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Related papers: Low-temperature anomalies in one-dimensional exact…

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A limited number of 2D and 3D materials under a constant pressure contract in volume upon heating isobarically; this anomalous phenomenon is known as the negative thermal expansion (NTE). In this paper, the NTE anomaly is observed in 1D…

Statistical Mechanics · Physics 2025-06-05 Igor Travěnec , Ladislav Šamaj

We have devised an isotropic interaction potential that gives rise to negative thermal expansion (NTE) behavior in equilibrium many-particle systems in both two and three dimensions over a wide temperature and pressure range (including zero…

Materials Science · Physics 2008-07-24 Mikael C. Rechtsman , Frank H. Stillinger , Salvatore Torquato

We study negative thermal expansion (NTE) in model lattices with multiple atoms per cell and first- and second-nearest neighbor interactions using the (anharmonic) Morse potential. By exploring the phase space of neighbor distances and…

Materials Science · Physics 2016-06-15 Joseph T. Schick , Andrew M. Rappe

The negative thermal expansion (NTE) compound ZrW2O8 has been well-studied because it remains cubic with a nearly constant, isotropic NTE coefficient over a broad temperature range. However, its elastic constants seem just as strange as its…

Materials Science · Physics 2007-05-23 C. Pantea , A. Migliori , P. B. Littlewood , Y. Zhao , H. Ledbetter , T. Kimura , J. Van Duijn , G. R. Kowach

While most solids expand when heated, some materials show the opposite behavior: negative thermal expansion (NTE). In polymers and biomolecules, NTE originates from the entropic elasticity of an ideal, freely-jointed chain. The origin of…

H2O is a unique substance with exceptional thermal properties arising from the subtle interplay between its electronic, phononic, and structural degrees of freedom. Of particular interest in H2O are the negative thermal expansion (NTE)…

Chemical Physics · Physics 2025-12-30 B. I. Min , J. -S. Kang

The thermal and lattice dynamical properties of seven silicon clathrate framework structures are investigated with ab initio density functional methods (frameworks I, II, IV, V, VII, VIII, and H). The negative thermal expansion (NTE)…

Materials Science · Physics 2014-01-28 Ville J. Härkönen , Antti J. Karttunen

Many ceramic and hybrid metal-organic framework materials show negative thermal expansion (NTE): they \textit{contract} instead of expanding on heating \cite{Barrera_Miller_Lind_Romao 2005}. Their structures are invariably characterised as…

Materials Science · Physics 2014-07-02 Hong Fang , Martin T. Dove , Anthony E. Phillips

Minimal models are developed to examine the origin of large negative thermal expansion (NTE) in under-constrained systems. The dynamics of these models reveals how underconstraint can organize a thermodynamically extensive manifold of…

Materials Science · Physics 2009-11-13 Z. Schlesinger , J. A. Rosen , J. N. Hancock , A. P. Ramirez

Negative thermal expansion (NTE) describes the anomalous propensity of materials to shrink when heated. Since its discovery, the NTE effect has been found in a wide variety of materials with an array of magnetic, electronic and structural…

Materials Science · Physics 2018-11-09 Connor A. Occhialini , G. G. Guzmán-Verri , Sahan U. Handunkanda , Jason N. Hancock

Negative thermal expansion (NTE) - the phenomenon where some materials shrink rather than expand when heated - is both intriguing and useful, but remains poorly understood. Current understanding hinges on the role of specific vibrational…

Materials Science · Physics 2020-09-23 Martin T Dove , Juan Du , Zhongsheng Wei , David A Keen , Matthew G Tucker , Anthony E Phillips

In the paper we report the modeling and design of material which has a negative thermal expansion (NTE). The basic assumption is a potential between the atoms in the material can be approximated by a Lennard-Jones potential (6-12) and the…

Materials Science · Physics 2016-01-12 Mikrajuddin Abdullah

The phenomenon of negative thermal expansion (NTE) deals with the increase of the lattice parameters and the volume of the unit cell when the material is thermally cooled. The NTE is typically associated with thermal phonons and anomalous…

Strongly Correlated Electrons · Physics 2023-03-10 Wojciech Brzezicki , Filomena Forte , Canio Noce , Mario Cuoco , Andrzej M. Oleś

We discovered unique uniaxial negative thermal expansion (NTE) behavior for a weak-itinerant-ferromagnetic phase of CoZr$_{2}$H$_{3.49}$. CoZr$_{2}$ is known as a superconductor exhibiting uniaxial NTE along the $c$-axis, which is called…

Materials Science · Physics 2025-09-26 Yuto Watanabe , Kota Suzuki , Takayoshi Katase , Akira Miura , Aichi Yamashita , Yoshikazu Mizuguchi

Negative thermal expansion (NTE) is unusual but important property for control of thermal expansion. In the present study, the chemical modification is utilized to engineer controllable thermal expansion in cubic NTE ScF3. A broad window of…

Materials Science · Physics 2016-12-09 Xiaojian Wang , Jun Chen , Fei Han , Yang Ren , Tao Wang , Jinxia Deng , Xianran Xing

We use the hyper-netted chain approximation of liquid state theory to analyze the evolution with density of the pair correlation function in a model of soft spheres with harmonic repulsion. As observed in recent experiments on jammed soft…

Statistical Mechanics · Physics 2010-10-01 Hugo Jacquin , Ludovic Berthier

We use a combination of variable-temperature / variable-pressure neutron powder diffraction, variable-pressure inelastic neutron scattering, and quantum chemical calculations to interrogate the behaviour of the negative thermal expansion…

We have investigated temperature dependence of the lattice parameters and the unit cell volume of ZnF$_2$ by neutron diffraction and have discovered negative thermal expansion (NTE) at low temperature. To understand why this simple compound…

Materials Science · Physics 2012-07-03 Tapan Chatterji , Mohamed Zbiri , Thomas C. Hansen

Pressure and temperature dependence of the negative thermal expansion in Zn(CN)$_2$ is fully investigated using molecular dynamics simulations with a built potential model. The advantage of this study allows us to reproduce all the exotic…

Materials Science · Physics 2014-07-02 Hong Fang , Martin T. Dove , Leila H. N. Rimmer , Alston J. Misquitta

The dynamics of inertial particles in Rayleigh-B\'{e}nard convection, where both particles and fluid exhibit thermal expansion, is studied using direct numerical simulations (DNS). We consider the effect of particles with a thermal…

Soft Condensed Matter · Physics 2019-07-02 Kim M. J. Alards , Rudie P. J. Kunnen , Herman J. H. Clercx , Federico Toschi
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