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Using density functional theory, we investigate fluctuations of the ground state energy of spin-polarized, disordered quantum dots in the metallic regime. To compare to experiment, we evaluate the distribution of addition energies and find…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 K. Hirose , F. Zhou , N. Wingreen

We present the basic concepts and our recent developments in the density functional approaches with the Skyrme functionals for describing nuclear dynamics at low energy. The time-dependent density-functional theory (TDDFT) is utilized for…

Nuclear Theory · Physics 2013-10-16 Takashi Nakatsukasa

We present a method to constrain local charge multipoles within density-functional theory. Such multipoles quantify the anisotropy of the local charge distribution around atomic sites and can indicate potential hidden orders. Our method…

One of the greatest challenges when designing new technologies that make use of non-trivial quantum materials is the difficulty associated with predicting material-specific properties, such as critical temperature, gap parameter, etc. There…

Superconductivity · Physics 2025-03-24 Adrian D. Scheppe , Michael V. Pak

Energy density functional (EDF) theory provides a unified framework for the description of nuclei and of infinite nuclear matter. In principle, it facilitates direct connections between nuclear data and the nuclear equation of state (EoS).…

Nuclear Theory · Physics 2025-12-01 Panagiota Papakonstantinou

The density-functional (DF) theory provides a simple method for calculating the properties of an interacting system under an external potential by associating it with a corresponding non-interacting system. Here, we find some relations in…

Chemical Physics · Physics 2009-11-10 Junzo Chihara , Mitsuru Yamagiwa

It was recently shown [Y. Suzuki, L. Lacombe, K. Watanabe, and N. T. Maitra, Phys. Rev. Lett. 119, 263401 (2017)] that peak and valley structures in the exact exchange-correlation potential of time-dependent density functional theory are…

Chemical Physics · Physics 2018-07-04 Lionel Lacombe , Yasumitsu Suzuki , Kazuyuki Watanabe , Neepa T. Maitra

Embedded density functional theory (e-DFT) is used to describe the electronic structure of strongly interacting molecular subsystems. We present a general implementation of the Exact Embedding (EE) method [J. Chem. Phys. 133, 084103 (2010)]…

Other Condensed Matter · Physics 2011-07-27 Jason D. Goodpaster , Taylor A. Barnes , Thomas F. Miller

The systematic investigation of the ground state and fission properties of even-even actinides and superheavy nuclei with $Z=90-120$ from the two-proton up to two-neutron drip lines with proper assessment of systematic theoretical…

Nuclear Theory · Physics 2021-03-09 A. Taninah , S. E. Agbemava , A. V. Afanasjev

Ensemble density functional theory (eDFT) is an exact time-independent alternative to time-dependent DFT (TD-DFT) for the calculation of excitation energies. Despite its formal simplicity and advantages in contrast to TD-DFT (multiple…

Strongly Correlated Electrons · Physics 2017-01-19 Killian Deur , Laurent Mazouin , Emmanuel Fromager

We review an approach where the energy functional of Density-Functional Theory (DFT) can be determined without empiricism via a Quantum Monte Carlo (QMC) procedure. The idea consists of a nested iterative loop where the configurational…

Strongly Correlated Electrons · Physics 2017-11-22 Luigi Delle Site

Configuration mixing calculations performed in terms of the Skyrme/Gogny Energy Density Functional (EDF) rely on extending the Single-Reference energy functional into non-diagonal EDF kernels. The standard way to do so, based on an analogy…

Nuclear Theory · Physics 2009-12-17 Denis Lacroix , Michael Bender , Thomas Duguet

The electric dipole (E1) strength functions have been systematically calculated based on the time-dependent density functional theory (TDDFT), using the finite amplitude method and the real-time approach to the TDDFT with pairing…

Nuclear Theory · Physics 2017-08-23 Shuichiro Ebata , Tsunenori Inakura , Takashi Nakatsukasa

We show that using complex, spin-restricted orbitals (cR) in Kohn-Sham density functional theory (KS-DFT) allows one to access a new class of densities that is not accessible by either spin-restricted (RKS) or spin-unrestricted (UKS)…

Chemical Physics · Physics 2019-09-13 Joonho Lee , Luke W. Bertels , Martin Head-Gordon

The theory of the nuclear energy-density functional is used to provide a unified and thermodynamically consistent treatment of all regions of cold non-accreting neutron stars. In order to assess the impact of our lack of complete knowledge…

High Energy Astrophysical Phenomena · Physics 2020-01-28 J. M. Pearson , N. Chamel , A. Y. Potekhin , A. F. Fantina , C. Ducoin , A. K. Dutta , S. Goriely

We study the density estimation problem with observations generated by certain dynamical systems that admit a unique underlying invariant Lebesgue density. Observations drawn from dynamical systems are not independent and moreover, usual…

Machine Learning · Statistics 2016-07-14 Hanyuan Hang , Ingo Steinwart , Yunlong Feng , Johan A. K. Suykens

We propose a local real-space formulation for orbital-free DFT with density dependent kinetic energy functionals and a unified variational framework for computing the configurational forces associated with geometry optimization of both…

Materials Science · Physics 2015-06-15 Sambit Das , Mrinal Iyer , Vikram Gavini

Degenerate perturbation theory from quantum mechanics is inadequate in density functional theory (DFT) because of nonlinearity in the Kohn-Sham potential. Herein, we develop the fully general perturbation theory for open-shell, degenerate…

Materials Science · Physics 2017-07-19 Mark C. Palenik , Brett I. Dunlap

We prove that the electron density function of a real physical system can be uniquely determined by its values on any finite subsystem. This establishes the existence of a rigorous density-functional theory for any open electronic system.…

Quantum Physics · Physics 2007-05-23 Xiao Zheng , Fan Wang , GuanHua Chen

Accurate first-principles calculations for the energies, charge distributions, and spin symmetries of many-electron systems are essential to understand and predict the electronic and structural properties of molecules and materials.…

Chemical Physics · Physics 2024-01-24 Yuming Shi , Yi Shi , Adam Wasserman
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