Christophe Mora , Xavier Waintal

The essence of atomic structure theory, quantum chemistry, and computational materials science is solving the multi-electron stationary Schr\"odinger equation. The Quantum Monte Carlo-based neural network wave function method has surpassed…

Atomic Physics · Physics 2023-12-27 JinDe Liu , Chenglong Qin , Xi He , Gang Jiang

To calculate excited states in quantum many-body systems, multi-configuration mixing has often been employed. However, it has been still unclear how to choose important Slater determinants from a huge model space. We propose a novel…

Nuclear Theory · Physics 2022-03-02 Takatoshi Ichikawa , Naoyuki Itagaki

Large language models, like transformers, have recently demonstrated immense powers in text and image generation. This success is driven by the ability to capture long-range correlations between elements in a sequence. The same feature…

Quantum Physics · Physics 2024-03-19 Kyle Sprague , Stefanie Czischek

We present in detail the recently developed multi-configurational symmetrized projector quantum Monte Carlo (MSPQMC) method for excited states of the Hubbard model. We describe the implementation of the Monte Carlo method for a…

Condensed Matter · Physics 2009-10-28 Bhargavi Srinivasan , S. Ramasesha , H. R. Krishnamurthy

We present a multi-reference configuration mixing scheme for describing ground and excited states, with well defined spin and space group symmetry quantum numbers, of the one-dimensional Hubbard model with nearest-neighbor hopping and…

Strongly Correlated Electrons · Physics 2013-06-28 R. Rodríguez-Guzmán , Carlos A. Jiménez-Hoyos , R. Schutski , Gustavo E. Scuseria

A new computational method for finite-temperature properties of strongly correlated electrons is proposed by extending the variational Monte Carlo method originally developed for the ground state. The method is based on the path integral in…

Strongly Correlated Electrons · Physics 2016-06-10 Kensaku Takai , Kota Ido , Takahiro Misawa , Youhei Yamaji , Masatoshi Imada

The representation of a quantum wave function as a neural network quantum state (NQS) provides a powerful variational ansatz for finding the ground states of many-body quantum systems. Nevertheless, due to the complex variational landscape,…

Quantum Physics · Physics 2023-12-06 Eimantas Ledinauskas , Egidijus Anisimovas
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