Related papers: Evidence for Phenylium Reactivity under Interstell…
We present an analysis of optical spectroscopy and infrared aperture photometry of more than 100 H II complexes in nine galaxies. Spectra obtained with the 6-m telescope of SAO RAS are used along with archival data from Spitzer and several…
Recent astronomical observations revealed an increasing molecular complexity in the interstellar medium through the detection of a series of large cyclic carbon species. To correctly interpret these detections, a complex analysis is…
H2 formation remains a major issue for the understanding of interstellar physics. We investigate H2 formation in the interstellar medium at the light of the most recent experimental and theoretical data. We implemented detailed H2 formation…
Many organic molecules have been observed in the interstellar medium thanks to advances in radioastronomy, and very recently the presence of urea was also suggested. While those molecules were observed, it is not clear what the mechanisms…
We present the analysis of the Polycyclic Aromatic Hydrocarbon (PAH) spectra of a sample of 92 typical star forming galaxies at 0.03 < z < 0.2 observed with the Spitzer IRS. We compare the relative strengths of PAH emission features with…
1-propanol (CH3CH2CH2OH) is a three carbon-bearing representative of primary linear alcohols that may have its origin in the cold dark cores in interstellar space. To test this, we investigated in the laboratory whether 1-propanol ice can…
Astrochemistry lies at the nexus of astronomy, chemistry, and molecular physics. On the basis of precise laboratory data, a rich collection of more than 200 familiar and exotic molecules have been identified in the interstellar medium, the…
We report new results from quantum calculations of energy-transfer processes taking place in interstellar environments and involving two newly observed molecular species: C$_5$N$^-$ and C$_7$N$^-$ in collision with He atoms and the p-H$_2$…
Peptide bonds, as the molecular bridges that connect amino acids, are crucial to the formation of proteins. Searches and studies of molecules with embedded peptide-like bonds are thus important for the understanding of protein formation in…
Hydrocarbons play a key role in shaping the chemistry of the interstellar medium (ISM), but their enrichment and relationship with carbonaceous grains and polycyclic aromatic hydrocarbons (PAHs) still lack clear observational constraints.…
The recent detection of the hydrocarbon anion C6H- in the interstellar medium has led us to investigate the synthesis of hydrocarbon anions in a variety of interstellar and circumstellar environments. We find that the anion/neutral…
The development of molecular complexity during stellar and planetary formation owes much to the interaction of gas and dust. When the first astrochemical models including solid-state chemistry were developed more than forty years ago, data…
The formation of double and triple C-C bonds from the processing of pure c-C6H12 (cyclohexane) and mixed H2O:NH3:c-C6H12 (1:0.3:0.7) ices by highly-charged, and energetic ions (219 MeV O^{7+} and 632 MeV Ni^{24+}) is studied. The…
Methanol and formaldehyde are two simple organic molecules that are ubiquitously detected in the interstellar medium. An origin in the solid phase and a subsequent nonthermal desorption into the gas phase is often invoked to explain their…
We have developed a model for molecular hydrogen formation under astrophysically relevant conditions. This model takes fully into account the presence of both physisorbed and chemisorbed sites on the surface, allows quantum mechanical…
Polycyclic aromatic hydrocarbons (PAHs) play a critical role in the reprocessing of stellar radiation and in balancing the heating and cooling processes in the interstellar medium (ISM), but appear to be destroyed in HII regions. However,…
Using new large area maps of the cold neutral medium (CNM) fraction, $f_{\rm CNM}$, we investigate the relationship between the CNM, the abundance of polycyclic aromatic hydrocarbons (PAHs), and the anomalous microwave emission (AME). We…
Rate constants for the C(3P) + CH3OH reaction have been measured in a continuous supersonic flow reactor over the range 50 K to 296 K. C(3P) was created by the in-situ pulsed laser photolysis of CBr4, a multiphoton process which also…
Complex organic molecules (COMs) have been identified toward high- and low-mass protostars as well as molecular clouds, suggesting that these interstellar species originate from the early stage(s) of starformation. The reaction pathways…
A recent suggestion that acetamide, \ce{CH3C(O)NH2}, could be readily formed on water-ice grains by the acid induced addition of water across the \ce{CN} bond is now shown to be valid. Computational modelling of the reaction between…