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Li-CO$_2$ batteries are promising energy storage systems due to their high theoretical energy density and CO$_2$ fixation capability, relying on reversible Li$_2$CO$_3$/C formation during discharge/charge cycles. We present a multiscale…

Advances in lithium-metal anodes have inspired interest in discovery of Li-free cathodes, most of which are natively found in their charged state. This is in contrast to today's commercial lithium-ion battery cathodes, which are more stable…

Materials Science · Physics 2024-09-12 Haoming Howard Li , Qian Chen , Gerbrand Ceder , Kristin A. Persson

Use of electrode materials that show phase change behavior and hence drastic changes in electrochemical activity during operation, have not been explored for Li-ion batteries. Here we demonstrate the vanadium oxide (VO2) cathode that…

Interfaces are ubiquitous in Li-ion battery electrodes, occurring across compositional gradients, regions of multiphase intergrowths, and between electrodes and solid electrolyte interphases or protective coatings. However, the impact of…

Materials Science · Physics 2017-04-05 Shenzhen Xu , Ryan Jacobs , Chris Wolverton , Thomas Kuech , Dane Morgan

The polyanionic compound Na2MnSiO4 is regarded as one of the promising cathode materials for Na-ion batteries due to good specific capacity with its attractive prospect of utilization of two electrons in the redox processes. So, in this…

Materials Science · Physics 2021-10-19 Vishnu Sudarsanan , Anu Maria Augustine , P Ravindran

Sodium-titanate \ce{Na2Ti3O7} (NTO) is regarded as a highly promising anode material with a very low voltage for Na-ion batteries and capacitors, but suffered from relatively low specific capacity and poor electron conductivity. Here we…

Materials Science · Physics 2020-06-19 Chol-Jun Yu , Suk-Gyong Hwang , Yong-Chol Pak , Song-Hyok Choe , Jin-Song Kim , Kum-Chol Ri

The open circuit voltage Voc and the corresponding charge carrier density were measured in dependence of temperature and illumination intensity by current-voltage and charge extraction measurements for P3HT:PCBM and P3HT:bisPCBM solar…

Materials Science · Physics 2011-10-05 Daniel Rauh , Alexander Wagenpfahl , Carsten Deibel , Vladimir Dyakonov

Owing to the trade-off between the accuracy and efficiency, machine-learning-potentials (MLPs) have been widely applied in the battery materials science, enabling atomic-level dynamics description for various critical processes. However,…

Modern energy applications, especially electric vehicles, demand high energy batteries. However, despite decades of intensive efforts, the highest energy density and commercially viable batteries are still based on LiCoO2, the very first…

Under open-circuit condition, the current is not extracted and the photogenerated carriers in principle disappear only by recombination. We study the open-circuit voltage $V_{\rm OC}$ and transient photovoltage under the effect of bulk…

Materials Science · Physics 2014-01-03 Kazuhiko Seki , Kazuhiro Marumoto , M. Tachiya

LixTMO2 (TM=Ni, Co, Mn) forms an important family of cathode materials for Li-ion batteries, whose performance is strongly governed by Li composition-dependent crystal structure and phase stability. Here, we use LixCoO2 (LCO) as a model…

Computational Engineering, Finance, and Science · Computer Science 2023-02-20 G. H. Teichert , S. Das , M. Faghih Shojaei , J. Holber , T. Mueller , L. Hung , V. Gavini , K. Garikipati

Batteries are critical for electrified transportation and aviation, yet thermodynamic understanding of electrode materials remains lacking, as indicated by the often-seen violation of the second law of thermodynamics of open-circuit voltage…

Chemical Physics · Physics 2025-07-16 Archie Mingze Yao , Amal Sebastian , Venkatasubramaian Viswanathan

The design of novel cathode materials for Li-ion batteries would greatly benefit from accurate first-principles predictions of structural, electronic, and magnetic properties as well as intercalation voltages in compounds containing…

Materials Science · Physics 2022-11-03 Iurii Timrov , Francesco Aquilante , Matteo Cococcioni , Nicola Marzari

Sodium-ion batteries have gained much interest over the past years and especially layered oxides are highly considered as cathodes for the next generation of batteries. However, there are still significant challenges to overcome in these…

Materials Science · Physics 2025-12-09 Konstantin Köster , Payam Kaghazchi

The influences of work function of transparent conducting oxides (TCO) on the per-formance of organic solar cells, including open circuit voltage, conversion efficiency and fill factor, has been simulated. It is obtained that for non-Ohmic…

Instrumentation and Detectors · Physics 2016-05-31 Aqing Chen , Kaigui Zhu , Qingyi Shao , Zhenguo Ji

We present a computational microscopy analysis (targeted molecular dynamics simulations) of the structure and performance of conductive metal organic framework (MOF) electrodes in supercapacitors with room temperature ionic liquids. The…

Materials Science · Physics 2020-02-24 Sheng Bi , Ming Chen , Runxi Wang , Jiamao Feng , Mircea Dinca , Alexei A. Kornyshev , Guang Feng

The key challenge in advancing multivalent-ion batteries lies in finding suitable intercalation hosts. Open-tunnel oxides, featuring one-dimensional channels or nanopores, show promise for enabling effective ion transport. However, the vast…

Materials Science · Physics 2024-10-10 Joy Datta , Dibakar Datta , Amruth Nadimpally , Nikhil Koratkar

We present a multiscale simulation framework to compute the current vs. voltage (I-V ) characteristics of metal/oxide/metal structures building the core of conductive bridging random access memory (CBRAM) cells and to shed light on their…

Under the dual background of deep adjustment of global energy pattern and severe challenges of environmental problems, solid oxide fuel cell (SOFC) has become the focus of research on efficient and clean energy conversion technology due to…

Applied Physics · Physics 2025-11-04 Wang Hao , Xie Jiamiao , Hao Wenqian , Li Jingyang , Zhang Peng , Ma Xiaofan , Liu Fu , Wang Xu

Upon insertion and extraction of lithium, materials important for electrochemical energy storage can undergo changes in thermal conductivity (${\Lambda}$) and elastic modulus ($\it M$). These changes are attributed to evolution of the…

Applied Physics · Physics 2022-01-10 Jungwoo Shin , Sanghyeon Kim , Hoonkee Park , Ho Won Jang , David G. Cahill , Paul V. Braun