Related papers: Enhanced zeta potentials caused by surface ion mob…
Using a Fourier approach we offer a general solution to calculations of slip velocity within the circuit description of the electro-hydrodynamics in a binary electrolyte confined by a plane surface with a modulated surface potential. We…
An isolated charge-neutral drop suspended in an unbounded medium does not migrate in a uniform DC electric field. A nearby wall breaks the symmetry and causes the drop to drift towards or away from the boundary, depending on the electric…
Electrostatics in the solution phase is governed by free electrical charges such as ions, as well as by bound charges that arise when a polarizable medium responds to an applied field. In a local medium, described by a constant dielectric…
The hydrodynamic phase field model is applied to the problem of film spreading on a solid surface. The disjoining potential, responsible for modification of the fluid properties near a three-phase contact line, is computed from the…
We consider pressure-driven flows of electrolyte solutions in small channels or capillaries in which tracer particles are used to probe velocity profiles. Under the assumption that the double layer is thin compared to the channel…
We describe the ``electrolubrication'' occurring in liquid mixtures confined between two charged surfaces. For a mixture of two liquids, the effective viscosity decreases markedly in the presence of a field. The origin of this reduction is…
Electrokinetic boundary conditions are derived for AC electrokinetic (ACEK) phenomena over leaky dielectric (i.e., semiconducting) surfaces. Such boundary conditions correlate the electric potentials across the semiconductor-electrolyte…
We propose an electro-hydrodynamics model to describe the dynamic evolution of a slender drop containing a dilute ionic surfactant on a naturally wettable surface, with a varying external electric field. This unified model reproduces…
We compute the electrostatic potential at the surface, or zeta potential $\zeta$, of a charged particle embedded in a colloidal suspension using a hybrid mesoscopic model. We show that for weakly perturbing electric fields, the value of…
This paper studies the nature of the effective velocity boundary conditions for liquid flow over a plane boundary on which small free-slip islands are randomly distributed. It is found that, to lowest order in the area fraction $\beta$…
Viscoelasticity and rate-dependent adhesion of soft matter lead to difficulties in modeling the 'relatively simple' problem of a rigid sphere in contact with a viscoelastic half-space. For this reason, approximations in describing surface…
By means of a matched asymptotic expansions approach the electrophoretic velocity and zeta potential of a catalytic particle that uniformly releases ions have been investigated. Attention is focused on large, compared to diffuse layer,…
We demonstrate that "moderate" departures from the no-slip hydrodynamic boundary condition (hydrodynamic slip lengths in the nanometer range) can result in a very large enhancement - up to two orders of magnitude- of most interfacially…
For over a hundred years, electron transport in conductive materials has been primarily described by the Drude model, which assumes that current flow is impeded primarily by momentum-relaxing collisions between electrons and extrinsic…
Continuum simulation is employed to study ion transport and fluid flow through a nanopore in a solid-state membrane under an applied potential drop. Results show the existence of concentration polarization layers on the surfaces of the…
We investigate the effects of electric double layers and flexoelectricity on the surface anchoring in general nematic fluids. Within a simplified model, we demonstrate for a nematic electrolyte how the surface anchoring strength can be…
A wide spectrum of electrokinetic studies is modelled as isothermal ones to expedite analysis even when such conditions may be extremely difficult to realize in practice. As a clear and novel departure from this trend, we address the case…
This work investigates electroviscous effects in presence of charge-dependent slip in steady pressure-driven laminar flow of a symmetric (1:1) electrolyte liquid through a uniformly charged slit contraction - expansion (4:1:4) microfluidic…
We study water between parallel metal walls under applied electric field accounting for the image effect at $T=298$ K. The electric field due to the surface charges serves to attract and orient nearby water molecules, while it tends to a…
Variation of voltage profiles with different time scales leads to the redistribution of deposited energy as well as electro-hydrodynamic forces, while the mechanism and scaling law is still unknown. On the basis of theoretical and numerical…