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Static and dynamic structure factors and various transport coefficients are computed for a Lennard-Jones model of a binary fluid (A,B) with a symmetrical miscibility gap, varying both temperature and relative concentration of the mixture.…

Statistical Mechanics · Physics 2009-11-10 Subir K. Das , Jürgen Horbach , Kurt Binder

We study the structure and morphological changes of fluids that are in contact with solid composites formed by alternating and microscopically wide stripes of two different materials. One type of the stripes interacts with the fluid via…

Statistical Mechanics · Physics 2019-12-30 Martin Pospíšil , Martin Láska , Alexandr Malijevský

The electrostatic interaction between two non-identical, moderately charged colloids situated in close proximity of each other at a fluid interface is studied. By resorting to a well-justified model system, this problem is analytically…

Soft Condensed Matter · Physics 2018-04-30 Arghya Majee , Timo Schmetzer , Markus Bier

A recently proposed rational-function approximation [Phys. Rev. E \textbf{84}, 041201 (2011)] for the structural properties of nonadditive hard spheres is applied to evaluate analytically (in Laplace space) the local density profiles of…

Soft Condensed Matter · Physics 2013-04-08 Riccardo Fantoni , Andrés Santos

We argue in favour of developing a comprehensive dynamical theory for rationalizing, predicting, designing, and machine learning nonequilibrium phenomena that occur in soft matter. To give guidance for navigating the theoretical and…

Soft Condensed Matter · Physics 2024-02-28 Daniel de las Heras , Toni Zimmermann , Florian Sammüller , Sophie Hermann , Matthias Schmidt

We present a theoretical study of wetting phenomena and interactions between liquid-vapor interfaces based on the density functional theory. The focus is mostly on the impact of long-range van der Waals interactions both within the fluid…

Chemical Physics · Physics 2011-11-10 Arik Yochelis , Len M. Pismen

An extension of the Asakura-Oosawa-Vrij model of hard sphere colloids and non-adsorbing polymers, that takes polymer non-ideality into account through a repulsive stepfunction pair potential between polymers, is studied with grand canonical…

Soft Condensed Matter · Physics 2007-05-23 R. L. C. Vink , M. Schmidt

Macroscopic models of nucleation provide powerful tools for understanding activated phase transition processes. These models do not provide atomistic insights and can thus sometime lack material-specific descriptions. Here we provide a…

Statistical Mechanics · Physics 2020-02-19 Bingqing Cheng , Michele Ceriotti , Gareth A. Tribello

Solvent-mediated interactions emerge from complex mechanisms that depend on the solute structure, its wetting properties and the nature of the liquid. While numerous studies have focused on the two first influences, here, we compare results…

Soft Condensed Matter · Physics 2018-10-17 Julien Lam , James F. Lutsko

Density functional theory is used to study colloidal hard-rod fluids near an individual right-angled wedge or edge as well as near a hard wall which is periodically patterned with rectangular barriers. The Zwanzig model, in which the…

Soft Condensed Matter · Physics 2009-11-10 L. Harnau , F. Penna , S. Dietrich

In this paper we use molecular dynamics (MD) to answer a classical question: how does the surface tension on a liquid/gas interface appear? After defining surface tension from the first principles and performing several consistency checks,…

Soft Condensed Matter · Physics 2013-10-24 Alex Lukyanov , Alexei Likhtman

A novel mechanical approach is developed to explore by means of atom-scale simulation the concept of line tension at a solid-liquid-vapor contact line as well as its dependence on temperature, confinement, and solid/fluid interactions. More…

Mesoscale and Nanoscale Physics · Physics 2020-03-18 Romain Bey , Benoit Coasne , Cyril Picard

A system of soft ellipsoid molecules confined between two planar walls is studied using classical Density Functional Theory (DFT). Both the isotropic and nematic phases are considered. The excess free energy is evaluated using two different…

Materials Science · Physics 2009-11-10 David Cheung , Friederike Schmid

We study various manifestations of structural crossover in the properties of a binary mixture of hard-spheres. For homogeneous mixtures that are sufficiently asymmetric, there is a crossover line in the phase diagram such that for…

Soft Condensed Matter · Physics 2009-11-11 C. Grodon , M. Dijkstra , R. Evans , R. Roth

Determining the microstructure of colloidal suspensions under shear flows has been a challenge for theoretical and computational methods due to the singularly-perturbed boundary-layer nature of the problem. Previous approaches have been…

Soft Condensed Matter · Physics 2019-06-05 L. Banetta , A. Zaccone

Noncovalent van der Waals (vdW) interactions are responsible for a wide range of phenomena in matter. Popular density-functional methods that treat vdW interactions use disparate physical models for these intricate forces, and as a result…

Materials Science · Physics 2020-04-15 Jan Hermann , Alexandre Tkatchenko

A binary mixture of particles interacting with spherically-symmetric potentials leading to microsegregation is studied by theory and molecular dynamics (MD) simulations. We consider spherical particles with equal diameters and volume…

Soft Condensed Matter · Physics 2020-11-20 O. Patsahan , M. Litniewski , A. Ciach

Molecular dynamics simulations of miscible and partially miscible binary Lennard--Jones mixtures are used to study the dynamics and thermodynamics of vapor condensation onto a non-volatile liquid drop in the canonical ensemble. When the…

Soft Condensed Matter · Physics 2015-06-17 Levent Inci , Richard. K. Bowles

In this continuum theory, we propose a mathematical framework to study the mechanical interplay of bulk-surfaces materials undergoing deformation and phase segregation. To this end, we devise a principle of virtual powers with a…

Fluid Dynamics · Physics 2024-01-19 Anne Boschman , Luis Espath , Kris van der Zee

We study the settling of solid particles within a viscous incompressible fluid contained in a two-dimensional channel, where the mass density of the particles is slightly greater than that of the fluid. The fluid-structure interaction…

Fluid Dynamics · Physics 2015-09-07 Sudeshna Ghosh , John M. Stockie