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Pairing the accuracy of Kohn-Sham density-functional framework with the efficiency of a stochastic algorithmic approach, mixed stochastic-deterministic Density Functional Theory (mDFT) achieves a favorable computational scaling with system…

Chemical Physics · Physics 2025-10-07 Vidushi Sharma , Lee A. Collins , Alexander J. White

Recent advances using Density Functional Theory (DFT) to augment Multiplet Ligand Field Theory (MLFT) have led to ab-initio calculations of many formerly empirical parameters. This development makes MLFT more predictive instead of…

Strongly Correlated Electrons · Physics 2023-05-01 Charles Cardot , Joshua Kas , Jared Abramson , John Rehr , Gerald T. Seidler

Even though quantum chromodynamics is a broken conformal theory, the AdS/CFT correspondence has led to important insights into the properties of QCD. For example, as shown by Polchinski and Strassler, dimensional counting rules for the…

High Energy Physics - Phenomenology · Physics 2009-09-11 Stanley J. Brodsky , Guy F. de Teramond

We have integrated density functional theory (DFT) into quantitative convergent-beam electron diffraction (QCBED) to create a synergy between experiment and theory called QCBED-DFT. This synergy resides entirely in the electron density…

Strongly Correlated Electrons · Physics 2021-05-05 Ding Peng , Philip N. H. Nakashima

We develop a new theoretical framework for describing light-matter interactions in cavity quantum electrodynamics (QED), optimized for efficient convergence at arbitrarily strong coupling strengths and is naturally applicable to…

Quantum Physics · Physics 2023-11-16 Michael A. D. Taylor , Braden M. Weight , Pengfei Huo3

We show that the analytic structure of the dynamical xc kernels of semiconductors and insulators can be sensed in terms of its poles which mark physically relevant frequencies of the system where the counter-phase motion of discrete…

Materials Science · Physics 2023-04-19 D. R. Gulevich , Ya. V. Zhumagulov , V. Kozin , I. V. Tokatly

We present a new ab initio approach to study molecules containing heavy atoms strongly interacting with quantum fields in optical devices. The theory has been derived from the relativistic quantum electrodynamics (QED) introducing the…

Chemical Physics · Physics 2025-07-03 Guillaume Thiam , Riccardo Rossi , Henrik Koch , Leonardo Belpassi , Enrico Ronca

We discuss dynamical response functions near quantum critical points, allowing for both a finite temperature and detuning by a relevant operator. When the quantum critical point is described by a conformal field theory (CFT), conformal…

High Energy Physics - Theory · Physics 2017-08-03 Andrew Lucas , Todd Sierens , William Witczak-Krempa

QCDFT is a multiscale modeling approach that can simulate multi-million atoms effectively via density functional theory (DFT). The method is based on the framework of quasicontinuum (QC) approach with DFT as its sole energetics formulation.…

Mesoscale and Nanoscale Physics · Physics 2011-05-20 Qing Peng , Xu Zhang , Gang Lu

The role of nuclear quantum effects on the adsorption of molecular hydrogen in metal-organic frameworks (MOFs) has been investigated on grounds of Grand-Canonical Quantized Liquid Density-Functional Theory (GC-QLDFT) calculations. For this…

Chemical Physics · Physics 2015-06-22 Mohammad Wahiduzzaman , Christian F. J. Walther , Thomas Heine

This chapter presents the development of a density functional theory (DFT)-based method for accurate, reliable treatment of various resonances in atoms. Many of these are known to be notorious for their strong correlation, proximity to more…

Chemical Physics · Physics 2019-04-19 Amlan K. Roy

Background: Nuclear excited states within a wide range of excitation energies are formally described by the linear response theory. Besides its conventional formulation within the quasiparticle random phase approximation (QRPA) representing…

Nuclear Theory · Physics 2015-06-23 Elena Litvinova

The particle-hole interaction problem is longstanding within time-dependent density functional theory (TDDFT) and leads to extreme errors in the prediction of K-edge X-ray absorption spectra (XAS). We derive a linear-response formalism that…

Chemical Physics · Physics 2022-10-18 Kevin Carter-Fenk , Leonardo A. Cunha , Juan E. Arias-Martinez , Martin Head-Gordon

Multiconfigurational short-range density functional theory (MC-srDFT) rigorously combines ground state wavefunction theory with DFT. Unlike single-reference range-separated hybrid functionals, MC-srDFT has lacked theoretically grounded…

Chemical Physics · Physics 2026-03-05 Michał Hapka , Katarzyna Pernal , Ewa Pastorczak

Excitonic effects in the optical absorption spectra of solids can be described with time-dependent density-functional theory (TDDFT) in the linear-response regime, using a simple class of approximate, long-range corrected (LRC)…

Materials Science · Physics 2025-04-10 Jared R. Williams , Carsten A. Ullrich

Ensemble density functional theory (EDFT) is a promising alternative to time-dependent density functional theory for computing electronic excitation energies. Using coordinate scaling, we prove several fundamental exact conditions in EDFT…

Strongly Correlated Electrons · Physics 2023-07-04 Thais R. Scott , John Kozlowski , Steven Crisostomo , Aurora Pribram-Jones , Kieron Burke

We present a density-functional theory (DFT) approach to the study of the phase diagram of the maximum density droplet (MDD) in two-dimensional quantum dots in a magnetic field. Within the lowest Landau level (LLL) approximation, analytical…

Mesoscale and Nanoscale Physics · Physics 2009-10-30 M. Ferconi , G. Vignale

An approximate method based on adiabatic time dependent density functional theory (TDDFT) is presented, that allows for the description of the electron dynamics in nanoscale junctions under arbitrary time dependent external potentials. In…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 Y. Wang , C. -Y. Yam , G. H. Chen , Th. Frauenheim , T. A. Niehaus

An explicit expression for the quadratic density-response function of a many-electron system is obtained in the framework of the time-dependent density-functional theory, in terms of the linear and quadratic density-response functions of…

Materials Science · Physics 2009-11-10 V. U. Nazarov , J. M. Pitarke , C. S. Kim , Y. Takada

Response functions are key observables for probing the structure and dynamics of many-body systems. We introduce and demonstrate a quantum-classical framework for computing response functions of general many-fermion systems that also…

Quantum Physics · Physics 2026-02-10 Weijie Du , Yangguang Yang , Zixin Liu , Chao Yang , James P. Vary