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Diffusion of symmetric diblock copolymer chains in macroscopically oriented lamellar block copolymers are studied in a molecular dynamics simulation. Results for diffusion constant both parallel $D_\parallel$ and perpendicular $D_\perp$ to…

Soft Condensed Matter · Physics 2008-02-03 Michael Murat , Gary S. Grest , Kurt Kremer

The structure of a polystyrene matrix filled with tightly cross-linked polystyrene nanoparticles, forming an athermal nanocomposite system, is investigated by means of a Monte Carlo sampling formalism. The polymer chains are represented as…

Soft Condensed Matter · Physics 2014-01-17 Georgios G. Vogiatzis , Evangelos Voyiatzis , Doros N. Theodorou

Vesicles self-assembled from amphiphilic diblock copolymers exhibit a wide diversity of behavior upon electroporation, due to competitions between edge, surface and bending energies that drive the system, while different viscous dissipation…

Soft Condensed Matter · Physics 2009-11-07 Harry Bermudez , Helim Aranda-Espinoza , Daniel A. Hammer , Dennis E. Discher , .

We report on the complexation between charged-neutral block copolymers and oppositely charged surfactants studied by small-angle neutron scattering. Two block copolymers/surfactant systems are investigated, poly(acrylic…

Soft Condensed Matter · Physics 2007-05-23 Jean-Francois Berret

Nanolayered lamellae are common structures in nanoscience and nanotechnology, but most are nearly symmetric in layer thickness. Here, we report on the structure and mechanics of highly asymmetric and thermodynamically stable soft--hard…

The orientation of the lamellae formed by the phase separation of symmetric diblock copolymer thin films is strongly affected by the wetting properties of the polymer blocks with respect to the substrate. On bare silicon wafers the lamellae…

In this paper, we propose new coupled codes constructed by overlapping circular spatially-coupled low-density parity-check (SC-LDPC) codes, which show better asymptotic and finite-length decoding performance compared to the conventional…

Information Theory · Computer Science 2018-03-28 Heeyoul Kwak , Bohwan Jun , Pilwoong Yang , Jong-Seon No , Dong-Joon Shin

We present the Multi-Block DC (BDC) class, a rich class of structured nonconvex functions that admit a DC ("difference-of-convex") decomposition across parameter blocks. This multi-block class not only subsumes the usual DC programming, but…

Optimization and Control · Mathematics 2026-04-21 Pouria Fatemi , Hoomaan Maskan , Alp Yurtsever , Suvrit Sra

In distributed storage systems built using commodity hardware, it is necessary to have data redundancy in order to ensure system reliability. In such systems, it is also often desirable to be able to quickly repair storage nodes that fail.…

Information Theory · Computer Science 2012-01-24 Joseph C. Koo , John Gill

The dynamics of microphase separation and the orientation of lamellae in diblock copolymers is investigated in terms of a mean-field model. The formation of lamellar structures and their stable states are explored and it is shown that…

Soft Condensed Matter · Physics 2015-06-15 Vanessa Weith , Alexei Krekhov , Walter Zimmermann

We carry out numerical simulations of vesicle formation based on the density functional theory for block copolymer solutions. It is shown by solving the time evolution equations for concentrations that a polymer vesicle is spontaneously…

Soft Condensed Matter · Physics 2007-05-23 Takashi Uneyama

2D materials and their monolayers have attracted widespread interest by virtue of their unique electronic and optical properties. In addition to their remarkable physical characteristics, their atomically thin nature enables their…

Polymer vesicles are stable robust vesicles made from block copolymer amphiphiles. Recent progress in the chemical design of block copolymers opens up the exciting possibility of creating a wide variety of polymer vesicles with varying fine…

Soft Condensed Matter · Physics 2009-09-02 Lin Jia , Amin Cao , Daniel Levy , Bing Xu , Pierre-Antoine Albouy , Xiangjun Xing , Mark J. Bowick , Min-Hui Li

We systematically explore the self-assembly of semi-flexible polymers in deformable spherical confinement across a wide regime of chain stiffness, contour lengths and packing fractions by means of coarse-grained molecular dynamics…

Soft Condensed Matter · Physics 2021-07-12 Maxime M. C. Tortora , Daniel Jost

Distributed model predictive control (MPC) is either cooperative or competitive, and control-theoretic properties have been less studied in the competitive (e.g., game theory) setting. This paper studies MPC with linear dynamics and a…

Optimization and Control · Mathematics 2017-09-27 Yonatan Mintz , John Audie Cabrera , Jhoanna Rhodette Pedrasa , Anil Aswani

We present NanoImprint lithography experiments and modeling of thin films of block copolymers (BCP). The NanoImprint lithography is used to align perpendicularly lamellar phases, over distances much larger than the natural lamellar…

Synthetic and biological living polymers are self-assembling chains whose chain length distributions (CLDs) are dynamic. We show these dynamics are ultrasensitive: even a small perturbation (e.g. temperature jump) non-linearly distorts the…

Soft Condensed Matter · Physics 2009-11-07 Ben O'Shaughnessy , Dimitrios Vavylonis

Molecular dynamics simulations have been employed to study the formation of a physical (thermoreversible) gel by amphiphilic A-B-A triblock copolymers in aqueous solution. In order to mimic the structure of hydrogel-forming polypeptides…

Soft Condensed Matter · Physics 2007-05-23 Lei Guo , Erik Luijten

In broadband millimeter-wave (mm-Wave) systems, it is desirable to design hybrid beamformers with common analog beamformer for the entire band while employing different baseband beamformers in different frequency sub-bands. Furthermore, the…

Signal Processing · Electrical Eng. & Systems 2019-11-01 Ahmet M. Elbir , Kumar Vijay Mishra

Structures with artificial mechanical properties, often called mechanical metamaterials, exhibit divergent yet tunable performance. Various types of mechanical metamaterials have been proposed, which harness light or magnetic interactions,…