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A quantum Monte Carlo study of the atomization energies for the G2 set of molecules is presented. Basis size dependence of diffusion Monte Carlo atomization energies is studied with a single determinant Slater-Jastrow trial wavefunction…

Chemical Physics · Physics 2015-06-04 F. R. Petruzielo , Julien Toulouse , C. J. Umrigar

Highly accurate methods such as coupled cluster (CC) techniques can be used for periodic systems within the framework of the method of increments. Its extension to low-dimensional conducting system is considered. To demonstrate the…

Materials Science · Physics 2012-01-31 Elena Voloshina

Foundational Machine Learning Potentials can resolve the accuracy and transferability limitations of classical force fields. They enable microscopic insights into material behavior through Molecular Dynamics simulations, which can crucially…

Computational Physics · Physics 2025-12-04 Paul Fuchs , Julija Zavadlav

We propose a new cross-correlation method that can recognize independent realizations of the same type of stochastic processes and can be used as a new kind of pattern recognition tool in biometrics, sensing, forensic, security and image…

Data Analysis, Statistics and Probability · Physics 2007-05-23 Jong U. Kim , Laszlo B. Kish

We develop a recursive computational procedure to efficiently calculate the macroscopic dielectric function of multi-component metamaterials of arbitrary geometry and composition within the long wavelength approximation. Although the…

Optics · Physics 2020-06-04 W. Luis Mochán , Raksha Singla , Lucila Juárez , Guillermo P. Ortiz

We present a DFT+U-type functional for strong correlation, derived from multiconfigurational wavefunction theory. The reference system experiences electron-electron interactions only in DFT+U-type atomic states, yielding a block-localized…

Chemical Physics · Physics 2023-07-25 Benjamin G. Janesko

We propose an adaptive lossy joint source-channel coding (JSCC) scheme for sending correlated sources over two-terminal discrete-memoryless two-way channels (DM-TWCs). The main idea is to couple the independent operations of the terminals…

Information Theory · Computer Science 2020-06-29 Jian-Jia Weng , Fady Alajaji , Tamás Linder

In many applications, such as classification of images or videos, it is of interest to develop a framework for tensor data instead of an ad-hoc way of transforming data to vectors due to the computational and under-sampling issues. In this…

Machine Learning · Statistics 2020-11-13 You-Lin Chen , Mladen Kolar , Ruey S. Tsay

We discuss correlated lattice models with a time-dependent potential across a barrier and show how to implement a Josephson-junction-like behavior. The pairing occurs by a correlation effect enhanced by the symmetry of the system. In order…

Superconductivity · Physics 2009-11-11 Stefano Bellucci , Michele Cini , Pasquale Onorato , Enrico Perfetto

We report a new implementation of multireference algebraic diagrammatic construction theory (MR-ADC) for simulations of electron attachment and ionization in strongly correlated molecular systems (EA/IP-MR-ADC). Following our recent work on…

Chemical Physics · Physics 2021-01-19 Koushik Chatterjee , Alexander Yu. Sokolov

New density functional theory approach based on a complete active space self-consistent field (CASSCF) reference function in Extended Koopmans' approximation is discussed. Recently, the number of generalizations of density functional theory…

Chemical Physics · Physics 2018-02-15 Sergey Gusarov , Yurii Dmitriev

Density-functional theory forces, stresses and energies comprise a database from which the optimal parameters of a spline-based empirical potential combining Stillinger-Weber and modified embedded-atom forms are determined. Accuracy of the…

Materials Science · Physics 2017-05-10 Robert C. Ehemann , Jeremy W. Nicklas , Hyoungki Park , John W. Wilkins

In this work, we developed an efficient approach to compute ensemble averages in systems with pairwise-additive energetic interactions between the entities. Methods involving full enumeration of the configuration space result in exponential…

Biomolecules · Quantitative Biology 2020-10-13 Arun V. Sathanur , Nathan A. Baker

Transcranial direct current stimulation is a non-invasive brain stimulation technique which modifies neural excitability by providing weak currents through scalp electrodes. The aim of this study is to introduce and analyze a novel…

Optimization and Control · Mathematics 2016-09-27 Sven Wagner , Martin Burger , Carsten H. Wolters

Excited states exhibiting double excitation character are notoriously difficult to model using conventional single-reference methods, such as adiabatic time-dependent density-functional theory (TD-DFT) or equation-of-motion coupled cluster…

We introduce a novel computational approach for the investigation of complex correlated electron materials which makes it possible to evaluate interatomic forces and thereby determine atomic displacements and structural transformations…

Strongly Correlated Electrons · Physics 2014-04-24 I. Leonov , V. I. Anisimov , D. Vollhardt

The development of the relativistic all-order method where all single, double, and partial triple excitations of the Dirac-Hartree-Fock wave function are included to all orders of perturbation theory led to many important results for study…

Atomic Physics · Physics 2015-05-27 H. Gharibnejad , E. Eliav , M. S. Safronova , A. Derevianko

We present a combination of the bi-orthogonal orbital optimisation framework with the recently introduced xTC version of transcorrelation. This allows us to implement non-iterative perturbation based methods on top of the transcorrelated…

Chemical Physics · Physics 2024-04-12 Daniel Kats , Evelin M. C. Christlmaier , Thomas Schraivogel , Ali Alavi

The reference field method, known as the difference formulation, is a key variance reduction technique for Monte Carlo simulations of thermal radiation transport problems. When the material temperature is relatively high and the spatial…

Computational Physics · Physics 2024-11-06 Minsheng Huang , Ruo Li , Kai Yan , Chengbao Yao , Wenjun Ying

The present work reports results from systematic multiconfiguration Dirac-Hartree-Fock calculations of isotope shifts for several well-known transitions in neutral magnesium. Relativistic normal and specific mass shift factors as well as…

Atomic Physics · Physics 2016-07-13 Livio Filippin , Michel Godefroid , Jörgen Ekman , Per Jönsson
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