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We examine the dynamics of hard spheres and discs at high packing fractions in two and three dimensions, modeling the simplest systems exhibiting a glass transition. As it is well known, cooperativity and dynamic heterogeneity arise as…

Soft Condensed Matter · Physics 2007-05-23 Burkhard Doliwa , Andreas Heuer

Supercooled liquids exhibit spatial heterogeneity in the dynamics of their fluctuating atomic arrangements. The length and time scales of the heterogeneous dynamics are central to the glass transition and influence nucleation and growth of…

Materials Science · Physics 2018-05-09 Pei Zhang , Jason J. Maldonis , Ze Liu , Jan Schroers , Paul M. Voyles

We investigate the local structural fluctuations of a model equilibrium fluid with an aim of better understanding the structural basis of locally heterogeneous dynamics identified in recent simulations and experimental studies of…

Soft Condensed Matter · Physics 2018-11-14 Tamoghna Das , Jack F. Douglas

In a recent publication we established an analogy between the free energy of a hard sphere system and the energy of an elastic network [1]. This result enables one to study the free energy landscape of hard spheres, in particular to define…

Disordered Systems and Neural Networks · Physics 2007-08-08 Carolina Brito , Matthieu Wyart

We introduce a new measure of the structure of a liquid which is the softness of the mean-field potential developed by us earlier. We find that this softness is sensitive to small changes in the structure. We then study its correlation with…

Soft Condensed Matter · Physics 2021-05-26 Manoj Kumar Nandi , Sarika Maitra Bhattacharyya

We analyse the relationship between dynamics and configuration space structure of Ising spin glass systems. The exact knowledge of the structure of the low--energy landscape is used to study the relaxation of the system by random walk in…

Disordered Systems and Neural Networks · Physics 2009-11-07 S. Kobe , J. Krawczyk

The origin of the dramatic changes in the behavior of liquids as they approach their vitreous state - increases of many orders of magnitude in transport properties and dynamic time scales - is a major unsolved problem in condensed matter.…

Soft Condensed Matter · Physics 2015-06-23 R. Casalini , D. Fragiadakis , C. M. Roland

The relationship between spatially heterogeneous dynamics (SHD) and jamming is studied in a glass-forming binary Lennard-Jones system via molecular dynamics simulations. It has been suggested that the probability distribution of…

Disordered Systems and Neural Networks · Physics 2007-05-23 Naida Lacevic , Sharon C. Glotzer

We study the relation between short-time vibrational modes and long-time relaxational dynamics in a kinetically constrained lattice gas with harmonic interactions between neighbouring particles. We find a correlation between the location of…

Statistical Mechanics · Physics 2014-03-14 Douglas J. Ashton , Juan P. Garrahan

In trajectory space, dynamical heterogeneities in glass-forming liquids correspond to the emergence of a dynamical phase transition between an active phase poor in local structure and an inactive phase which is rich in local structure. We…

Soft Condensed Matter · Physics 2021-08-10 Francesco Turci , Thomas Speck , C. Patrick Royall

The interplay between the structure and dynamics of partially confined Lennard Jones (LJ) fluids, deep into the supercritical phase, is studied over a wide range of densities in the context of the Frenkel line (FL), which separates rigid…

Statistical Mechanics · Physics 2019-03-20 Kanka Ghosh , C. V. Krishnamurthy

We investigate the growth of dynamic heterogeneity in a glassy hard-sphere mixture for volume fractions up to and including the mode-coupling transition. We use an 80 000 particle system to test a new procedure to evaluate a dynamic…

Soft Condensed Matter · Physics 2015-05-19 Elijah Flenner , Grzegorz Szamel

In this paper the phenomenon of dynamic heterogeneity in supercooled liquid systems is considered in terms of the recently proposed gauge theory of glass transition. The physical interpretation of the dynamic scaling is considered. It is…

Statistical Mechanics · Physics 2015-06-23 Mikhail Vasin

Dynamic heterogeneity is expected to be a key concept for understanding the origin of slow dynamics near the glass transition. In previous studies, quantitative evaluations of dynamic heterogeneity have been attempted using two different…

Disordered Systems and Neural Networks · Physics 2022-04-11 Kohsei Kanayama , Taiki Hoshino , Ryoichi Yamamoto

When a liquid is cooled below its melting temperature, if crystallization is avoided, it forms a glass. This phenomenon, called glass transition, is characterized by a marked increase of viscosity, about 14 orders of magnitude, in a narrow…

Disordered Systems and Neural Networks · Physics 2008-08-23 Simone Capaccioli , Giancarlo Ruocco , Francesco Zamponi

Dynamic heterogeneity is now recognised as a central aspect of structural relaxation in disordered materials with slow dynamics, and was the focus of intense research in the last decade. Here we describe how initial, indirect observations…

Statistical Mechanics · Physics 2010-09-28 Ludovic Berthier , Giulio Biroli , Jean-Philippe Bouchaud , Robert L Jack

We report Molecular Dynamics simulations for a new model of tetrahedral network glass-former, based on short-range, spherical potentials. Despite the simplicity of the forcefield employed, our model reproduces some essential physical…

Statistical Mechanics · Physics 2016-09-08 D. Coslovich , G. Pastore

We investigate the connection between local structure and dynamical heterogeneity in supercooled liquids. Through the study of four different models we show that the correlation between a particle's mobility and the degree of local order in…

Statistical Mechanics · Physics 2014-10-20 Glen M. Hocky , Daniele Coslovich , Atsushi Ikeda , David R. Reichman

Amorphous solids, or glasses, are distinguished from crystalline solids by their lack of long-range structural order. At the level of two-body structural correlations, glassformers show no qualitative change upon vitrifying from a…

Soft Condensed Matter · Physics 2015-06-11 C. Patrick Royall , Stephen R. Williams

The fragility of a glassforming liquid characterizes how rapidly its relaxation dynamics slow down with cooling. The viscosity of strong liquids follows an Arrhenius law with a temperature-independent barrier height to rearrangements…

Soft Condensed Matter · Physics 2020-08-25 Ekin D. Cubuk , Andrea J. Liu , Efthimios Kaxiras , Samuel S. Schoenholz