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A key goal of exoplanet spectroscopy is to measure atmospheric properties, such as abundances of chemical species, in order to connect them to our understanding of atmospheric physics and planet formation. In this new era of high-quality…
Atmospheric compositions for rocky exoplanets will depend strongly on the bulk planetary composition and the orbital position of the planet. Non-traditional gases may be present in the atmospheres of exceptionally hot planets. Atmospheres…
The demographics of sub-Jovian planets around low-mass stars is dominated by populations of ``sub-Neptunes" and ``super-Earths", distinguished by the presence or absence of envelopes of low-molecular weight volatiles, i.e., H2, He, and H2O.…
Some sub-Neptune planets may host habitable conditions; for example "Hycean" worlds with H2 envelopes over liquid water oceans can maintain potentially hospitable pressures and temperatures at their surface. Recent JWST observations of…
The most productive tracer of exoplanetary atmospheric escape is the measurement of excess absorption in the near-infrared metastable helium triplet during transits. Atmospheric escape of a close-in planet's atmosphere plays a role in its…
It is now understood that the accretion of terrestrial planets naturally involves giant collisions, the moon-forming impact being a well known example. In the aftermath of such collisions the surface of the surviving planet is very hot and…
The recent discovery and initial characterization of sub-Neptune-sized exoplanets that receive stellar irradiance of approximately Earth's raised the prospect of finding habitable planets in the coming decade, because some of these…
Determining the He/H ratio in cool stars presents a fundamental astrophysical challenge. While this ratio is established for hot O and B stars, its extrapolation to cool stars remains uncertain due to the absence of helium lines in their…
Exoplanets are now being discovered in profusion. However, to understand their character requires spectral models and data. These elements of remote sensing can yield temperatures, compositions, and even weather patterns, but only if…
A quantitative understanding of the nature and composition of low-mass rocky (exo)planet atmospheres during their evolution is needed to interpret observations. The magma ocean stage of terrestrial- and sub-Neptune planets permits mass…
The characterization of exoplanetary atmospheres has come of age in the last decade, as astronomical techniques now allow for albedos, chemical abundances, temperature profiles and maps, rotation periods and even wind speeds to be measured.…
Interpretations of exoplanetary transmission spectra have been undermined by apparent obscuration due to clouds/hazes. Debate rages on whether weak H$_2$O features seen in exoplanet spectra are due to clouds or inherently depleted oxygen.…
[Abridged] The transmission of light through a planetary atmosphere can be studied as a function of altitude and wavelength using stellar or solar occultations, giving often unique constraints on the atmospheric composition. For exoplanets,…
Hi-resolution spectroscopy (R > 25,000) has recently emerged as one of the leading methods to detect atomic and molecular species in the atmospheres of exoplanets. However, it has so far been lacking in a robust method to extract…
The atmospheric pressure-temperature profiles for transiting giant planets cross a range of chemical transitions. Here we show that the particular shape of these irradiated profiles for warm giant planets below 1300 K lead to striking…
Most of the molecules detected thus far in exoplanet atmospheres, such as water and CO, are present for a large range of pressures and temperatures. In contrast, metal hydrides exist in much more specific regimes of parameter space, and so…
Volatile loss from exoplanetary atmospheres and its possible implications for the longevity of habitable surface conditions is a topic of vigorous debate currently. The vast majority of the habitable zone terrestrial-like exoplanets known…
We investigate the signals from neutral He atoms observed from Earth orbit in 2010 by IBEX. The full He signal observed during the 2010 observation season can be explained as a superposition of pristine neutral interstellar He gas and an…
The He I line at 1.08 $\mu$m is a valuable tracer of atmospheric escape in exoplanet atmospheres. We expand past networks used to predict the absorbing He(2$^3S$) by including, firstly, processes that involve H$_2$ and some molecular ions…
Characterising the atmospheres of exoplanets is key to understanding their nature and provides hints about their formation and evolution. High-resolution measurements of the helium triplet, He(2$^{3}$S), absorption of highly irradiated…