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The classical Gibbs paradox concerns the entropy change upon mixing two gases. Whether an observer assigns an entropy increase to the process depends on their ability to distinguish the gases. A resolution is that an "ignorant" observer,…

Quantum Physics · Physics 2021-04-14 Benjamin Yadin , Benjamin Morris , Gerardo Adesso

The issue of the Gibbs paradox is that when considering mixing of two gases within classical thermodynamics, the entropy of mixing appears to be a discontinuous function of the difference between the gases: it is finite for whatever small…

Quantum Physics · Physics 2009-11-11 A. E. Allahverdyan , Th. M. Nieuwenhuizen

In this work, Gibbs paradox was discussed from the view of observer. The limitations of real observer are analyzed quantitatively. The entropy of mixing was found to be determined by both the identification ability and the information…

Classical Physics · Physics 2016-12-12 Liangsuo Shu , Xiaokang Liu , Suyi Huang , Shiping Jin

In this paper, we investigate and compare two well-developed definitions of entropy relevant for describing the dynamics of isolated quantum systems: bipartite entanglement entropy and observational entropy. In a model system of interacting…

Quantum Physics · Physics 2020-06-01 Dana Faiez , Dominik Šafránek , J. M. Deutsch , Anthony Aguirre

Recent years have seen an enormously revived interest in the study of thermodynamic notions in the quantum regime. This applies both to the study of notions of work extraction in thermal machines in the quantum regime, as well as to…

Quantum Physics · Physics 2016-12-28 M. Perarnau-Llobet , A. Riera , R. Gallego , H. Wilming , J. Eisert

In this work the non-additive entropy is examined. It appears in isolated particle systems composed of few components. Therefore, the mixing of isolated particle systems S=S1+S2 has been studied. Two cases are considered T1=T2 and T1\leqT2,…

General Physics · Physics 2012-11-13 Miriam Lemanska

The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…

Chemical Physics · Physics 2009-12-03 Chi-Ho Cheng

We develop the framework of classical Observational entropy, which is a mathematically rigorous and precise framework for non-equilibrium thermodynamics, explicitly defined in terms of a set of observables. Observational entropy can be seen…

Statistical Mechanics · Physics 2020-09-09 Dominik Šafránek , Anthony Aguirre , J. M. Deutsch

The thermodynamical entropy of a system which consists of different kinds of ideal gases is known to be defined successfully in the case when the differences are described by classical or quantum theory. Since these theories are special…

Quantum Physics · Physics 2020-02-19 Ryo Takakura

For a thought experiment concerning the mixing of two classical gases, Gibbs concluded that the work that can be extracted from mixing is determined by whether or not the gases can be distinguished by a semi-permeable membrane; that is, the…

Quantum Physics · Physics 2020-11-19 Zoë Holmes , Florian Mintert , Janet Anders

In this paper, we analyze the relationship between entropy and information in the context of the mixing process of two identical ideal gases. We will argue that entropy has a special information-based feature that is enfolded in the…

Quantum Physics · Physics 2015-06-26 Afshin Shafiee , Majid Karimi

The ``Gibbs Paradox'' refers to several related questions concerning entropy in thermodynamics and statistical mechanics: whether it is an extensive quantity or not, how it changes when identical particles are mixed, and the proper way to…

Statistical Mechanics · Physics 2009-11-07 Chih-Yuan Tseng , Ariel Caticha

Gibbs paradox in the context of statistical mechanics addresses the issue of additivity of entropy of mixing gases. The usual discussion attributes the paradoxical situation to classical distinguishability of identical particles and credits…

Quantum Physics · Physics 2018-11-12 C. S. Unnikrishnan

A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…

Quantum Physics · Physics 2013-05-08 J. M. Deutsch , Haibin Li , Auditya Sharma

Traditional quantum thermodynamic frameworks associate work to energy exchanges induced by unitary transformations generated by external controls, and heat to energy exchanges induced by bath interaction. Recently, a framework was…

Quantum Physics · Physics 2026-01-06 Tiago F. F. Santos , Camille Latune

Entropy is one of the key thermodynamic variables reflecting changes in the state of matter. Unlike other thermodynamic variables, it is well-defined also for nonequilibrium steady states through its relation to information. Applying this…

Statistical Mechanics · Physics 2026-04-15 Haim Diamant , Gil Ariel

The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schr\"odinger equation, which preserves…

Quantum Physics · Physics 2025-01-16 Florian Meier , Tom Rivlin , Tiago Debarba , Jake Xuereb , Marcus Huber , Maximilian P. E. Lock

The amount of extractable work from a physical system is fundamentally connected to the information available about its state, as illustrated by Maxwell's demon and the Gibbs paradox. In standard thermodynamic protocols involving…

Quantum Physics · Physics 2026-02-27 Tanmoy Biswas

Entanglement entropy is one of the most prominent measures in quantum physics. We show that it has an interesting ergotropic interpretation in terms of unitarily extracted work. It determines how much energy one can extract from a source of…

Quantum Physics · Physics 2023-06-16 Dominik Šafránek

Observational entropy captures both the intrinsic uncertainty of a thermodynamic state and the lack of knowledge due to coarse-graining. We demonstrate two interpretations of observational entropy, one as the statistical deficiency…

Quantum Physics · Physics 2024-11-20 Ge Bai , Dominik Šafránek , Joseph Schindler , Francesco Buscemi , Valerio Scarani
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