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To apply the Hubbard-corrected density-functional theory for predicting some known materials' properties, the Hubbard parameters are usually so tuned that the calculations give results in agreement with some experimental data and then one…

Materials Science · Physics 2023-06-13 Mahmoud Payami , Samira Sheykhi , Mohammad-Reza Basaadat

The existence of band gaps in Mott insulators such as perovskite oxides with partially filled 3d shells has been traditionally explained in terms of strong, dynamic inter-electronic repulsion codified by the on-site repulsion energy U in…

Materials Science · Physics 2019-07-24 Julien Varignon , Manuel Bibes , Alex Zunger

DFT+U provides a convenient, cost-effective correction for the self-interaction error (SIE) that arises when describing correlated electronic states using conventional approximate density functional theory (DFT). The success of a DFT+U(+J)…

Density-functional theory with on-site $U$ and inter-site $V$ Hubbard corrections (DFT+$U$+$V$) is a powerful and accurate method for predicting various properties of transition-metal compounds. However, its accuracy depends critically on…

Materials Science · Physics 2025-12-23 Wooil Yang , Iurii Timrov , Francesco Aquilante , Young-Woo Son

A self-consistent calculation scheme for correlated electron systems is created based on the density-functional theory (DFT). Our scheme is a multi-reference DFT (MR-DFT) calculation in which the electron charge density is reproduced by an…

Strongly Correlated Electrons · Physics 2009-11-13 Koichi Kusakabe , Naoshi Suzuki , Shusuke Yamanaka , Kizashi Yamaguchi

We develop a generalization of the Kohn-Sham density functional theory (KS-DFT) + Hubbard $U$ (DFT+$U$) method to the excited-state regime. This has the form of Hubbard $U$ corrected linear-response time-dependent DFT, or `TDDFT+$U$'.…

Strongly Correlated Electrons · Physics 2019-04-24 Okan K. Orhan , David D. O'Regan

In approximate density functional theory (DFT), the self-interaction error is an electron delocalization anomaly associated with underestimated insulating gaps. It exhibits a predominantly quadratic energy-density curve that is amenable to…

Chemical Physics · Physics 2016-12-21 Glenn Moynihan , Gilberto Teobaldi , David D. O'Regan

The density functional theory (DFT)+$U$ method is a pragmatic and effective approach for calculating the ground-state properties of strongly-correlated systems, and linear response calculations are widely used to determine the requisite…

Strongly Correlated Electrons · Physics 2018-12-31 Edward B. Linscott , Daniel J. Cole , Michael C. Payne , David D. O'Regan

Typical density-functional theory calculations that wrongly predict undoped cuprates to be metallic also predict Cu-O half- and full-breathing phonon energies that are significantly softer than observed, presumably because of weak on-site…

Strongly Correlated Electrons · Physics 2021-11-03 Tyler C. Sterling , Dmitry Reznik

Titanium dioxide (TiO$_2$) presents a long-standing challenge for approximate Kohn-Sham density-functional theory (KS-DFT), as well as to its Hubbard-corrected extension, DFT+$U$. We find that a previously proposed extension of…

Materials Science · Physics 2020-06-23 Okan K. Orhan , David D. O'Regan

The electronic structure and magnetic properties of the strongly correlated material La$_2$O$_3$Fe$_2$Se$_2$ are studied by using both the density function theory plus $U$ (DFT+$U$) method and the DFT plus Gutzwiller (DFT+G) variational…

Materials Science · Physics 2016-09-07 Guangxi Jin , Yilin Wang , Xi Dai , Xinguo Ren , Lixin He

Streamlined prediction of the electronic properties of photoactive materials warrants a Density Functional Theory (DFT) based approach that (i) yields reliable bandgaps, (ii) is free of empirically tuned parameters, and (iii) exhibits low…

Materials Science · Physics 2025-12-17 Andrew C. Burgess , Lórien MacEnulty , Ethan D'Arcy , David Gavin , David D. O'Regan

First principles density functional theory (DFT) is used to investigate the electronic structure of \beta-MnO2. From collinear spin polarized calculations we find that DFT+U_Eff predicts a gapless ferromagnet in contrast with experiment…

Strongly Correlated Electrons · Physics 2012-11-26 David A. Tompsett , Derek S. Middlemiss , M. Saiful Islam

Spectral distribution functions of electron-phonon interaction $\alpha^2F(\omega )$ obtained by ab initio linear--response calculations are used to describe various superconducting and transport properties in a number of elemental metals…

Condensed Matter · Physics 2009-10-28 S. Y. Savrasov , D. Y. Savrasov

In the density-functional studies of materials with localized electronic states, the local/semilocal exchange-correlation functionals are often either combined with a Hubbard parameter $U$ as in the LDA+$U$ method or mixed with a fraction…

Materials Science · Physics 2014-07-24 Mehmet Aras , Çetin Kılıç

While methods based on density-functional perturbation theory have dramatically improved our understanding of electron-phonon contributions to transport in materials, methods for accurately capturing electron-electron scattering relevant to…

Rare-earth trihydrides ($R$H$_3$) exhibit intriguing coupled electronic and structural properties as a function of doping, hydrogen vacancies, and thermodynamic conditions. Theoretical studies of these materials typically rely on density…

Strongly Correlated Electrons · Physics 2024-10-07 Adam Denchfield , Hyeondeok Shin , Panchapakesan Ganesh , Russell J Hemley , Hyowon Park

We study the lattice dynamics of antiferromagnetic transition-metal oxides by using self-consistent Hubbard functionals. We calculate the ground states of the oxides with the on-site and intersite Hubbard interactions determined…

Strongly Correlated Electrons · Physics 2022-06-01 Wooil Yang , Bo Gyu Jang , Young-Woo Son , Seung-Hoon Jhi

We perform investigation of Hubbard model with interaction between strongly correlated conducting electrons on a lattice with Debye phonons. To solve the problem generalized dynamical mean-field DMFT+\Sigma method is employed with…

Strongly Correlated Electrons · Physics 2009-10-02 E. Z. Kuchinskii , I. A. Nekrasov , M. V. Sadovskii

The simultaneous influence of electronic correlations and magnetic ordering on the theoretical estimation of phonons and related properties of Ni is investigated. The work includes a comparative DFT and DFT+U study, where on-site Coulomb…

Strongly Correlated Electrons · Physics 2023-07-13 Shivani Bhardwaj , Sudhir K. Pandey