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Disentangling the mechanistic details of a chemical reaction pathway is a hard problem that often requires a considerable amount of chemical intuition and a component of luck. Experiments struggle in observing short-life metastable…

Chemical Physics · Physics 2019-08-01 Valerio Rizzi , Dan Mendels , Emilia Sicilia , Michele Parrinello

The quantum normal form approach to quantum transition state theory is used to compute the cumulative reaction probability for collinear exchange reactions. It is shown that for heavy atom systems like the nitrogen exchange reaction the…

Chemical Physics · Physics 2010-03-17 Arseni Goussev , Roman Schubert , Holger Waalkens , Stephen Wiggins

A poorly understood step in the transition from a chemical to a biological world is the emergence of self-replicating molecular systems. We study how a precursor for such a replicator might arise in a hydrothermal RNA reactor, which…

Biomolecules · Quantitative Biology 2011-06-30 B. Obermayer , H. Krammer , D. Braun , U. Gerland

Conventional joint modeling approaches generally characterize the relationship between longitudinal biomarkers and discrete event occurrences within terminal, recurring or competing risk settings, thereby offering a limited representation…

Methodology · Statistics 2026-05-26 Félix Laplante , Christophe Ambroise

Based on the theory of stochastic chemical kinetics, the inherent randomness and stochasticity of biochemical reaction networks can be accurately described by discrete-state continuous-time Markov chains. The analysis of such processes is,…

Numerical Analysis · Mathematics 2014-10-14 Andreychenko Alexander , Mikeev Linar , Wolf Verena

Quantifying animal interactions is crucial for understanding various ecological processes, including social community structures, predator-prey dynamics, spreading of pathogens and information. Despite the ubiquity of interaction processes…

Statistical Mechanics · Physics 2023-10-06 Debraj Das , V. M. Kenkre , Ran Nathan , Luca Giuggioli

Pretrained language models (LMs) showcase significant capabilities in processing molecular text, while concurrently, message passing neural networks (MPNNs) demonstrate resilience and versatility in the domain of molecular science. Despite…

Machine Learning · Computer Science 2025-06-17 Jiaqing Xie , Ziheng Chi

The probabilistic description of the time evolution of a physical system can take two conceptually distinct forms: a trajectory of probabilities, which specifies how probabilities evolve over time, and a probability on trajectories, which…

Quantum Physics · Physics 2026-03-02 Győző Egri , Marton Gomori , Balazs Gyenis , Gábor Hofer-Szabó

Stochastic reaction network models are widely utilized in biology and chemistry to describe the probabilistic dynamics of biochemical systems in general, and gene interaction networks in particular. Most often, statistical analysis and…

Quantitative Methods · Quantitative Biology 2017-10-18 Eugenio Cinquemani

In this article, we carry out a study of long-term behavior of reaction-diffusion systems augmented with self- and cross-diffusion, using an augmented Gray-Scott system as a general example. The methodology remains generic, and is therefore…

Pattern Formation and Solitons · Physics 2023-08-16 Benjamin Aymard

Positional and relational perspectives on network data have led to two different research traditions in textual analysis and social network analysis, respectively. Latent Semantic Analysis (LSA) focuses on the latent dimensions in textual…

Computers and Society · Computer Science 2016-08-16 Loet Leydesdorff

Efficient information processing is crucial for both living organisms and engineered systems. The mutual information rate, a core concept of information theory, quantifies the amount of information shared between the trajectories of input…

Molecular Networks · Quantitative Biology 2025-09-01 Manuel Reinhardt , Age J. Tjalma , Anne-Lena Moor , Christoph Zechner , Pieter Rein ten Wolde

Stochastic modeling of transcription is a classic yet long-standing problem in theoretical biophysics. The lack of unified results and a computationally efficient approach for a general, fine-grained transcription model has confined…

Biological Physics · Physics 2025-11-17 Yuntao Lu , Yunxin Zhang

We developed an automated approach to construct the complex reaction network and explore the reaction mechanism for several reactant molecules. The nanoreactor type molecular dynamics was employed to generate possible chemical reactions, in…

Chemical Physics · Physics 2023-12-05 Yutai Zhang , Chao Xu , Zhenggang Lan

For a theoretical understanding of the reactivity of complex chemical systems, relative energies of stationary points on potential energy hypersurfaces need to be calculated to high accuracy. Due to the large number of intermediates present…

Chemical Physics · Physics 2018-10-30 Gregor N. Simm , Markus Reiher

A reliable estimation of the communication chan-nel which connects automated vehicles is an important steptowards the safety of connected and automated vehicles. The communication channel is usually modeled as Markov chain with slowly…

Signal Processing · Electrical Eng. & Systems 2019-11-25 Johannes Müller , Thomas Griebel , Michael Gabb , Michael Buchholz

Analyzing, understanding, and describing human behavior is advantageous in different settings, such as web browsing or traffic navigation. Understanding human behavior naturally helps to improve and optimize the underlying infrastructure or…

Machine Learning · Computer Science 2024-01-09 Tobias Koopmann , Jan Pfister , André Markus , Astrid Carolus , Carolin Wienrich , Andreas Hotho

"Leaping" methods show great promise for significantly accelerating stochastic simulations of complex biochemical reaction networks. However, few practical applications of leaping have appeared in the literature to date. Here, we address…

Subcellular Processes · Quantitative Biology 2009-07-06 Leonard A. Harris , Aaron M. Piccirilli , Emily R. Majusiak , Paulette Clancy

This paper presents a novel learning analytics method: Transition Network Analysis (TNA), a method that integrates Stochastic Process Mining and probabilistic graph representation to model, visualize, and identify transition patterns in the…

Social and Information Networks · Computer Science 2025-02-06 Mohammed Saqr , Sonsoles López-Pernas , Tiina Törmänen , Rogers Kaliisa , Kamila Misiejuk , Santtu Tikka

Continuous-time Markov chains are frequently used as stochastic models for chemical reaction networks, especially in the growing field of systems biology. A fundamental problem for these Stochastic Chemical Reaction Networks (SCRNs) is to…

Probability · Mathematics 2023-04-12 Felipe A. Campos , Simone Bruno , Yi Fu , Domitilla Del Vecchio , Ruth J. Williams