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Silicon is a promising anode material for next-generation lithium-ion batteries due to its exceptionally high specific capacity (3600 mAh g$^{-1}$), significantly exceeding that of conventional graphite. However, its practical application…

Chemical Physics · Physics 2026-01-08 D Sugunan , Y Jiang , J Guo , H Wang , M Marinescu , G Offer

Li-ion rechargeable batteries have enabled the wireless revolution transforming global communication. Future challenges, however, demands distributed energy supply at a level that is not feasible with the current energy-storage technology.…

Developing sustainable battery electrode manufacturing methods is particularly pressing for alloying-type active materials, such as silicon, which often require additional energy-intensive and solvent-based processing to reinforce them with…

Materials Science · Physics 2022-06-30 Moumita Rana , Afshin Pendashteh , Richard Schäufele , Joaquim Gispert , Juan J. Vilatela

Silicon anodes offer high energy densities for next-generation lithium-ion batteries; however, their application is limited by severe volume expansion during cycling. Making silicon porous or nanostructured mitigates this expansion but…

The development of silicon anodes to replace conventional graphite in efforts to increase energy densities of lithium-ion batteries has been largely impeded by poor interfacial stability against liquid electrolytes. Here, stable operation…

Enhanced EV market penetration requires durability of the battery with high energy throughput. For long-term cycle stability of silicon-graphite anode capable of high energy density, the reversible redox reactions are crucial. Here, we…

There is increasing interest in materials that combine energy-storing functions with augmented mechanical properties, ranging from flexibility in bending to stretchability to structural properties. In the case of lithium-ion batteries,…

Applied Physics · Physics 2020-04-29 N. Boaretto , J. Almenara , A. Mikhalchan , R. Marcilla , J. J. Vilatela

We developed two-step solution-phase reactions to form hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery applications. Mn3O4 nanoparticles grown selectively on RGO sheets over free…

Cubic spinel lithium manganese oxide (LiMn2O4) has been able to attract a great deal of attention over the years as a promising cathode material for large scale lithium ion batteries. Here a facile hydrothermal route followed by solid state…

Materials Science · Physics 2018-08-31 Niraj Kumar , Jassiel R. Rodriguez , Vilas G. Pol , Arijit Sen

Silicon is one of the most promising anode materials for Lithium-ion batteries. Silicon endures volume changes upon cycling, which leads to subsequent pulverization and capacity fading. These drawbacks lead to a poor lifespan and hamper the…

Materials Science · Physics 2022-12-23 Mariam Ezzedine , Fatme Jardali , Ileana Florea , Mihai-robert Zamfir , Costel-sorin Cojocaru

Graphite, the standard commercial anode for Li-ion batteries, is thermodynamically incompatible with Na-ion batteries, leading researchers to search for alternative C-based structures (e.g., hard carbon, expanded graphite). In a simplified…

Materials Science · Physics 2026-05-15 Ihor Radchenko , Oleksandr I. Malyi

The market quest for fast-charging, safe, long-lasting and performant batteries drives the exploration of new energy storage materials, but also promotes fundamental investigations of materials already widely used. Presently, revamped…

Amorphous polymer derived silicon oxycarbide (SiOC) is an attractive candidate for Lithium ion battery anodes, as an alternative to graphite, which is limited to a theoretical capacity of 372 mAh/g. However, SiOC tends to exhibit poor…

By means of Density Functional Theory calculations we evaluate several lithium carbonate - graphite interface models as a prototype of the Solid Electrolyte Interphase capping layer on graphite anodes in lithium-ion batteries. It is found…

Materials Science · Physics 2016-12-06 Elena Zvereva , Damien Caliste , Pascal Pochet

Using density functional theory simulations, this study introduces Petal-Graphyne (PLG), a novel multi-ring metallic structure composed of 4-, 8-, 10-, and 16-membered rings. Its structural, electronic, and lithium/sodium storage properties…

Herein, in-situ reduction of bismuth and graphene oxide was performed by a solvothermal method under a nitrogen atmosphere, and the resulting Bi on RGO nanocomposites were used as an anode material for Mg-ion batteries. The nanocomposite of…

Next-generation lithium-ion batteries with silicon anodes have positive characteristics due to higher energy densities compared to state-of-the-art graphite anodes. However, the large volume expansion of silicon anodes can cause high…

Numerical Analysis · Mathematics 2024-04-03 R. Schoof , G. F. Castelli , W. Dörfler

Embedding silicon nanoparticles in an intermetallic matrix is a promising strategy to produce remarkable bulk anode materials for lithium-ion (Li-ion) batteries with low potential, high electrochemical capacity and good cycling stability.…

Materials Science · Physics 2021-01-06 Tahar Azib , Claire Thaury , Fermin Cuevas , Eric Leroy , Christian Jordy , Nicolas Marx , Michel Latroche

A flexible, light weight and high conductivity current collector is the key element that enables fabrication of high performance flexible lithium ion battery. Here we report a thin, light weight and flexible lithium ion battery that uses…

Chemical Physics · Physics 2015-11-13 Hang Qu , Jingshan Hou , Yufeng Tang , Oleg Semenikihin , Maksim Skorobogatiy

Graphite has been reported to have anion as well as cation intercalation capacities as both cathode and anode host materials for the dual ion battery. In this work, we study the intercalation of bis(trifluoromethanesulfonyl) imide (TFSI)…

Materials Science · Physics 2018-07-04 Chol-Jun Yu , Un-Song Ri , Gum-Chol Ri , Jin-Song Kim
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