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Density Functional Theory (DFT) sees prominent use in computational chemistry and physics, however, problems due to the self-interaction error (SIE) pose additional challenges to obtaining qualitatively correct results. An unphysical energy…

Chemical Physics · Physics 2023-02-08 Dale R. Lonsdale , Lars Goerigk

In one-dimensional systems, spontaneous symmetry breaking (SSB) states are fragile by nature, as the injection of a non-zero energy density above the ground state is expected to restore the symmetry. This instability implies that local…

Statistical Mechanics · Physics 2026-03-18 Florent Ferro

In a physical system undergoing a continuous quantum phase transition, spontaneous symmetry breaking occurs when certain symmetries of the Hamiltonian fail to be preserved in the ground state. In the traditional Landau theory, a symmetry…

Quantum Algebra · Mathematics 2019-03-05 Marcel Bischoff , Corey Jones , Yuan-Ming Lu , David Penneys

Self-interaction error (SIE), arising from the imperfect cancellation of the spurious classical Coulomb interaction between an electron and itself, is a persistent challenge in modern density functional approximations. This issue is…

An alternative approach to density functional theory based on self-consistent field theory for ring polymers is applied to neutral atoms hydrogen to neon in their ground states. The spontaneous emergence of atomic shell structure and…

Quantum Physics · Physics 2026-02-05 Phil A. LeMaitre , Russell B. Thompson

Spontaneous symmetry breaking is central to our understanding of physics and explains many natural phenomena, from cosmic scales to subatomic particles. Its use for applications requires devices with a high level of symmetry, but engineered…

Spontaneous symmetry breaking occurs in a system when its Hamiltonian possesses a certain symmetry, whereas the ground state wave functions do not preserve it. This provides such a scenario that a bifurcation, which breaks the symmetry,…

Statistical Mechanics · Physics 2015-05-13 Jian-Hui Zhao , Hong-Lei Wang , Bo Li , Huan-Qiang Zhou

Traditional band theory of perfect crystalline solids often uses as input the structure deduced from diffraction experiments; when modeled by the minimal unit cell this often produces a spatially averaged model. The present study…

Materials Science · Physics 2021-01-04 Zhi Wang , Xingang Zhao , Robert Koch , Simon J. L. Billinge , Alex Zunger

The concept of symmetry breaking and the emergence of corresponding local order parameters constitute the pillars of modern day many body physics. The theory of quantum entanglement is currently leading to a paradigm shift in understanding…

Quantum Physics · Physics 2016-11-18 V. Zauner , D. Draxler , L. Vanderstraeten , J. Haegeman , F. Verstraete

We show that the spontaneous symmetry breaking can be defined also for finite systems based on the properly defined jump probability between the ground states in the 2d and 3d Ising models on a square and a cubic lattice respectively. Our…

Statistical Mechanics · Physics 2021-06-25 Fotis K. Diakonos , Yiannis F. Contoyiannis , Stelios M. Potirakis

The description of spontaneous symmetry breaking that underlies the connection between classically ordered objects in the thermodynamic limit and their individual quantum mechanical building blocks is one of the cornerstones of modern…

Other Condensed Matter · Physics 2010-04-29 Jasper van Wezel

Spontaneous symmetry breaking is a cornerstone of modern physics, defining a wealth of phenomena in condensed-matter and high-energy physics, and beyond. It requires an infinite number of degrees of freedom, and even then, for continuous…

Disordered Systems and Neural Networks · Physics 2026-04-10 Oleg Evnin

We present a clear and mathematically simple procedure explaining spontaneous symmetry breaking in quantum mechanical systems. The procedure is applicable to a wide range of models and can be easily used to explain the existence of a…

Classical Physics · Physics 2010-04-29 Jasper van Wezel , Jeroen van den Brink

We introduce a dual-core system with double symmetry, one between the cores, and one along each core, imposed by the spatial modulation of local nonlinearity in the form of two tightly localized spots, which may be approximated by a pair of…

Pattern Formation and Solitons · Physics 2018-05-15 Krzysztof B. Zegadlo , Nguyen Viet Hung , Aleksandr Ramaniuk , Marek Trippenbach , Boris A. Malomed

Spontaneous symmetry breaking generally circumvents one-dimensional systems with local interactions in thermal equilibrium. Here, we analyze a category of one-dimensional Hermitian models via local non-Hermitian constructions. Notably,…

Quantum Physics · Physics 2025-06-30 Jia-Bao Wang , Zi-Hao Dong , Yi Zhang

Despite its widespread use, density functional theory (DFT) has several notable areas of failure; perhaps the most well-studied of these failures is self-interaction error (SIE). Density corrected DFT (DC-DFT) was proposed as a potential…

Chemical Physics · Physics 2023-06-28 Devin J. Hernandez , Adam Rettig , Martin Head-Gordon

Spontaneous symmetry breaking originats in quantum mechanical measurement of the relevant observable defining the physical situation, order parameter is the average of this observable. A modification is made on the random-phase postulate…

Quantum Physics · Physics 2008-02-03 Yu Shi

Symmetry breaking--the phenomenon in which the symmetry of a system is not inherited by its stable states--underlies pattern formation, superconductivity, and numerous other effects. Recent theoretical work has established the possibility…

Adaptation and Self-Organizing Systems · Physics 2021-09-24 Ferenc Molnar , Takashi Nishikawa , Adilson E. Motter

Effects of short-range electronic interactions in a three-dimensional line-node semimetal that supports linearly dispersing quasiparticles around an isolated loop in the Brillouin zone are discussed. Due to vanishing density of states…

Mesoscale and Nanoscale Physics · Physics 2017-08-02 Bitan Roy

Self-interactions (SIs) are a major problem in density functional approximations and the source of serious divergence from experimental results. Here, we propose to optimize density functional total energies in terms of the effective local…

Other Condensed Matter · Physics 2012-06-20 Nikitas I. Gidopoulos , Nektarios N. Lathiotakis
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