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The metastable hexagonal-diamond phase of Si and Ge (and of SiGe alloys) displays superior optical properties with respect to the cubic-diamond one. The latter is the most stable and popular one: growing hexagonal-diamond Si or Ge without…

Materials Science · Physics 2021-02-24 E. Scalise , A. Sarikov , L. Barbisan , A. Marzegalli , D. B. Migas , F. Montalenti , L. Miglio

Hexagonal group IV materials like silicon and germanium are expected to display remarkable optoelectronic properties for future development of photonic technologies. However, the fabrication of hexagonal group IV semiconductors within the…

The emergence of hexagonal Ge (2H-Ge) as a candidate direct-gap group-IV semiconductor for Si photonics mandates rigorous understanding of its optoelectronic properties. Theoretical predictions of a "pseudo-direct" band gap, characterized…

Materials Science · Physics 2024-12-17 Christopher A. Broderick , Xie Zhang , Mark E. Turiansky , Chris G. Van de Walle

Engineering light absorption in the extended short-wave infrared (e-SWIR) range using scalable materials is a long-sought-after capability that is crucial to implement cost-effective and high-performance sensing and imaging technologies.…

Applied Physics · Physics 2021-01-27 A. Attiaoui , É. Bouthillier , G. Daligou , A. Kumar , S. Assali , O. Moutanabbir

A Dirac metal is a doped (gated) Dirac material with the Fermi energy ($E_\text{F}$) lying either in the conduction or valence bands. In the non-interacting picture, optical absorption in gapless Dirac metals occurs only if the frequency of…

Strongly Correlated Electrons · Physics 2023-03-16 Adamya P. Goyal , Prachi Sharma , Dmitrii L. Maslov

Semiconductor nanowires are attractive for photovoltaic applications because light absorption can be enhanced compared to planar layers due to the more complex coupling of light with wavelength-scale matter. However, experimentally it is…

Applied Physics · Physics 2025-09-29 Francisca Marín , Ijaas Mohamed , Oliver Brandt , Lutz Geelhaar

Despite their electronic dominance, cubic diamond structured Si and Ge, are optoelectronically deficient. Recent work indicates, however, that a volume-expanded hexagonal Ge modification can exhibit intensely sought, superior optoelectronic…

Silicon crystallized in the usual cubic (diamond) lattice structure has dominated the electronics industry for more than half a century. However, cubic silicon (Si), germanium (Ge) and SiGe-alloys are all indirect bandgap semiconductors…

We report on simulations and measurements of the optical absorption of silicon nanowires (NWs) versus their diameter. We first address the simulation of the optical absorption based on two different theoretical methods : the first one,…

High-quality defect-free lonsdaleite Si and Ge can now be grown on hexagonal nanowire substrates. These hexagonal phases of group-IV semiconductors have been predicted to exhibit improved electronic and optical properties for optoelectronic…

We investigate nonlinear optical absorption in diamond crystals containing high densities of nitrogen vacancy (NV) centers using open-aperture Z-scan measurements with 230 fs laser pulses at 1032 nm, within the transparency window of…

Sn-containing Si and Ge alloys belong to an emerging family of semiconductors with the potential to impact group IV semiconductor devices. Indeed, the ability to independently engineer both lattice parameter and band gap holds the premise…

Hexagonal germanium polytypes have emerged as promising direct-gap semiconductors for silicon-integrated optoelectronics, yet their optical properties remain largely unexplored beyond the well-studied 2H phase. We present a comprehensive…

Materials Science · Physics 2026-05-12 Martin Keller , Haichen Wang , Friedhelm Bechstedt , Jürgen Furthmüller , Silvana Botti

Embedded Si and Ge nanocrystals (NCs) in wide band-gap matrices are studied theoretically using an atomistic pseudopotential approach. From small clusters to large NCs containing on the order of several thousand atoms are considered.…

Materials Science · Physics 2007-11-27 C. Bulutay

Optically levitated nanodiamonds with nitrogen-vacancy centers promise a high-quality hybrid spin-optomechanical system. However, the trapped nanodiamond absorbs energy form laser beams and causes thermal damage in vacuum. We propose to…

Optics · Physics 2017-06-05 Lei-Ming Zhou , Ke-Wen Xiao , Jun Chen , Nan Zhao

Recent advances in nanowire synthesis have enabled the realization of crystal phases that in bulk are attainable only under extreme conditions, i.e. high temperature and/or high pressure. For group IV semiconductors this means access to…

The optical spectra of hydrogen at $\sim$500 GPa were studied theoretically using a combination of \emph{ab initio} methods. Among the four most competitive structures, i.e. C2/c-24, Cmca-12, Cmca-4, and I41/amd, only the atomic phase…

Materials Science · Physics 2018-10-24 Xiaowei Zhang , En-Ge Wang , Xin-Zheng Li

Recent advances in the characterization of hexagonal-diamond silicon (2H-Si) have shown that this material possesses remarkably different structural, electronic, and optical properties as compared to the common cubic-diamond (3C) polytype.…

Materials Science · Physics 2024-10-22 Marc Túnica , Alberto Zobelli , Michele Amato

Although diamond photonics has driven considerable interest and useful applications, as shown in frequency generation devices and single photon emitters, fundamental studies on the third-order optical nonlinearities of diamond are still…

We studied the optical absorption induced by 4.7eV pulsed laser radiation on Ge-doped a-SiO2 synthesized by a sol-gel technique. The absorption spectra in the ultraviolet spectral range were measured during and after the end of irradiation…

Materials Science · Physics 2015-06-25 F. Messina , M. Cannas , R. Boscaino , S. Grandi , P. Mustarelli
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