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During the intercalation of lithium in layered host materials such as graphite, lithium atoms can move within the plane between two neighboring graphene sheets, but cannot cross the sheets. Repulsive interactions between atoms in different…

Materials Science · Physics 2024-09-06 Antoine Cordoba , Marion Chandesris , Mathis Plapp

Phase separation may be driven by the minimization of a suitable free energy ${\cal F}$. This is the case, e.g., for diblock copolimer melts, where ${\cal F}$ is minimized by a steady periodic pattern whose wavelength $\lambda_{GS}$ depends…

Statistical Mechanics · Physics 2015-09-14 Paolo Politi , Alessandro Torcini

Asymptotic homogenisation is considered for problems with integral constraints imposed on a slowly-varying microstructure; an insulator with an array of perfectly dielectric inclusions of slowly varying size serves as a paradigm. Although…

Classical Analysis and ODEs · Mathematics 2023-04-03 A. Kent , S. L. Waters , J. Oliver , S. J. Chapman

We present extensive results from 2-dimensional simulations of phase separation kinetics in a model with order-parameter dependent mobility. We find that the time-dependent structure factor exhibits dynamical scaling and the scaling…

Condensed Matter · Physics 2009-10-30 Sanjay Puri , Alan Bray , Joel Lebowitz

We propose a new phase of matter, an electronic phase separation transition that starts near the upper pseudogap and segregates the holes into high and low density domains. The Cahn-Hilliard approach is used to follow quantitatively this…

Superconductivity · Physics 2015-05-13 E. V. L de Mello , R. B. Kasal , Otton S. T. Filho , C. A. C. Passos

In the limit of vanishing lattice spacing we provide a rigorous variational coarse-graining result for a next-to-nearest neighbor lattice model of a simple crystal. We show that the $\Gamma$-limit of suitable scaled versions of the model…

Analysis of PDEs · Mathematics 2024-07-08 Annika Bach , Marco Cicalese , Adriana Garroni , Gianluca Orlando

A combination of cellular contractility and active phase separation in cell-matrix composites is thought to be an enabler of spatiotemporal patterning in multicellular tissues across scales, from somitogenesis to cartilage condensation. To…

Soft Condensed Matter · Physics 2022-11-21 Sifan Yin , L Mahadevan

The kinetic separation of repulsive active Brownian particles into a dense and a dilute phase is analyzed using a systematic coarse-graining strategy. We derive an effective Cahn-Hilliard equation on large length and time scales, which…

Soft Condensed Matter · Physics 2014-06-02 Thomas Speck , Julian Bialké , Andreas M. Menzel , Hartmut Löwen

The advective Cahn-Hilliard equation describes the competing processes of stirring and separation in a two-phase fluid. Intuition suggests that bubbles will form on a certain scale, and previous studies of Cahn-Hilliard dynamics seem to…

Fluid Dynamics · Physics 2007-12-12 Lennon O Naraigh , Jean-Luc Thiffeault

The Cahn--Hilliard equation is one of the most common models to describe phase separation processes of a mixture of two materials. For a better description of short-range interactions between the material and the boundary, various dynamic…

Analysis of PDEs · Mathematics 2021-04-27 Patrik Knopf , Kei Fong Lam , Chun Liu , Stefan Metzger

Materials with nanoscale phase separation are considered. These materials are formed by a mixture of several phases, so that inside one phase there exist nanosize inclusions of other phases, with random shapes and random spatial locations.…

Mesoscale and Nanoscale Physics · Physics 2014-03-31 V. I. Yukalov , E. P. Yukalova

Phase field models are widely used to describe multiphase systems. Here a smooth indicator function, called phase field, is used to describe the spatial distribution of the phases under investigation. Material properties like density or…

Numerical Analysis · Mathematics 2015-11-10 Christian Kahle

In this paper a generalization of the Cahn-Hilliard theory of binary liquids is presented for multi-component incompressible liquid mixtures. First, a thermodynamically consistent convection-diffusion type dynamics is derived on the basis…

Materials Science · Physics 2016-02-03 Gyula I. Toth , Mojdeh Zarifi , Bjorn Kvamme

The Cahn--Hilliard equation is one of the most common models to describe phase segregation processes in binary mixtures. In recent times, various dynamic boundary conditions have been introduced to model interactions of the materials with…

Analysis of PDEs · Mathematics 2021-10-12 Patrik Knopf , Andrea Signori

If a binary liquid mixture, composed of two alternative species with equal amounts, is quenched from a high temperature to a low temperature, below the critical point of demixing, then the mixture will phase separate through a process known…

Statistical Mechanics · Physics 2022-02-04 Thomas J. Longo , Mikhail A. Anisimov

We propose finite-volume schemes for the Cahn-Hilliard equation which unconditionally and discretely preserve the boundedness of the phase field and the dissipation of the free energy. Our numerical framework is applicable to a variety of…

Numerical Analysis · Mathematics 2023-12-18 Rafael Bailo , José A. Carrillo , Serafim Kalliadasis , Sergio P. Perez

The evolution of the microstructure due to spinodal decomposition in phase separated mixtures has a strong impact on the final material properties. In the late stage of coarsening, the system is characterized by the growth of a single…

Soft Condensed Matter · Physics 2021-12-09 Björn König , Olivier J. J. Ronsin , Jens Harting

In this work, we study the effective behavior of a two-dimensional variational model within finite crystal plasticity for high-contrast bilayered composites. Precisely, we consider materials arranged into periodically alternating thin…

Analysis of PDEs · Mathematics 2019-02-01 Elisa Davoli , Rita Ferreira , Carolin Kreisbeck

We propose a novel phase-field model to predict elastic microphase separation in polymer gels. To this end, we extend the Cahn-Hilliard free-energy functional to incorporate an elastic strain energy and a coupling term. These contributions…

Materials Science · Physics 2025-05-05 Hamza Oudich , Pietro Carrara , Laura De Lorenzis

The Cahn-Hilliard equation is one of the most common models to describe phase separation processes in mixtures of two materials. For a better description of short-range interactions between the material and the boundary, various dynamic…

Numerical Analysis · Mathematics 2023-01-23 Stefan Metzger