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Endothermic singlet fission (SF), an exciton multiplication process that produces a pair of high-energy triplet excitons (T1T1), is appealing for photovoltaic or photoelectrochemical applications, as it allows the conversion of entropy into…

Hybrid perovskite thin films have demonstrated impressive performance for solar energy conversion and optoelectronic applications. However, further progress will benefit from a better knowledge of the intrinsic photophysics of materials.…

F\"orster Resonant Energy Transfer (FRET)-mediated exciton diffusion through artificial nanoscale building block assemblies could be used as a new optoelectronic design element to transport energy. However, so far nanocrystal (NC) systems…

Ultrafast scintillators are indispensable for precise timing in high-energy physics and medical diagnostics. Fundamentally constrained by the trade-off between emission rate and light yield, conventional scintillators remain kinetically…

In photovoltaics (PVs) and artificial photosynthetic systems based on excitons, the question of how energy must be lost in overcoming the Coulomb barrier, converting excitons to free charges, is fundamental, as it determines the achievable…

Mesoscale and Nanoscale Physics · Physics 2017-04-13 Maxim Tabachnyk , Samuel L. Smith , Leah R. Weiss , Aditya Sadhanala , Alex W. Chin , Richard H. Friend , Akshay Rao

There is a resurgence of interest in the electronic structure of perylene for its applications in molecular devices such as organic photovoltaics and organic light emitting diodes. In this study, we have obtained the low-lying singlet…

Strongly Correlated Electrons · Physics 2018-11-21 Geetanjali Giri , Suryoday Prodhan , Y. Anusooya Pati , S. Ramasesha

Perovskite solar cells employing self assembled monolayers such as Me-4PACz as hole transport layer has been reported to demonstrate high device efficiency. However, the poor perovskite wetting on the Me-4PACz caused by poor perovskite ink…

We report an ultra long range energy transfer in a layered donor:spacer:acceptor structures, which consist of the typical organic photovoltaic material system of P3HT as the donor and PCBM as the acceptor. By varying the thicknesses of…

Applied Physics · Physics 2021-04-29 Eran Avnon , Ariel Epstein , Olga Solomeshch , Nir Tessler

Understanding and controlling exciton transport is a strategic way to enhance the optoelectronic properties of high-performance organic devices. In this article we study triplet exciton migration in crystalline poly($p$-phenylene vinylene)…

Materials Science · Physics 2019-11-13 Igor Lyskov , Egor Trushin , Ben Q. Baragiola , Timothy W. Schmidt , Jared H. Cole , Salvy P. Russo

Chiral perovskites are emerging semiconducting materials with broken symmetry that can selectively absorb and emit circularly polarized light. However, most of the chiral perovskites are typically low-dimensional structures with limited…

We studied the dynamics of transfer of photoexcited electronic states in a bilayer of the two-dimensional transition metal dichalcogenide ReS$_2$ and tetracene, with the aim to produce triplets in the latter. This material combination was…

Ion and metal diffusion in metal halide perovskites, charge-transporting layers, and electrodes are detrimental to the performance and stability of perovskite-based photovoltaic devices. As a result, there is an intense research interest in…

The power conversion efficiency of photovoltaic devices based on semiconductor perovskites has reached ~20% after just several years of research efforts. With concomitant discoveries of other promising applications in lasers, light-emitting…

In semiconductors, exciton or charge carrier diffusivity is typically described as an inherent material property. Here, we show that the transport of excitons (i.e., bound electron-hole pairs) in CsPbBr3 perovskite nanocrystals (NCs)…

Efficient semi-transparent solar cells can trigger the adoption of building integrated photovoltaics. Halide perovskites are particularly suitable in this respect owing to their tunable bandgap. Main drawbacks in the development of…

Transport of elementary excitations is a fundamental property of 2D semiconductors, important for wide-ranging emergent phenomena and device applications. While exciton transport reported in 2D materials barely exceeds 1-2 $\mu$m, coherent…

Optics · Physics 2025-06-03 Xin Xie , Qiuyang Li , Chenxi Liu , Yuze Liu , Chulwon Lee , Kai Sun , Hui Deng

Two-dimensional (2D) halide perovskites (HPs) are promising materials for various optoelectronic applications, yet a comprehensive understanding of their dynamics is still elusive. Here, we offer insight into the dynamics of prototypical 2D…

Materials Science · Physics 2024-08-15 Erik Fransson , Julia Wiktor , Paul Erhart

Singlet fission is a process whereby two triplet excitons can be produced from one photon, potentially increasing the efficiency of photovoltaic devices. Endothermic singlet fission is desired for maximum energy conversion efficiency, and…

Nanostructured semiconductors emit light from electronic states known as excitons[1]. According to Hund's rules[2], the lowest energy exciton in organic materials should be a poorly emitting triplet state. Analogously, the lowest exciton…

Lead halide perovskite quantum dots (QDs), the latest generation of colloidal QD family, exhibit outstanding optical properties which are now exploited as both classical and quantum light sources. Most of their rather exceptional properties…