Related papers: Evidence for Phenylium Reactivity under Interstell…
Context. Among the most significant chemical functional groups of interstellar molecules are the class of nitriles, which are proposed as key prebiotic molecules due to their chemical connection to the peptide bond after hydrolysis. CN…
Fragmentation is an important decay mechanism for polycyclic aromatic hydrocarbons (PAHs) under harsh interstellar conditions and represents a possible formation pathway for small molecules such as H2, C2H2, C2H4. Our aim is to investigate…
The first experimental study of the low-temperature kinetics of the gas-phase reaction of NH2 with formaldehyde (CH2O) has been performed. This reaction has previously been suggested as a source of formamide (NH2CHO) in interstellar…
We use observations of the CI, CII, HI, and H_2 column densities along lines of sight in the Galactic plane to determine the formation rate of H_2 on grains and to determine chemical reaction rates with Polycyclic Aromatic Hydrocarbons.…
The increasingly large number of complex organic molecules detected in the interstellar medium necessitates robust kinetic models that can be relied upon for investigating the involved chemical processes. Such models require rate constants…
Context: Polycyclic Aromatic Hydrocarbons, largely known as PAHs, are widespread in the universe and have been identified in a vast array of astronomical observations from the interstellar medium to protoplanetary discs. They are likely to…
The simultaneous detection of organic molecules of the form C$_2$H$_{\text{n}}$O, such as ketene (CH$_2$CO), acetaldehyde (CH$_3$CHO), and ethanol (CH$_3$CH$_2$OH), toward early star-forming regions offers hints of shared chemical history.…
Reactions between cyano radical and aromatic hydrocarbons are believed to be important pathways for the formation of aromatic nitriles in the interstellar medium (ISM) including those identified in the Taurus molecular cloud (TMC-1).…
The solid-state reaction C + H$_2$O $\rightarrow$ H$_2$CO was studied experimentally following the codeposition of C atoms and H$_2$O molecules at low temperatures. In spite of the reaction barrier and absence of energetic triggering, the…
Interstellar carbonaceous dust is mainly formed in the innermost regions of circumstellar envelopes around carbon-rich asymptotic giant branch (AGB) stars. In these highly chemically stratified regions, atomic and diatomic carbon, along…
Astrochemical evolution step of polycyclic aromatic hydrocarbon (PAH) around a Herbig Ae young star was analyzed using the first principles quantum chemical calculation. For simplicity, model molecule was selected to be acenaphthylene…
The gas-phase formation and spectroscopic characteristics of ethanimine have been re-investigated as a paradigmatic case illustrating the accuracy of state-of-the-art quantum-chemical (QC) methodologies in the field of astrochemistry.…
Carbon ($^3$P) atom is a reactive species that, according to laboratory experiments and theoretical calculations, condensates with interstellar ice components. This fact is of uttermost importance for the chemistry in the interstellar…
We report on the absorption spectra of the polycyclic aromatic hydrocarbon (PAH) molecules anthracene, phenanthrene, and pyrene carrying either an ethynyl (-C2H) or a butadiynyl (-C4H) group. Measurements were carried out in the mid…
Interstellar molecules are thought to build up in the shielded environment of molecular clouds or in the envelope of evolved stars. This follows many sequential reaction steps of atoms and simple molecules in the gas phase and/or on (icy)…
Understanding how the $\mathrm{H}_2$ molecule is formed under the chemical conditions of the interstellar media (ISM) is critical to the whole chemistry of it. Formation of $\mathrm{H}_2$ in the ISM requires a third body acting as a…
Interstellar formamide (NH2CHO) has recently attracted significant attention due to its potential role as a molecular building block in the formation of precursor biomolecules relevant for the origin of life. Its formation, whether on the…
The formation of methanol (CH3OH) on icy grain mantles during the star formation cycle is mainly associated with the CO freeze-out stage. Yet there are reasons to believe that CH3OH also can form at an earlier period of interstellar ice…
Small aromatic molecules, including functionalized derivatives of benzene, are known to be present throughout the different stages of star and planet formation. In particular, oxygen-bearing monosubstituted aromatics, likely including…
Benzonitrile (c-C6H5CN) has been recently detected in cold and dense regions of the interstellar medium (ISM), where it has been used as a signpost of a rich aromatic organic chemistry that might lead to the production of polycyclic…