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Related papers: Efficient local atomic cluster expansion for BaTiO…

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A second-principles effective interatomic potential is introduced for the prototypical perovskite CaTiO$_3$ (CTO), relying on a Taylor polynomial expansion of the Born-Oppenheimer energy surface around the cubic reference structure, in…

Materials Science · Physics 2025-12-04 Huazhang Zhang , Michael Marcus Schmitt , Louis Bastogne , Xu He , Philippe Ghosez

Barium titanate (BaTiO$_3$) is a prototypical ferroelectric perovskite that undergoes the rhombohedral-orthorhombic-tetragonal-cubic phase transitions as the temperature increases. In this work, we develop a classical interatomic potential…

Materials Science · Physics 2016-11-23 Yubo Qi , Shi Liu , Ilya Grinberg , Andrew M. Rappe

We present an atomic cluster expansion (ACE) for carbon that improves over available classical and machine learning potentials. The ACE is parameterized from an exhaustive set of important carbon structures at extended volume and energy…

Materials Science · Physics 2023-06-13 Minaam Qamar , Matous Mrovec , Yury Lysogorskiy , Anton Bochkarev , Ralf Drautz

The accurate description of the structural and thermodynamic properties of ferroelectrics has been one of the most remarkable achievements of Density Functional Theory (DFT). However, running large simulation cells with DFT is…

Materials Science · Physics 2024-06-14 Lorenzo Gigli , Alexander Goscinski , Michele Ceriotti , Gareth A. Tribello

We present a general-purpose parameterization of the atomic cluster expansion (ACE) for magnesium. The ACE shows outstanding transferability over a broad range of atomic environments and captures physical properties of bulk as well as…

Materials Science · Physics 2023-05-08 Eslam Ibrahim , Yury Lysogorskiy , Matous Mrovec , Ralf Drautz

Ferroelectric materials play a crucial role in a broad range of technologies due to their unique properties that are deeply connected to the pattern and behavior of their ferroelectric (FE) domains. Chief among them, barium titanate…

We introduce an open-source, fully atomistic second-principles interatomic potential for lead titanate (PbTiO3), a benchmark ferroelectric material known for its strong polarization and hightemperature phase transitions. While density…

Materials Science · Physics 2025-10-10 Louis Bastogne , Philippe Ghosez

Atomic cluster expansion (ACE) methods provide a systematic way to describe particle local environments of arbitrary body order. For practical applications it is often required that the basis of cluster functions be symmetrized with respect…

Materials Science · Physics 2024-02-27 James M. Goff , Charles Sievers , Mitchell A. Wood , Aidan P. Thompson

Ferroelectric materials display exotic polarization textures at the nanoscale that could be used to improve the energetic efficiency of electronic components. The vast majority of studies were conducted in two dimensions on thin films, that…

The stability, electronic structure, optical and thermoelectric properties of Te-doped BaTiO3 are investigated by first-principal calculation based on the density functional theory and Boltzmann transport theory implemented in WIEN2K and…

Materials Science · Physics 2022-02-16 Meryem Ziati , Hamid Ez-Zahraouy

Modeling ferroelectric materials from first principles is one of the successes of density-functional theory, and the driver of much development effort, requiring an accurate description of the electronic processes and the thermodynamic…

Materials Science · Physics 2022-10-26 Lorenzo Gigli , Max Veit , Michele Kotiuga , Giovanni Pizzi , Nicola Marzari , Michele Ceriotti

Titanium is the base material for a number of technologically important alloys for energy conversion and structural applications. Atomic-scale studies of Ti-based metals employing first-principles methods, such as density functional theory,…

Materials Science · Physics 2020-01-08 Alberto Ferrari , Malte Schröder , Yury Lysogorskiy , Jutta Rogal , Matous Mrovec , Ralf Drautz

Functional oxide perovskites are the pillar of cutting-edge technological applications. Density functional theory (DFT) simulations are the theoretical methods of choice to understand and design perovskite materials. However, tests on the…

Materials Science · Physics 2020-05-11 Kiel T. Williams , Lucas K. Wagner , Claudio Cazorla , Tim Gould

Long-range electrostatic interactions critically affect polar materials. However, state-of-the-art atomistic potentials, such as neural networks or Gaussian approximation potentials employed in large-scale simulations, often neglect the…

Materials Science · Physics 2024-12-03 Lorenzo Monacelli , Nicola Marzari

Atomic Bose-Einstein condensates (BECs) can be viewed as macroscopic objects where atoms form correlated atom clusters to all orders. Therefore, the presence of a BEC makes the direct use of the cluster-expansion approach --- lucrative e.g.…

Quantum Gases · Physics 2015-07-08 M. Kira

Insight into structural and thermodynamic properties of nanoparticles is crucial for designing optimal catalysts with enhanced activity and stability. We present a semi-automated workflow for parameterizing the atomic cluster expansion…

We show with first-principles molecular dynamics the persistence of intrinsic $\langle111\rangle$ Ti off-centerings for BaTiO$_3$ in its cubic paraelectric phase. Intriguingly, these are inconsistent with the Pm$\bar 3$m space group often…

Materials Science · Physics 2022-04-01 Michele Kotiuga , Samed Halilov , Boris Kozinsky , Marco Fornari , Nicola Marzari , Giovanni Pizzi

We study the convergence of a linear atomic cluster expansion (ACE) potential with respect to its basis functions, in terms of the effective two-body interactions of elemental Carbon and Silicon systems. We build ACE potentials with…

Computational Physics · Physics 2025-07-30 Apolinario Miguel Tan , Franco Pellegrini , Stefano de Gironcoli

Using the atomic cluster expansion (ACE) framework, we develop a machine learning interatomic potential for fast and accurately modelling the phonon transport properties of wurtzite aluminum nitride. The predictive power of the ACE…

Materials Science · Physics 2024-02-23 Guang Yang , Yuan-Bin Liu , Lei Yang , Bing-Yang Cao

We present a highly accurate and transferable parameterization of water using the atomic cluster expansion (ACE). To efficiently sample liquid water, we propose a novel approach that involves sampling static calculations of various ice…

Materials Science · Physics 2024-06-21 Eslam Ibrahim , Yury Lysogorskiy , Ralf Drautz
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