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An accurate description of electron correlation energies in molecules requires either basis set extrapolation or the use of explicitly-correlated wave functions that address the deficiencies of standard determinantal expansions at short…

Chemical Physics · Physics 2025-12-09 Samuel R. Powell , Edward F. Valeev

An efficient method of interpretation of the crystal field effect in non-metallic f-electron systems, the {\it enhanced angular overlap model} (EAOM), is presented. The method is established on the ground of perturbation expansion of the…

Materials Science · Physics 2007-05-23 Z. Gajek

We have performed first-principles calculations of Si/SiO$_2$ superlattices in order to examine their electronic states, confinement and optical transitions, using linearized-augmented-plane-wave techniques and density-functional theory.…

Materials Science · Physics 2009-11-07 Pierre Carrier , Laurent J. Lewis , M. W. Chandre Dharma-wardana

We show that the spectral weights $W_{m\vec K}(\vec k)$ used for the unfolding of two-component spinor eigenstates $| {\psi_{m\vec K}^\mathrm{SC}} > = | \alpha > | {\psi_{m\vec{K}}^\mathrm{SC, \alpha}} > + | \beta > |…

Materials Science · Physics 2015-01-29 Paulo V. C. Medeiros , Stepan S. Tsirkin , Sven Stafström , Jonas Björk

We present a first-principles-based multiscale simulation framework for quantitative predictions of the high-energy part of the Ultraviolet Photoelectron Spectroscopy (UPS) spectra of amorphous molecular solids. The approach combines a…

This paper presents phononic band-structure calculation results obtained using a mixed variational formulation for 1-, and 2-dimensional unit cells. The formulation itself is presented in a form which is equally applicable to 3-dimensiomal…

Materials Science · Physics 2014-11-13 Ankit Srivastava , Sia Nemat-Nasser

We introduce the concept of compressed convolution, a technique to convolve a given data set with a large number of non-orthogonal kernels. In typical applications our technique drastically reduces the effective number of computations. The…

Instrumentation and Methods for Astrophysics · Physics 2014-01-08 F. Elsner , B. D. Wandelt

A fully analytical approximation for the observable characteristics of many-electron atoms is developed via a complete and orthonormal hydrogen-like basis with a single-effective charge parameter for all electrons of a given atom. The basis…

Quantum Physics · Physics 2017-12-06 O. D. Skoromnik , I. D. Feranchuk , A. U. Leonau , C. H. Keitel

Photonic crystals (PhCs) are periodic dielectric structures that exhibit unique electromagnetic properties, such as the creation of band gaps where electromagnetic wave propagation is inhibited. Accurately predicting dispersion relations,…

Numerical Analysis · Mathematics 2024-11-12 Yueqi Wang , Richard Craster , Guanglian Li

Though several theoretical models have been proposed to design electronic flat-bands, the definite experimental realization in two-dimensional atomic crystal is still lacking. Here we propose a novel and realistic flat-band model based on…

Materials Science · Physics 2021-02-04 Jiang Zeng , Ming Lu , Haiwen Liu , Hua Jiang , X. C. Xie

An ab initio downfolding method is formulated to construct low-dimensional models for correlated electrons. In addition to the band downfolding by constrained random phase approximation formulated for 3D models, screening away from the…

Strongly Correlated Electrons · Physics 2011-01-11 Kazuma Nakamura , Yoshihide Yoshimoto , Yoshiro Nohara , Masatoshi Imada

Recently, the study of topological structures in photonics has garnered significant interest, as these systems can realize robust, non-reciprocal chiral edge states and cavity-like confined states that have applications in both linear and…

Optics · Physics 2023-11-30 Alexander Cerjan , Terry A. Loring

We present here a Finite Element Method devoted to the simulation of 3D periodic structures of arbitrary geometry. The numerical method based on ARPACK and PARDISO libraries, is discussed with the aim of extracting the eigenmodes of…

Computational Physics · Physics 2014-02-21 Romain Garnier , André Barka , Olivier Pascal

This research thesis presents a novel higher-order spectral element method (SEM) formulated in cylindrical coordinates for analyzing electromagnetic fields in waveguides filled with complex anisotropic media. In this study, we consider a…

Numerical Analysis · Mathematics 2024-11-22 Raul Oliveira Ribeiro

Band bending is a central concept in solid-state physics that arises from local variations in charge distribution especially near semiconductor interfaces and surfaces. Its precision measurement is vital in a variety of contexts from the…

A procedure is presented that combines density functional theory computations of bulk semiconductor alloys with the semiconductor Bloch equations, in order to achieve an ab initio based prediction of the optical properties of semiconductor…

Materials Science · Physics 2017-06-08 L. C. Bannow , P. Rosenow , P. Springer , E. W. Fischer , J. Hader , J. V. Moloney , R. Tonner , S. W. Koch

Accurate description of deformed atomic nuclei by the orbital-free density functional theory has been a longstanding textbook challenge, due to the difficulty in accounting for the intricate quantum shell effects that are present in such…

Nuclear Theory · Physics 2024-12-31 X. H. Wu , Z. X. Ren , P. W. Zhao

A band structure description of the observed large band gaps and moments in both the antiferromagnetic (AFM) and paramagnetic (PM) phases of the classic NaCl-structure Mott insulators MnO, FeO, CoO, and NiO is provided by ordinary,…

Materials Science · Physics 2018-01-10 Giancarlo Trimarchi , Alex Zunger

Quantum--Mechanical methods that are both computationally fast and accurate are not yet available for electronic excitations having charge transfer character. In this work, we present a significant step forward towards this goal for those…

Chemical Physics · Physics 2015-06-12 Michele Pavanello , Troy Van Voorhis , Lucas Visscher , Johannes Neugebauer

We show, for the first time, how to calculate photonic band structures for metals and other dispersive systems using an efficient Order N scheme. The method is applied to two simple periodic metallic systems where it gives results in close…

Materials Science · Physics 2009-10-31 J. Arriaga , A. J. Ward , J. B. Pendry