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It has been shown that oxide ceramics containing multiple transition and/or rare-earth elements in equimolar ratios have a strong tendency to crystallize in simple single phase structures, stabilized by the high configurational entropy. In…

Materials Science · Physics 2019-03-27 Ralf Witte , Abhishek Sarkar , Robert Kruk , Benedikt Eggert , Richard A. Brand , Heiko Wende , Horst Hahn

The prediction of new high entropy oxides (HEOs) remains a profound challenge due to their inherent chemical complexity. In this work, we combine experimental and computational methods to search for new HEOs in the tetravalent $A$O$_2$…

Recent research in multi-principal element alloys (MPEAs) has increasingly focused on the exploration and exploitation of short-range order (SRO) to enhance material performance. However, the understanding of SRO formation and the precise…

Solid oxide fuel cells are efficient energy conversion devices essential to clean energy development, yet their broad application is limited by material challenges, including sluggish oxygen reduction kinetics at intermediate temperatures,…

Materials Science · Physics 2026-02-18 Yueyuan Gu , Juan Shi , Dilshod Nematov , Aoqi Liu , Yanru Yin , Hailu Dai , Lei Bi

All the existing entropy stable (ES) schemes for relativistic hydrodynamics (RHD) in the literature were restricted to the ideal equation of state (EOS), which however is often a poor approximation for most relativistic flows due to its…

Numerical Analysis · Mathematics 2024-09-18 Linfeng Xu , Shengrong Ding , Kailiang Wu

The equilibrium short-range order (SRO) in Cu-Pd alloys is studied theoretically. The evolution of the Fermi surface-related splitting of the (110) diffuse intensity peak with changing temperature is examined. The results are compared with…

Statistical Mechanics · Physics 2009-10-31 I. Tsatskis , E. K. H. Salje

We study nuclear relaxation in the presence of localized electrons in a two-dimensional electron gas in a disordered delta-doped semiconductor heterostructure and show that this method can reliably probe their magnetic interactions and…

Strongly Correlated Electrons · Physics 2009-09-01 Kusum Dhochak , V. Tripathi

Electronic properties of disordered binary alloys are studied via the calculation of the average Density of States (DOS) in two and three dimensions. We propose a new approximate scheme that allows for the inclusion of local order effects…

Disordered Systems and Neural Networks · Physics 2007-05-23 D. F. de Mello , G. G. Cabrera

Chemical short-range order (CSRO) is believed to be a key contributor to the exceptional properties of multicomponent alloys. However, direct validation and confirmation of CSRO has been highly elusive in most compounds. Recent studies for…

Materials Science · Physics 2022-11-11 A. Naghdi , F. J. Dominguez-Gutierrez , W. Y. Huo , K. Karimi , S. Papanikolaou

We explore correlations of inhomogeneous local density of states (LDoS) for impure superconductors with different symmetries of the order parameter (s-wave and d-wave) and different types of scatterers (elastic and magnetic impurities). It…

Superconductivity · Physics 2012-06-08 A. E. Koshelev , A. A. Varlamov

Short-range ordering (SRO) in Fe-Cr has been the subject of a number of recent experimental and theoretical investigations, as ordering effects are significant for the phase stability of this technologically important alloy. Recently,…

Materials Science · Physics 2012-04-30 G. Apostolopoulos , K. Mergia , S. Messoloras

We report a comparative high-pressure study of two fluorite-type rare-earth oxides with increasing configurational entropy, (CePr)O$_{2-{\delta}}$ and (CePrLa)O$_{2-{\delta}}$. Synchrotron-based powder X-ray diffraction and Raman…

We develop a percolation model for face centered cubic binary alloys with chemical short-range order (SRO) to account for chemical ordering/clustering that occurs in nominally random solid solutions. We employ a lattice generation scheme…

Materials Science · Physics 2024-08-28 Abhinav Roy , Karl Sieradzki , James M. Rondinelli , Ian D. McCue

High-entropy oxides (HEOs) are a promising class of multicomponent ceramics with tunable structural and electronic properties. In this study, we investigate the local electronic structure of rare-earth HEOs in the (Ce, Sm, Pr, La, Y)O2…

We present total energy and force calculations on the (GaN)$_{1-x}$(ZnO)$_{x}$ alloy. Site-occupancy configurations are generated by Monte Carlo (MC) simulations, based on a cluster expansion (CE) model proposed in a previous study.…

Materials Science · Physics 2015-12-11 Jian Liu , Luana S. Pedroza , Carissa Misch , Maria V. Fernández-Serra , Philip B. Allen

Chemical short-range order (SRO) refers to preference or avoidance between neighboring atomic species, which significantly impacts the properties of advanced alloys. However, quantifying and further controlling SRO remains a major…

Using an all-electron, first principles, Landau-type theory, we study the nature of short-range order and compositional phase stability in equiatomic refractory high entropy alloys, NbMoTa, NbMoTaW, and VNbMoTaW. We also investigate…

Materials Science · Physics 2024-03-13 Christopher D. Woodgate , Julie B. Staunton

Oxide Li-conducting solid-state electrolytes (SSEs) offer excellent chemical and thermal stability but typically exhibit lower ionic conductivity than sulfides and chlorides. This motivates the search for new oxide materials with enhanced…

Materials Science · Physics 2025-10-02 Seungwoo Hwang , Jiho Lee , Seungwu Han , Youngho Kang , Sungwoo Kang

Equiatomic CoCrNi medium entropy alloys are known for their unique properties linked to chemical short-range order (CSRO), crucial in both percolation processes and/or nucleation and growth processes influencing alloy passivation in aqueous…

EXAFS analysis of pure elements, binary and ternary equiatomic refractory alloys within the Nb-Zr-Ti-Hf-Ta system is performed at the Nb and Zr K-edges to analyze the evolution of the chemical local environment and the lattice distortion. A…