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Using the non equilibrium Green functions formalism we propose a study of the electronic excitation and collection in nano-structured intermediate-band solar cell. We demonstrate that a thin tunnel barrier between the nano-objects and the…

Successful commercialization of Perovskite/Si tandem solar cells (P/Si TSCs) need a-priori estimation of technological benchmarks to outperform c-Si based technologies under field conditions. To this end, through detailed numerical…

Materials Science · Physics 2022-07-05 Ganga Vinod Chittiboina , Pradeep R. Nair

Identification of charge carrier separation processes in perovskite/silicon tandem solar cells and recombination at buried interfaces of charge selective contacts is crucial for photovoltaic research. Here, intensity- and wavelength-…

Materials Science · Physics 2025-07-15 Maxim Simmonds , Ke Xu , Steve Albrecht , Lars Korte , Igal Levine

Here, we report an experimental demonstration of perovskite solar cells dominated by bimolecular recombination and critically analyse their performance against radiative limits. To this end, we first establish a set of quantitative…

Materials Science · Physics 2024-04-23 Kashimul Hossain , Dhyana Sivadas , Dinesh Kabra , Pradeep R. Nair

Operational stability of perovskite solar cells is remarkably influenced by the device temperature, therefore, decreasing the interior temperature of the device is one of the most effective approaches to prolong the service life. Herein, we…

We present a novel method to measure transient photovoltage at nanointerfaces using ultrafast electron diffraction. In particular, we report our results on the photoinduced electronic excitations and their ensuing relaxations in a…

Materials Science · Physics 2009-11-13 Ryan A. Murdick , Ramani K. Raman , Yoshie Murooka , Chong-Yu Ruan

We demonstrate four and two-terminal perovskite-perovskite tandem solar cells with ideally matched bandgaps. We develop an infrared absorbing 1.2eV bandgap perovskite, $FA_{0.75}Cs_{0.25}Sn_{0.5}Pb_{0.5}I_3$, that can deliver 14.8 %…

Non-radiative recombination processes are the biggest hindrance to approaching the radiative limit of the open-circuit voltage for wide-band gap perovskite solar cells. In addition, to high bulk quality, good interfaces and good energy…

Materials Science · Physics 2021-02-09 Zhifa Liu , Johanna Siekmann , Benjamin Klingebiel , Uwe Rau , Thomas Kirchartz

Lead-halide perovskites have demonstrated astonishing increases in power conversion efficiency in photovoltaics over the last decade. The most efficient perovskite devices now outperform industry-standard multi-crystalline silicon solar…

Applied Physics · Physics 2023-02-20 Yi-Teng Huang , Sean R. Kavanagh , David O. Scanlon , Aron Walsh , Robert L. Z. Hoye

Current-voltage measurements are a standard testing protocol to determine the efficiency of any solar cell. However, perovskite solar cells display significant kinetic phenomena that modify the performance at several time scales, due to…

Applied Physics · Physics 2024-07-03 Enrique H. Balaguera , Juan Bisquert

The interaction of high-energy electrons and X-ray photons with soft semiconductors such as halide perovskites is essential for the characterisation and understanding of these optoelectronic materials. Using nano-probe diffraction…

Cuprous oxide has been conceived as a potential alternative to traditional organic hole transport layers in hybrid halide perovskite-based solar cells. Device simulations predict record efficiencies using this semiconductor, but…

We spatially resolve photocarrier dynamics in halide perovskites using time-resolved electrostatic force microscopy (trEFM) to map surface potential equilibration during photoexcitation. Following treatment with different surface…

Materials Science · Physics 2024-12-06 Madeleine D. Breshears , Justin Pothoof , Rajiv Giridharagopal , David S. Ginger

In this work, perovskite solar cells (PSCs) with different transport layers were fabricated to understand the hysteresis phenomenon under a series of scan rates. The experimental results show that the hysteresis phenomenon would be affected…

Materials Science · Physics 2022-05-24 Jun-Yu Huang , You-Wei Yang , Wei-Hsuan Hsu , En-Wen Chang , Mei-Hsin Chen , Yuh-Renn Wu

Solution-processable, two-dimensional semiconductors are promising optoelectronic materials which could find application in low-cost solar cells. Lead sulfide nanocrystals raised attention since the effective band gap can be adapted over a…

Materials Science · Physics 2015-07-20 Sedat Dogan , Thomas Bielewicz , Vera Lebedeva , Christian Klinke

In this paper, an optoelectronic device simulation framework valid for arbitrary spatial variation of electronic potentials and optical modes, and for transport regimes ranging from ballistic to diffusive, is used to study non-local photon…

Mesoscale and Nanoscale Physics · Physics 2014-11-17 Urs Aeberhard

Hybrid organic-inorganic halide perovskites have emerged as a disruptive new class of materials, exhibiting optimum properties for a broad range of optoelectronic applications, most notably for photovoltaics. The first report of highly…

Materials Science · Physics 2018-08-21 Marina R. Filip , George Volonakis , Feliciano Giustino

Solar energy is clean and renewable but has a low flux density. The lack of a continuous and reliable power supply reduces their average daily output. Since the infrared part is not utilized to produce electricity, conventional photovoltaic…

Materials Science · Physics 2021-01-01 M. M. Nishchenko , M A Shevchenko , E A Tsapko , A A Frolov , G A Frolov , L. L. Sartinska , A. I. Blanovsky

Despite the rapid rise in perovskite solar cell efficiency, poor reproducibility remains a major barrier to commercialization. Film crystallization and device performance are highly sensitive to environmental factors during fabrication, yet…

Hy brid composites obtained upon blending conjugated polymers and colloidal inorganic semiconductor nanocrystals are regarded as attractive photo-active materials for optoelectronic applications. Here we demonstrate that tailoring…