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How should one define thermodynamic quantities (internal energy, work, heat, etc.) for quantum systems coupled to their environments strongly? We examine three (classically equivalent) definitions of a quantum system's internal energy under…

The quantum thermodynamic behavior of small systems is investigated in presence of finite quantum dissipation. We consider the archetype cases of a damped harmonic oscillator and a free quantum Brownian particle. A main finding is that…

Quantum Physics · Physics 2007-05-23 Peter Hänggi , Gert-Ludwig Ingold

Every theory of information, including classical and quantum, can be studied in the framework of operational probabilistic theories--where the notion of test generalizes that of quantum instrument, namely a collection of quantum operations…

Quantum Physics · Physics 2023-05-26 Giacomo M. D'Ariano , Paolo Perinotti , Alessandro Tosini

The outcomes of a series of measurements, made on a quantum system, form a sequence of random events which occur in a particular order. The system, together with a meter or meters, can be seen as following the paths of a stochastic network…

Quantum Physics · Physics 2016-08-01 D. Sokolovski

We treat a quantum mechanical system with certain general properties which are expected to be common in macroscopic quantum systems. Starting from a PURE initial state (which may not describe an equilibrium) in which energy is mildly…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

We showed that quantum mechanical superposition can sustain in the process of ion transfer in protein membrane for a substantial period, in spite of the presence of the interactions with environmental modes of molecular vibration. The…

Quantum Physics · Physics 2013-05-03 Samyadeb Bhattacharya , Sisir Roy

Thermodynamics is based on a coarse-grained approach, from which its fundamental variables emerge, effectively erasing the complicate details of the microscopic dynamics within a macroscopic system. The strength of Thermodynamics lies in…

Quantum Physics · Physics 2025-04-17 Gabriel Fernandez Ferrari , Łukasz Rudnicki , Lucas Chibebe Céleri

Recently, it has been suggested that ion channel selectivity filter may exhibit quantum coherence, which may be appropriate to explain ion selection and conduction processes. Potassium channels play a vital role in many physiological…

Quantum Physics · Physics 2022-05-31 Mina Seifi , Ali Soltanmanesh , Afshin Shafiee

Thermodynamics imposes restrictions on what state transformations are possible. In the macroscopic limit of asymptotically many independent copies of a state---as for instance in the case of an ideal gas---the possible transformations…

Quantum Physics · Physics 2019-11-14 Philippe Faist , Mario Berta , Fernando Brandão

We experimentally probe the interplay of the quantum switch with the laws of thermodynamics. The quantum switch places two channels in a superposition of orders and may be applied to thermalizing channels. Quantum-switching thermal channels…

The quantum-mechanical and thermodynamic properties of a 3-level molecular cooling cycle are derived. An inadequacy of earlier models is rectified in accounting for the spontaneous emission and absorption associated with the coupling to the…

Quantum Physics · Physics 2009-11-07 Jose P. Palao , Ronnie Kosloff , Jeffrey M. Gordon

Thermodynamics connects our knowledge of the world to our capability to manipulate and thus to control it. This crucial role of control is exemplified by the third law of thermodynamics, Nernst's unattainability principle, which states that…

Fluctuation theorems and the second law of thermodynamics are powerful relations constraining the behavior of out-of-equilibrium systems. While there exist generalizations of these relations to feedback controlled quantum systems, their…

Quantum Physics · Physics 2024-10-07 Kacper Prech , Patrick P. Potts

The second law of classical thermodynamics, based on the positivity of the entropy production, only holds for deterministic processes. Therefore the Second Law in stochastic quantum thermodynamics may not hold. By making a fundamental…

Quantum Physics · Physics 2019-11-14 B. Ahmadi , S. Salimi , A. S. Khorashad

A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…

Statistical Mechanics · Physics 2015-03-30 Tatsuhiko N. Ikeda , Naoyuki Sakumichi , Anatoli Polkovnikov , Masahito Ueda

We investigate fundamental connections between thermodynamics and quantum information theory. First, we show that the operational framework of thermal operations is nonequivalent to the framework of Gibbs-preserving maps, and we comment on…

Quantum Physics · Physics 2016-07-13 Philippe Faist

We establish quantum thermodynamics for open quantum systems weakly coupled to their reservoirs when the system exhibits degeneracies. The first and second law of thermodynamics are derived, as well as a finite-time fluctuation theorem for…

Statistical Mechanics · Physics 2017-03-08 Gregory Bulnes Cuetara , Massimiliano Esposito , Gernot Schaller

The superposition of quantum states lies at the heart of physics and has been recently found to serve as a versatile resource for quantum information protocols, defining the notion of quantum coherence. In this contribution, we report on…

Quantum Physics · Physics 2019-10-16 Valeria Cimini , Ilaria Gianani , Marco Sbroscia , Jan Sperling , Marco Barbieri

We exhibit three inequalities involving quantum measurement, all of which are sharp and state independent. The first inequality bounds the performance of joint measurement. The second quantifies the trade-off between the measurement quality…

Quantum Physics · Physics 2021-08-18 Bas Janssens

We introduce the resource-theoretic free energy of a quantum channel as the maximal work extractable from the channel as its output equilibrates to a thermal state and its reference system remains locally intact. It is proportional to the…

Quantum Physics · Physics 2025-10-29 Himanshu Badhani , Dhanuja G S , Siddhartha Das