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In this work, we combine the recently developed double unitary coupled cluster (DUCC) theory with the adaptive, problem-tailored variational quantum eigensolver (ADAPT-VQE) to explore accuracy of unitary downfolded Hamiltonians for quantum…

The quantum simulation of quantum chemistry is a promising application of quantum computers. However, for N molecular orbitals, the $\mathcal{O}(N^4)$ gate complexity of performing Hamiltonian and unitary Coupled Cluster Trotter steps makes…

Computational Physics · Physics 2022-05-18 Mario Motta , Erika Ye , Jarrod R. McClean , Zhendong Li , Austin J. Minnich , Ryan Babbush , Garnet Kin-Lic Chan

Quantum computing enables parallelism through superposition and entanglement and offers advantages over classical computing architectures. However, due to the limitations of current quantum hardware in the noisy intermediate-scale quantum…

Quantum Physics · Physics 2025-09-09 Guolong Zhong , Yi Fan , Zhenyu Li

With the advent of interconnected quantum computers, i.e., distributed quantum computing (DQC), multiple quantum computers can now collaborate via quantum networks to perform massively complex computational tasks. However, DQC faces…

Distributed, Parallel, and Cluster Computing · Computer Science 2022-10-07 Napat Ngoenriang , Minrui Xu , Sucha Supittayapornpong , Dusit Niyato , Han Yu , Xuemin , Shen

The Trotterized Unitary Coupled Cluster Single and Double (UCCSD) ansatz has recently attracted interest due to its use in Variation Quantum Eigensolver (VQE) molecular simulations on quantum computers. However, when the size of molecules…

Chemical Physics · Physics 2023-05-29 Mohammad Haidar , Marko J. Rančić , Yvon Maday , Jean-Philip Piquemal

In many practical applications, quantum algorithms require several qubits, significantly more than those available with current noisy intermediate-scale quantum processors. Distributed quantum computing (DQC) is considered a scalable…

Quantum Physics · Physics 2026-03-02 Michele Bandini , Davide Ferrari , Stefano Carretta , Michele Amoretti

Quantum simulation is a promising pathway toward practical quantum advantage by simulating large-scale quantum systems. In this work, we propose communication-efficient distributed quantum simulation protocols by exploring three quantum…

Quantum Physics · Physics 2024-11-06 Tianfeng Feng , Jue Xu , Wenjun Yu , Zekun Ye , Penghui Yao , Qi Zhao

Quantum chemistry and materials science are among the most promising areas for demonstrating algorithmic quantum advantage and quantum utility due to their inherent quantum mechanical nature. Still, large-scale simulations of quantum…

Accurate quantum chemistry simulations remain challenging on classical computers for problems of industrially relevant sizes and there is reason for hope that quantum computing may help push the boundaries of what is technically feasible.…

Quantum Physics · Physics 2021-03-17 Vincent E. Elfving , Marta Millaruelo , José A. Gámez , Christian Gogolin

Understanding the intricate quantum spin dynamics of radical pair reactions is crucial for unraveling the underlying nature of chemical processes across diverse scientific domains. In this work, we leverage Trotterization to map coherent…

Many quantum algorithms rely on a quality initial state for optimal performance. Preparing an initial state for specific applications can considerably reduce the cost of probabilistic algorithms such as the well studied quantum phase…

Quantum Physics · Physics 2024-12-10 Alexandre Fleury , James Brown , Erika Lloyd , Maritza Hernandez , Isaac H. Kim

We propose a quantum algorithm to simulate the dynamics in quantum chemistry problems. It is based on adding fresh qubits at each Trotter step, which enables a simpler implementation of the dynamics in the extended system. After each step,…

Quantum Physics · Physics 2025-02-07 Maxine Luo , J. Ignacio Cirac

The study and prediction of chemical reactivity is one of the most important application areas of molecular quantum chemistry. Large-scale, fully error-tolerant quantum computers could provide exact or near-exact solutions to the underlying…

Quantum Physics · Physics 2019-09-12 Michael Kühn , Sebastian Zanker , Peter Deglmann , Michael Marthaler , Horst Weiß

Distributed quantum computing (DQC) combines the computing power of multiple networked quantum processing modules, enabling the execution of large quantum circuits without compromising on performance and connectivity. Photonic networks are…

With the advantages of high-speed parallel processing, quantum computers can efficiently solve large-scale complex optimization problems in future networks. However, due to the uncertain qubit fidelity and quantum channel noise, distributed…

Distributed, Parallel, and Cluster Computing · Computer Science 2022-10-07 Napat Ngoenriang , Minrui Xu , Jiawen Kang , Dusit Niyato , Han Yu , Xuemin , Shen

An algorithm for the generation of shuttling sequences is necessary for the operation of a linear segmented ion-trap quantum computer. The present work provides an implementation of an algorithm that produces sequences proved to be optimal…

Due to their non-iterative nature, fixed Unitary Coupled-Cluster (UCC) ans\"atze are attractive for performing quantum chemistry Variational Quantum Eigensolver (VQE) computations as they avoid pre-circuit measurements on a quantum…

Quantum chemistry simulations that accurately predict the properties of materials are among the most highly anticipated applications of quantum computing. It is widely believed that simulations running on quantum computers will allow for…

Quantum simulators are essential tools for developing and testing quantum algorithms. However, the high-frequency traversal characteristic of quantum simulators represents an unprecedented demand in the history of IT, and existing…

Emerging Technologies · Computer Science 2025-08-22 Mingyang Yu , Haorui Yang , Donglin Wang , Desheng Kong , Ji Du , Yulong Fu , Wei Wang , Jing Xu

Quantum chemistry calculations for small molecules on quantum hardware have been demonstrated to date only on universal-gate quantum computers, not quantum annealers. The latter devices are limited to finding the lowest eigenstate of the…

Chemical Physics · Physics 2019-01-16 Scott N. Genin , Ilya G. Ryabinkin , Artur F. Izmaylov