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Materials exhibiting a substitutional disorder such as multicomponent alloys and mixed metal oxides/oxyfluorides are of great importance in many scientific and technological sectors. Disordered materials constitute an overwhelmingly large…

Cluster expansions are commonly employed as surrogate models to link the electronic structure of an alloy to its finite-temperature properties. Using cluster expansions to model materials with several alloying elements is challenging due to…

Materials Science · Physics 2025-01-31 Yann L. Müller , Anirudh Raju Natarajan

Long-standing challenges in cluster expansion (CE) construction include choosing how to truncate the expansion and which crystal structures to use for training. Compressive sensing (CS), which is emerging as a powerful tool for model…

Materials Science · Physics 2013-10-30 Lance J Nelson , Vidvuds Ozolins , Shane Reese , Fei Zhou , Gus L. W. Hart

The Cluster Expansion (CE) Method encounters significant computational challenges in multicomponent systems due to the computational expense of generating training data through density functional theory (DFT) calculations. This work aims to…

Materials Science · Physics 2024-12-10 Guillermo Vazquez , Daniel Sauceda , Raymundo Arróyave

Density functional theory (DFT)-based simulations of materials have first-principles accuracy, but are very computationally expensive. For simulating various properties of multi-component alloys, the cluster expansion (CE) technique has…

Materials Science · Physics 2026-04-01 Jacob Jeffries , Bochuan Sun , Enrique Martinez

Cluster expansion (CE) is effective in modeling the stability of metallic alloys, but sometimes cluster expansions fail. Failures are often attributed to atomic relaxation in the DFT-calculated data, but there is no metric for quantifying…

Materials Science · Physics 2017-07-19 Andrew H. Nguyen , Conrad W. Rosenbrock , C. Shane Reese , Gus L. W. Hart

Crystalline alloys and related mixed systems make up a large family of materials with high tunability which have been proposed as the solution to a large number of energy related materials design problems. Due to the presence of chemical…

Materials Science · Physics 2025-01-28 Pernilla Ekborg-Tanner , Petter Rosander , Erik Fransson , Paul Erhart

The Atomic Cluster Expansion (ACE) (Drautz, Phys. Rev. B 99, 2019) has been widely applied in high energy physics, quantum mechanics and atomistic modeling to construct many-body interaction models respecting physical symmetries.…

Numerical Analysis · Mathematics 2024-01-08 Cheuk Hin Ho , Timon S. Gutleb , Christoph Ortner

Using the maximum entropy method, we derive the "adaptive cluster expansion" (ACE), which can be trained to estimate probability density functions in high dimensional spaces. The main advantage of ACE over other Bayesian networks is its…

Neural and Evolutionary Computing · Computer Science 2007-05-23 Stephen Luttrell

Machine-learning-based interatomic potentials enable accurate materials simulations on extended time- and lengthscales. ML potentials based on the Atomic Cluster Expansion (ACE) framework have recently shown promising performance for this…

Computational Physics · Physics 2024-08-02 Daniel F. Thomas du Toit , Yuxing Zhou , Volker L. Deringer

Identifying a suitable set of descriptors for modeling physical systems often utilizes either deep physical insights or statistical methods such as compressed sensing. In statistical learning, a class of methods known as structured sparsity…

Materials Science · Physics 2019-10-30 Zhidong Leong , Teck Leong Tan

The domain of explainable AI is of interest in all Machine Learning fields, and it is all the more important in clustering, an unsupervised task whose result must be validated by a domain expert. We aim at finding a clustering that has high…

Artificial Intelligence · Computer Science 2024-03-28 Mathieu Guilbert , Christel Vrain , Thi-Bich-Hanh Dao

Machine learning interatomic potentials are revolutionizing large-scale, accurate atomistic modelling in material science and chemistry. Many potentials use atomic cluster expansion or equivariant message passing frameworks. Such frameworks…

Computational Physics · Physics 2024-07-31 Bingqing Cheng

In alloys cluster expansions (CE) are increasingly used to combine first-principles electronic-structure and Monte Carlo methods to predict thermodynamic properties. As a basis-set expansion in terms of lattice geometrical clusters and…

Materials Science · Physics 2017-11-28 Nikolai A. Zarkevich , D. D. Johnson

The Atomic Cluster Expansion (ACE) provides a formally complete basis for the local atomic environment. ACE is not limited to representing energies as a function of atomic positions and chemical species, but can be generalized to vectorial…

Materials Science · Physics 2023-05-25 Matteo Rinaldi , Matous Mrovec , Anton Bochkarev , Yury Lysogorskiy , Ralf Drautz

The Atomic Cluster Expansion (ACE) [R. Drautz, Phys. Rev. B, 99:014104 (2019)] provides a systematically improvable, universal descriptor for the environment of an atom that is invariant to permutation, translation and rotation. ACE is…

Computational Physics · Physics 2023-08-15 Christoph Ortner

The cluster expansion formalism used in materials science is reconstructed on an axiomatic basis with the aims of clarifying underlying concepts and improving computational procedures, and without using conventional cluster functions.…

Materials Science · Physics 2022-10-21 Paul E. Lammert , Vincent H. Crespi

The cluster expansion model (CEM) provides a powerful computational framework for rapid estimation of configurational properties in disordered systems. However, the traditional CEM construction procedure is still plagued by two fundamental…

Disordered Systems and Neural Networks · Physics 2023-07-24 Bibek Dash , Suhail Haque , Abhijit Chatterjee

We have developed a method to improve the doping computation efficiency, this method is based on first principles calculations and cluster expansion. First principles codes produce highly accurate total energies and optimized geometries for…

Materials Science · Physics 2017-03-02 Zongguo Wang , Xiaoyu Yang , Xushan Zhao , Ligen Wang , Juan Wang , Mingming Zhang , Jie Ren

It is often of interest to perform clustering on longitudinal data, yet it is difficult to formulate an intuitive model for which estimation is computationally feasible. We propose a model-based clustering method for clustering objects that…

Methodology · Statistics 2020-05-19 Daniel K. Sewell , Yuguo Chen , William Bernhard , Tracy Sulkin
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