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In the paper we propose an universal bridge functional for the closure of the Ornstein-Zernike (OZ) equation for the case of infinitely diluted solutions of Lennard-Jones shperes of different size in the Lennard-Jones fluid. Bridge…

Statistical Mechanics · Physics 2011-11-10 Volodymyr P. Sergiievskyi , Andrey I. Frolov

A method to obtain (approximate) analytical expressions for the radial distribution functions in a multicomponent mixture of additive hard spheres that was recently introduced is used to obtain the direct correlation functions and bridge…

Statistical Mechanics · Physics 2008-09-15 S. B. Yuste , A. Santos , M. López de Haro

A key challenge for soft materials design and coarse-graining simulations is determining interaction potentials between components that give rise to desired condensed-phase structures. In theory, the Ornstein-Zernike equation provides an…

Soft Condensed Matter · Physics 2021-02-22 Rhys E. A. Goodall , Alpha A. Lee

We explore the feasibility of using machine learning methods to obtain an analytic form of the classical free energy functional for two model fluids, hard rods and Lennard--Jones, in one dimension . The Equation Learning Network proposed in…

Soft Condensed Matter · Physics 2020-01-15 Shang-Chun Lin , Georg Martius , Martin Oettel

The electron-electron pair distribution functions (PDF) of the 2-D electron fluid (2DEF) in the quantum regime (at T=0) are calculated using a classical-map-hyper-netted-chain (CHNC) scheme and compared with currently available Quantum…

Materials Science · Physics 2010-10-26 M. W. C. Dharma-wardana

We present methodologies for calculating the direct correlation function, c(1,2), the cavity function, y(1,2), and the bridge function, b(1,2), for molecular liquids, from Monte Carlo simulations. As an example we present results for the…

Soft Condensed Matter · Physics 2009-11-11 David L. Cheung , Lucian Anton , Michael P. Allen , Andrew J. Masters

We address the problem of predicting the solvation free energy and equilibrium solvent density profile in fews minutes from the molecular density functional theory beyond the usual hypernetted-chain approximation. We introduce a bridge…

Chemical Physics · Physics 2017-10-02 Cédric Gageat , Luc Belloni , Daniel Borgis , Maximilien Levesque

We have studied the structure and thermodynamic properties of isotropic three-dimensional core-softened fluid by using the second-order Ornstein-Zernike integral equations completed by the hypernetted chain and Percus-Yevick closures. The…

Soft Condensed Matter · Physics 2011-06-17 O. Pizio , Z. Sokolowska , S. Sokolowski

We use supervised machine learning together with the concepts of classical density functional theory to investigate the effects of interparticle attraction on the pair structure, thermodynamics, bulk liquid-gas coexistence, and associated…

Soft Condensed Matter · Physics 2025-01-29 Florian Sammüller , Matthias Schmidt , Robert Evans

In the paper a bridge functional for the closure relation of the three-dimensional reference interaction model (3DRISM) equations is proposed. The effectiveness of the bridge for the aqueous solutions of the carbon nanomaterials is tested.…

Statistical Mechanics · Physics 2011-12-06 Volodymyr P. Sergiievskyi

This paper introduces a novel deep learning based method, named bridge neural network (BNN) to dig the potential relationship between two given data sources task by task. The proposed approach employs two convolutional neural networks that…

Machine Learning · Computer Science 2019-06-27 Yao Xu , Xueshuang Xiang , Meiyu Huang

Existing identification results in proximal causal inference often focus on marginal interventional distributions using standard outcome or treatment bridge functions. These methods do not generally identify joint interventional…

Methodology · Statistics 2026-05-20 Constantin Schott

We investigate the orientational properties of a homogeneous and inhomogeneous tetrahedral 4-patch fluid (Kern--Frenkel model). Using integral equations, either (i) HNC or (ii) a modified HNC scheme with simulation input, the full…

Soft Condensed Matter · Physics 2025-01-07 Alessandro Simon , Luc Belloni , Daniel Borgis , Martin Oettel

We propose simple methods for multivariate diffusion bridge simulation, which plays a fundamental role in simulation-based likelihood and Bayesian inference for stochastic differential equations. By a novel application of classical coupling…

Statistics Theory · Mathematics 2014-06-02 Mogens Bladt , Samuel Finch , Michael Sørensen

Simulation of conditioned diffusion processes is an essential tool in inference for stochastic processes, data imputation, generative modelling, and geometric statistics. Whilst simulating diffusion bridge processes is already difficult on…

Probability · Mathematics 2024-04-24 Erlend Grong , Karen Habermann , Stefan Sommer

We apply the recently developed adaptive ensemble optimization technique to simulate dense Lennard-Jones fluids and a particle-solvent model by broad-histogram Monte Carlo techniques. Equilibration of the simulated fluid is improved by…

Statistical Mechanics · Physics 2007-05-23 Simon Trebst , Emanuel Gull , Matthias Troyer

The excess free energy functional of classical density functional theory depends upon the type of fluid model, specifically on the choice of (pair) potential, is unknown in general, and is approximated reliably only in special cases. We…

Soft Condensed Matter · Physics 2025-03-12 Stefanie M. Kampa , Florian Sammüller , Matthias Schmidt , Robert Evans

We propose a novel method for simulating conditioned diffusion processes (diffusion bridges) in Euclidean spaces. By training a neural network to approximate bridge dynamics, our approach eliminates the need for computationally intensive…

Machine Learning · Statistics 2025-06-23 Gefan Yang , Frank van der Meulen , Stefan Sommer

We study, using Monte Carlo simulations, the cavity and the bridge functions of various hard sphere fluids: one component system, equimolar additive and non additive binary mixtures. In particular, we numerically check the assumption of…

Statistical Mechanics · Physics 2007-05-23 R. Fantoni , G. Pastore

Determining the microstructure of colloidal suspensions under shear flows has been a challenge for theoretical and computational methods due to the singularly-perturbed boundary-layer nature of the problem. Previous approaches have been…

Soft Condensed Matter · Physics 2019-06-05 L. Banetta , A. Zaccone
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