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By large-scale Monte Carlo simulations of semiflexible polymers in $d=2$ dimensions the applicability of the Kratky-Porod model is tested. This model is widely used as "standard model" for describing conformations and force versus extension…

Soft Condensed Matter · Physics 2011-11-15 Hsiao-Ping Hsu , Wolfgang Paul , Kurt Binder

We report grand canonical Monte Carlo simulations of the critical point properties of homopolymers within the Bond Fluctuation model. By employing Configurational Bias Monte Carlo methods, chain lengths of up to N=60 monomers could be…

Condensed Matter · Physics 2009-10-28 N. B. Wilding , M. Mueller , K. Binder

Monte Carlo simulations of coarse-grained polymers provide a useful tool to deepen the understanding of conformational and statistical properties of polymers both in physical as well as in biological systems. In this study we sample compact…

Soft Condensed Matter · Physics 2009-05-07 Manfred Bohn , Dieter W. Heermann

We prove to all orders of renormalized perturbative polymer field theory the existence of a short chain expansion applying to polymer solutions of long and short chains. For a general polymer network with long and short chains we show…

Condensed Matter · Physics 2016-08-31 Christian von Ferber

We analyze the scaling laws for a set of two different species of long flexible polymer chains joined together at one of their extremities (copolymer stars) in space dimension D=2. We use a formerly constructed field-theoretic description…

Soft Condensed Matter · Physics 2009-11-07 Christian von Ferber , Yurij Holovatch

We present a study of connectivity percolation in suspensions of hard spherocylinders by means of Monte Carlo simulation and connectedness percolation theory. We focus attention on polydispersity in the length, the diameter and the…

Soft Condensed Matter · Physics 2015-06-02 Hugues Meyer , Paul van der Schoot , Tanja Schilling

We consider the simplest representative of the class of multiply branched polymer macromolecules, known as a pom-pom structure. The molecule consists of a backbone linear chain terminated by two branching points with functionalities…

Soft Condensed Matter · Physics 2020-12-02 Khristine Haydukivska , Ostap Kalyuzhnyi , Viktoria Blavatska , Jaroslav Ilnytskyi

While stretching of a polymer along a flat surface is hardly different from the classical Pincus problem of pulling chain ends in free space, the role of curved geometry in conformational statistics of the stretched chain is an exciting…

Soft Condensed Matter · Physics 2022-08-30 Kirill E. Polovnikov , Sergei K. Nechaev , Alexander Y. Grosberg

Limited-valency colloidal particles can self-assemble into polymeric structures analogous to molecules. While their structural equilibrium properties have attracted wide attention, insight into their dynamics has proven challenging. Here,…

Soft Condensed Matter · Physics 2021-09-08 Simon Stuij , Joep Rouwhorst , Hannah Jonas , Nicola Ruffino , Zhe Gong , Stefanno Sacanna , Peter Bolhuis , Peter Schall

The electronic properties of $\pi$-conjugated two-dimensional (2D) polymers near the Fermi level are determined by structural topology and chemical composition. Thus, tight-binding (TB) calculations of the corresponding fundamental network…

Large-scale Monte Carlo simulations of a phase-separating colloid-polymer mixture are performed and compared to recent experiments. The approach is based on effective interaction potentials in which the central monomers of self-avoiding…

Soft Condensed Matter · Physics 2007-05-23 R. L. C. Vink , A. Jusufi , J. Dzubiella , C. N. Likos

A directed polymer is allowed to branch, with configurations determined by global energy optimization and disorder. A finite size scaling analysis in 2D shows that, if disorder makes branching more and more favorable, a critical transition…

Statistical Mechanics · Physics 2016-08-31 Giovanni Sartoni , Attilio L. Stella

We prove that the hierarchical fractal model recently proposed for describing the stretched polymers [A. N. Samukhin et al, Phys. Rev. Lett.{\bf 78}, 326(1997)] is equivalent to a one-dimensional chain with hierarchical aperiodic structure.…

Disordered Systems and Neural Networks · Physics 2009-10-31 Chen-Ping Zhu , Shi-Jie Xiong , Tao Chen

The paper presents a short overview of the theoretical, numerical and experimental works on the critical behavior of a dilute polymer solution of long-flexible polymer chains confined in semi-infinite space restricted by a surface or in a…

Soft Condensed Matter · Physics 2018-01-08 Zoryana Usatenko , Krzysztof S. Danel

The most conspicuous property of a semiflexible polymer is its persistence length, defined as the decay length of tangent correlations along its contour. Using an efficient stochastic growth algorithm to sample polymers embedded in a…

Soft Condensed Matter · Physics 2015-06-23 Sebastian Schöbl , Sebastian Sturm , Wolfhard Janke , Klaus Kroy

Recent advances in single macromolecule experiments have sparked interest in the ensemble dependence of force-extension relations. The thermodynamic limit may not be attainable for such systems, that leads to inequivalence of the…

Soft Condensed Matter · Physics 2018-07-30 Sandipan Dutta , Panayotis Benetatos

The phase diagram of soft spheres with size dispersion has been studied by means of an optimized Monte Carlo algorithm which allows to equilibrate below the kinetic glass transition for all sizes distribution. The system ubiquitously…

Soft Condensed Matter · Physics 2007-05-23 L. A. Fernandez , V. Martin-Mayor , P. Verrocchio

We analyze the equlibrium statistics of a long linear homo-polymer chain confined in between two flat geometrical constraints under good solvent condition. The chain is ocupying two dimensional space and geometrical constraints are two…

Statistical Mechanics · Physics 2015-12-29 Pramod Kumar Mishra

Writing $<R^2_N > = AN^{2\nu}(1+BN^{-\Delta_1}+CN^{-1}+ ...)$ for the mean square end--to--end length $<R^2_N>$ of a self--avoiding polymer chain of $N$ links, we have calculated $\Delta_1$ for the two--dimensional {\em continuum} case from…

Condensed Matter · Physics 2009-10-28 S. R. Shannon , T. C. Choy , R. J. Fleming

We present an exact solution for the distribution of sample averaged monomer to monomer distance of ring polymers. For non-interacting and weakly-interacting models these distributions correspond to the distribution of the area under the…

Soft Condensed Matter · Physics 2019-01-24 Shlomi Medalion , Erez Aghion , Hagai Meirovitch , Eli Barkai , David A. Kessler
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