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Artificial electrostatic potentials can be present in supercells constructed for atomistic simulations of surfaces and interfaces in ionic crystals. Treating the ions as point charges, we systematically derive an electrostatic formalism for…

Materials Science · Physics 2022-06-02 Cong Tao , Daniel Mutter , Daniel F. Urban , Christian Elsässer

Neutral particles in the plasma edge of fusion devices based on magnetic confinement are described by a transient kinetic equation incorporating ionization, recombination, and charge-exchange collisions. In charge-exchange dominated…

Plasma Physics · Physics 2023-06-29 Vince Maes , Wouter Dekeyser , Julian Koellermeier , Martine Baelmans , Giovanni Samaey

Porous flow-through electrodes are used as the core reactive component across electrochemical technologies. Controlling the fluid flow, species transport, and reactive environment is critical to attaining high performance. However,…

An exact Quantum Kinetic Monte Carlo method is proposed to calculate electron transport for 1D Fermi Hubbard model. The method is directly formulated in real time and can be applied to extract time dependent dynamics of general interacting…

Materials Science · Physics 2018-05-07 Fei Lin , Jianqiu Huang , Celine Hin

Viscous electron fluids have emerged recently as a new paradigm of strongly-correlated electron transport in solids. Here we report on a direct observation of the transition to this long-sought-for state of matter in a high-mobility…

Quantum impurity models describe an atom or molecule embedded in a host material with which it can exchange electrons. They are basic to nanoscience as representations of quantum dots and molecular conductors and play an increasingly…

Strongly Correlated Electrons · Physics 2011-05-09 Emanuel Gull , Andrew J. Millis , Alexander I. Lichtenstein , Alexey N. Rubtsov , Matthias Troyer , Philipp Werner

We consider two charged semipermeable membranes, which bound bulk electrolyte solutions and are separated by a thin film of salt-free liquid. Small counter-ions permeate into the gap, which leads to a steric charge separation in the system.…

Soft Condensed Matter · Physics 2016-11-23 Salim R. Maduar , Olga I. Vinogradova

Conducting Polymer Dendrites (CPD) are truly inspiring for unconventional electronics that shapes topological circuitries evolving upon an application. Driven by electrochemical processes, an electrochemical impedance rules signal…

Applied Physics · Physics 2024-07-02 Antoine Baron , Enrique Hernández-Balaguera , Sébastien Pecqueur

A superconducting qubit device suitable for interacting with a flying electron has recently been proposed [H. Okamoto and Y. Nagatani, Appl. Phys. Lett. \textbf{104}, 062604 (2014)]. Either a clockwise or counter clockwise directed loop of…

Quantum Physics · Physics 2018-04-30 Hiroshi Okamoto

We report on resistive switching of memristive electrochemical metallization devices using 3D kinetic Monte Carlo simulations describing the transport of ions through a solid state electrolyte of an Ag/TiO$_{\text{x}}$/Pt thin layer system.…

Materials Science · Physics 2017-06-06 Sven Dirkmann , Thomas Mussenbrock

In this paper we report a semianalytical model of the mass transfer impedance in microfluidic electrochemical chips (MEC). It is based on the molar advection diffusion equation in a microfluidic channel with a Poiseuille flow and an…

Chemical Physics · Physics 2022-10-18 Stéphane Chevalier , Marine Garcia , Alain Sommier , Jean-Christophe Batsale

This work inspects the thermally activated transfer of solute particles across the interface between two interstitial solid solution phases that equilibrate internally by fast diffusion on conserved arrays of sites. When each phase is…

Materials Science · Physics 2026-01-30 Jörg Weissmüller

This study presents a Monte Carlo simulation tool for modeling the transportation processes of thermal electrons in noble liquids, specifically focusing on liquid argon and liquid xenon. The study aims to elucidate the microscopical…

High Energy Physics - Experiment · Physics 2024-03-22 Yijun Xie , Yi Wang

We present the theory and implementation of a Poisson-Boltzmann implicit solvation model for electrolyte solutions. This model can be combined with arbitrary electronic structure methods that provide an accurate charge density of the…

Computational Physics · Physics 2020-01-08 Christopher J. Stein , John M. Herbert , Martin Head-Gordon

The ion distribution of electrolytes near interfaces with dielectric contrast has important consequences for electrochemical processes and many other applications. To date, most studies of such systems have focused on geometrically simple…

Soft Condensed Matter · Physics 2018-11-14 Huanxin Wu , Honghao Li , Francisco J. Solis , Monica Olvera de la Cruz , Erik Luijten

We have used molecular simulation and methods of importance sampling to study the thermodynamics and kinetics of ionic charge separation at a liquid water-metal interface. We have considered this process using canonical examples of two…

Chemical Physics · Physics 2022-06-08 John A. Kattirtzi , David T. Limmer , Adam P. Willard

We investigate electro-osmosis in aqueous solutions of polyelectrolytes using mean-field equations. A solution of positively charged polyelectrolytes is confined between two negatively charged planar surfaces, and an electric field is…

Soft Condensed Matter · Physics 2015-06-16 Yuki Uematsu , Takeaki Araki

Improvement of electrochemical technologies is one of the most popular topics in the field of renewable energy. However, this process requires a deep understanding of the electrode electrolyte interface behavior under operando conditions.…

Understanding the electrodes' surface morphology influence on the ions' distribution is essential for designing the supercapacitors with enhanced energy density characteristics. We develop a model for the structure of electrolytes near the…

Statistical Mechanics · Physics 2021-06-30 Timur Aslyamov , Konstantin Sinkov , Iskander Akhatov

Inclusive electron scattering off 4He is investigated for low and medium energy and momentum transfers. The final state interaction, given by the simple semirealistic Malfliet-Tjon potential, is treated rigorously applying the Lorentz…

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