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The presence of a non-optically active polymorph (yellow-phase) competing with the optically active polymorph (black $\gamma$-phase) at room temperature in CsSnI3 and the susceptibility of Sn to oxidation, represent two of the biggest…

The hybrid perovskite CH3NH3PbX3 (X= Cl, Br, I) is a promising material for developing novel optoelectronic devices. Owing to the intrinsic non-layer structure, it remains challenging to synthesize molecularly thin CH3NH3PbX3 with large…

Outstanding optoelectronic properties and a facile synthesis render halide perovskite nanocrystals (NCs) a promising material for nanostructure-based devices. However, the commercialization is hindered mainly by the lack of NC stability…

Mesoscale and Nanoscale Physics · Physics 2022-09-26 Michèle G. Greiner , Andreas Singldinger , Nina A. Henke , Carola Lampe , Ulrich Leo , Moritz Gramlich , Alexander S. Urban

In recent years, hybrid organic-inorganic metal halides have been at the forefront of materials research. Typically, the functional (e.g., optoelectronic) properties of hybrid halides are derived from the inorganic structural part, whereas…

All-inorganic halide perovskites have attracted a great interest as a promising light harvester of perovskite solar cells due to their enhanced chemical stability. In this work we investigate the material properties of solid solutions…

Materials Science · Physics 2020-04-22 Chol-Jun Yu , Un-Hyok Ko , Suk-Gyong Hwang , Yun-Sim Kim , Un-Gi Jong , Yun-Hyok Kye , Chol-Hyok Ri

We show that the decomposition of caesium lead halide perovskite nanocrystals under continuous X-ray illumination depends on the surface ligand. For oleic acid/oleylamine, we observe a fast decay accompanied by the formation of elemental…

The luminescent mechanism of nano-sized materials with indirect bandgap and parity-forbidden transition has always been a critical issue in breaking through bottlenecks in traditional luminescent materials. The lack of understanding has…

Materials Science · Physics 2024-04-30 Feilong Wang , Qiongrong Ou , Shuyu Zhang

Lead-halide perovskites attracted attention as materials for high-efficiency solar cells and light emitting applications. Among their attributes are solution processability, high absorbance in the visible spectral range and defect…

Materials Science · Physics 2018-11-14 Hee Taek Yi , Pavel Irkhin , Prakriti P. Joshi , Yuri N. Gartstein , Xiaoyang Zhu , Vitaly Podzorov

One effective way to prevent toxicity and improve the stability of materials for photovoltaic applications is to exclude lead and organic molecules from perovskite materials. Specifically, the CsSn1-xGexI3 appears to be a promising…

Metal halide perovskites are attracting tremendous interest for a variety of optoelectronic applications. The ability to tune the perovskite bandgap by tweaking the chemical compositions opens up new applications as coloured emitters and as…

$Lu_2S_3$ material from the family of sesquisulfide hosts appears to be a promising low-phonon material for use as a laser gain medium allowing for a laser emission over a broad spectral range from ultraviolet to far mid-infrared…

Hybrid perovskite thin films have demonstrated impressive performance for solar energy conversion and optoelectronic applications. However, further progress will benefit from a better knowledge of the intrinsic photophysics of materials.…

In the previous decade, there has been a significant advancement in the performance of perovskite solar cells (PSCs), characterized by a notable increase in efficiency from 3.8% to 25%. Nonetheless, PSCs face many problems when we…

Pb-based perovskites are considered to be the most efficient materials for energy harvest. However, real-time application is limited because of their toxicity. As a result, lead-free perovskites that offer similar advantages are potential…

Halide exchange in lead-based halide perovskites has been studied extensively. While mixed Cl-Br or Br-I alloy compositions can be formed with no miscibility gaps, this is precluded for mixed Cl-I compositions, due to the large difference…

The photoluminescence (PL), color purity, and stability of lead halide perovskite nanocrystals depend critically on the surface passivation. We present a study on the temperature dependent PL and PL decay dynamics of lead bromide perovskite…

Organic-inorganic metal halide perovskites have recently attracted increasing attention as highly efficient light harvesting materials for photovoltaic applications. However, the precise control of crystallization and morphology of…

Hybrid organic-inorganic halide perovskites have emerged as a disruptive new class of materials, exhibiting optimum properties for a broad range of optoelectronic applications, most notably for photovoltaics. The first report of highly…

Materials Science · Physics 2018-08-21 Marina R. Filip , George Volonakis , Feliciano Giustino

The realization of blue electroluminescence with high efficiency and lifetime remains a long-standing hurdle for OLED technology to overcome. Divalent Europium [Europium(II)] complexes offer a fundamentally distinct pathway toward this…

Inorganic lead halide perovskites are promising candidates for optoelectronic applications, due to their bandgap tunability, high photoluminescence quantum yield, and narrow emission line widths. In particular, they offer the possibility to…