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The spontaneous polarization of wurtzite III-V nitrides XN (X=Al, Ga, In) and II-VI oxides YO (Y=Be, Zn) is investigated via first-principles computational methods. The modern treatment defines this quantity as the polarization difference…

Fundamental properties of spontaneous and piezo polarization are reformulated and critically reviewed. It was demonstrated that Landau definition of polarization as a dipole density could be used to the infinite systems. The difference…

The wurtzite structure is one of the most frequently found crystal structures in modern semiconductors and its inherent spontaneous polarization is a defining materials property. Despite this significance, confusion has been rampant in the…

Materials Science · Physics 2025-05-07 Simon Fichtner , Mohamed Yassine , Chris van de Walle , Oliver Ambacher

Accurate values for polarization discontinuities between pyroelectric materials are critical for understanding and designing the electronic properties of heterostructures. For wurtzite materials, the zincblende structure has been used in…

Materials Science · Physics 2018-04-17 Cyrus E. Dreyer , Anderson Janotti , Chris G. Van de Walle , David Vanderbilt

The spontaneous and piezoelectric polarizations of III-nitrides considerably affect the operation of various III-nitride-based devices. We report an ab initio study of the spontaneous polarization (SP) and piezoelectric (PZ) constants of…

Applied Physics · Physics 2020-01-14 Kaikai Liu , Xiaohang Li

Huge built-in electric fields have been predicted to exist in wurtzite III-V nitrides thin films and multilayers. Such fields originate from heterointerface discontinuities of the macroscopic bulk polarization of the nitrides. Here we…

Materials Science · Physics 2009-10-31 V. Fiorentini , F. Bernardini , F. Della Sala , A. Di Carlo , P. Lugli

Huge built-in electric fields have been predicted to exist in wurtzite III-V nitrides thin films and multilayers. Such fields originate from heterointerface discontinuities of the macroscopic bulk polarization of the nitrides. Here we…

Materials Science · Physics 2007-05-23 V. Fiorentini , F. Bernardini , F. Della Sala , A. DiCarlo , P. Lugli

We study the dependence of macroscopic polarization on composition and strain in wurtzite III-V nitride ternary alloys using ab initio density-functional techniques. The spontaneous polarization is characterized by a large bowing, strongly…

Materials Science · Physics 2009-11-07 Fabio Bernardini , Vincenzo Fiorentini

The role of spontaneous and piezoelectric polarization in III-V nitride heterostructure devices is discussed. Problems as well as opportunities in incorporating polarization in abrupt and graded heterojunctions composed of binary, ternary,…

Macroscopic polarization plays a major role in determining the optical and electrical properties of nitride nanostructures via polarization-induced built-in electrostatic fields. While currently fashionable, this field of endeavour is still…

Materials Science · Physics 2015-06-25 Fabio Bernardini , Vincenzo Fiorentini

Modern polarization theory yields surface bound charge associated with spontaneous polarization of bulk. However, understanding polarization in nano systems also requires a proper treatment of charge transfer between surface dangling bonds.…

Materials Science · Physics 2021-09-01 Ke Yang , Zeyu Jiang , Duk-Hyun Choe , Damien West , Shengbai Zhang

While non-nitride III-V semiconductors typically have a zincblende structure, they may also form wurtzite crystals under pressure or when grown as nanowhiskers. This makes electronic structure calculation difficult since the band structures…

Mesoscale and Nanoscale Physics · Physics 2013-03-05 Amrit De , Craig E. Pryor

Ab initio calculations of the spontaneous polarization and piezoelectric properties of boron nitride nanotubes show that they are excellent piezoelectric systems with response values larger than those of piezoelectric polymers. The…

Materials Science · Physics 2009-12-16 S. M. Nakhmanson , A. Calzolari , V. Meunier , J. Bernholc , M. Buongiorno-Nardelli

The spontaneous polarization, dynamical Born charges, and piezoelectric constants of the III-V nitrides AlN, GaN, and InN are studied ab initio using the Berry phase approach to polarization in solids. The piezoelectric constants are found…

Materials Science · Physics 2009-10-30 Fabio Bernardini , Vincenzo Fiorentini , David Vanderbilt

We present a universal approach for determining the spontaneous polarization Psp of a wurtzite semiconductor from the emission energies of excitons bound to the different types of stacking faults in these crystals. Employing…

Ferroelectric switching is unambigiously demonstrated for the first time in a III-V semiconductor based material: AlScN -- A discovery which could help to satisfy the urgent demand for thin film ferroelectrics with high performance and good…

Materials Science · Physics 2019-03-27 Simon Fichtner , Niklas Wolff , Fabian Lofink , Lorenz Kienle , Bernhard Wagner

We have proposed the phenomenological description of polarization switching peculiarities in ferroelectric semiconductors with charged defects and prevailing extrinsic conductivity. Exactly we have modified Landau-Ginsburg approach shown…

Materials Science · Physics 2009-11-10 Anna N. Morozovska , Eugeny A. Eliseev

We study a simple microscopic model for thin, ferromagnetic, metallic layers on semi-infinite bulk superconductor. We find that for certain values of the exchange spliting, on the ferromagnetic side, the ground states of such structures…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 M. Krawiec , B. L. Gyorffy , J. F. Annett

Binary ferroelectric nitrides are promising materials for information technologies and power electronics. However, polarization switching in these materials is highly unusual. From the structural perspective, polarization reversal is…

Wurtzite ZnO can be substituted with up to ~30% MgO to form a metastable ZnMgO alloy while still retaining the wurtzite structure. Because this alloy has a larger band gap than pure ZnO, ZnMgO/ZnO quantum wells and superlattices are of…

Other Condensed Matter · Physics 2009-12-16 Andrei Malashevich , David Vanderbilt
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