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Trapping macromolecules is impoartant for the study of their conformations, interactions, dynamics and kinetic processes. Here, we develop a variational approach which self-consistently introduces a mean force that controls the…

Soft Condensed Matter · Physics 2024-04-23 Luofu Liu , Chao Duan , Rui Wang

In this paper we apply variational energy band theory to a form of the Holstein Hamiltonian in which the influence of lattice vibrations (optical phonons) on both local site energies (local coupling) and transfers of electronic excitations…

Condensed Matter · Physics 2009-10-28 Yang Zhao , David W. Brown , Katja Lindenberg

We present a first-principles framework to investigate the electron scattering channels and transport properties for polar material by combining the exact solution of linearized electron-phonon (e-ph) Boltzmann transport equation in its…

Materials Science · Physics 2017-02-22 Te-Huan Liu , Jiawei Zhou , Bolin Liao , David J. Singh , Gang Chen

We investigate the impact of the quantized mechanical motion of optically trapped atoms, arranged in proximity to a one-dimensional waveguide, on the propagation of polariton modes. Our study identifies a regime of resonant phonon-assisted…

Quantum Gases · Physics 2024-11-28 Denis Ilin , Alexander S. Solntsev , Ivan Iorsh

Polaron formation in pump-probe experiments is an inherently non-equilibrium phenomenon, driven by the ultrafast coupled dynamics of electrons and phonons, and culminating in the emergence of a localized quasiparticle state. In this work,…

Describing electron-phonon interactions in a solid requires knowledge of the electron-phonon matrix elements in the Hamiltonian. State-of-the-art first-principles calculations for the electron-phonon interaction are limited to the…

We develop a practical first-principles methodology to determine nonradiative carrier capture coefficients at defects in semiconductors. We consider transitions that occur via multiphonon emission. Parameters in the theory, including…

Materials Science · Physics 2015-03-25 Audrius Alkauskas , Qimin Yan , Chris G. Van de Walle

A theoretical investigation of the possible existence of the chiral polaron formation in graphene is reported. We present an analytical method to calculate the ground-state of the electron-phonon system within the framework of the Lee-Low…

Mesoscale and Nanoscale Physics · Physics 2019-07-09 B. S. Kandemir

We present the first numerically exact study of a polaron with quadratic coupling to the oscillator displacement, using two alternative methodological developments. Our results cover both anti-adiabatic and adiabatic regimes and the entire…

An optimized phonon approach for the numerical diagonalization of interacting electron-phonon systems is proposed. The variational method is based on an expansion in coherent states that leads to a dramatic truncation in the phonon space.…

Strongly Correlated Electrons · Physics 2009-11-10 V. Cataudella , G. De Filippis , F. Martone , C. A. Perroni

The self-trapping of exciton-polariton condensates is demonstrated and explained by the formation of a new polaron-like state. Above the polariton lasing threshold, local variation of the lattice temperature provides the mechanism for an…

Polarons, quasiparticles formed through interactions between lattice and charge carriers (electrons and holes), strongly influence the electronic and optical properties of functional materials. In nanostructured BiVO$_{4}$, polaron…

Materials Science · Physics 2025-11-26 Seyeon Park , Yajing Zhang , Michele Reticcioli , Cesare Franchini , Bongjae Kim

This article reviews the theory of electron-phonon interactions in solids from the point of view of ab-initio calculations. While the electron-phonon interaction has been studied for almost a century, predictive non-empirical calculations…

Materials Science · Physics 2017-03-08 Feliciano Giustino

Formation of self-trapped holes (STH) in a comprehensive list of scintillator materials, including halides and chalcogenides, are studied using an accurate and computationally efficient first-principles method, the polaron self-interaction…

Materials Science · Physics 2016-11-21 Fei Zhou , Babak Sadigh , Daniel Aberg

Small polarons remain a significant bottleneck in the realization of efficient devices using transition metal oxides. Routes to engineer small polaron coupling to electronic states and lattice modes to control carrier localization remain…

Here we study the polaronic transport through molecules weakly connected to metallic electrodes in the nonlinear response regime. Molecule itself is treated as a quantum dot with discrete energy levels, its connection to the electrodes is…

Mesoscale and Nanoscale Physics · Physics 2007-07-22 Kamil Walczak

Exact diagonalization calculations show a continuous transition from delocalized to small polaron behavior as a function of intersite electron-lattice coupling. A transition, found previously at Hartree-Fock level [Yonemitsu et al., Phys.…

Condensed Matter · Physics 2008-06-16 J. Lorenzana , A. Dobry

In this work we provide a comprehensive review of theoretical and experimental studies of the properties of polarons formed by mobile impurities strongly interacting with quantum many-body systems. We present a unified perspective on the…

We consider the polaron dynamics driven by Frohlich type, long wavelength dominated electron-phonon interaction, for three different semi-metals: single and bilayer graphene, and semi-Dirac, all grown on polar substrates such as, SiC or…

Strongly Correlated Electrons · Physics 2020-09-10 S. Banerjee

The formation of polarons due to the interaction between charge carriers and the crystal lattice has been proposed to have wide-ranging effects on charge carrier dynamics in lead--halide perovskites (LHPs). The hypothesis underlying many of…

Materials Science · Physics 2021-07-14 Matthew J. Wolf , Lewis A. D. Irvine , Alison B. Walker