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The Rouse model has recently been modified to take into account the excluded volume interactions that exist between various parts of a polymer chain by incorporating a narrow Gaussian repulsive potential between pairs of beads on the Rouse…

Soft Condensed Matter · Physics 2020-07-03 J Ravi Prakash

We propose a path for making quantitative analyses of mean-square displacement curves of polymer chains in the melt or in solution. The approach invokes a general functional form that accurately describes $g(t) \equiv \langle (\Delta…

Soft Condensed Matter · Physics 2025-02-19 George D. J. Phillies

The reptation concept in polymer dynamics is studied for model chains with added stiffness. The main idea of a chain diffusing inside a tube can be transferred from fully flexible chains. However, the picture, which renormalizes the chain…

Soft Condensed Matter · Physics 2007-05-23 Roland Faller , Florian Mueller-Plathe

A simple analytic expression for the first cumulant of the dynamic structure factor of a polymer coil in the Rouse model is derived. The obtained formula is exact within the usual assumption of the continuum distribution of beads along the…

Soft Condensed Matter · Physics 2007-09-27 V. Lisy , B. Brutovsky , J. Tothova

Active polymers play a central role in many biological systems, from bacterial flagella to cellular cytoskeletons. Minimal models of semiflexible active filaments have been used to study a variety of interesting phenomena in active systems,…

Soft Condensed Matter · Physics 2020-02-19 Matthew S. E. Peterson , Michael F. Hagan , Aparna Baskaran

Using the pruned-enriched Rosenbluth Monte Carlo algorithm, the scattering functions of semiflexible macromolecules in dilute solution under good solvent conditions are estimated both in $d=2$ and $d=3$ dimensions, considering also the…

Soft Condensed Matter · Physics 2015-06-11 Hsiao-Ping Hsu , Wolfgang Paul , Kurt Binder

The rheological behavior of ring-linear polymer blends under uniaxial elongational flow has remained a subject of intense debate, particularly regarding the emergence of stress overshoot. Herein, we employ coarse-grained molecular dynamics…

Soft Condensed Matter · Physics 2026-03-27 Takahiro Murashima , Katsumi Hagita , Toshihiro Kawakatsu

Bures distance holds a special place among various distance measures due to its several distinguished features and finds applications in diverse problems in quantum information theory. It is related to fidelity and, among other things, it…

Quantum Physics · Physics 2022-11-21 Aritra Laha , Agrim Aggarwal , Santosh Kumar

We present exact spatio-temporal correlation functions of a Rouse polymer chain submerged in a fluid having planar mixed flow, in the steady state. Using these correlators, determination of the time scale distribution functions associated…

Statistical Mechanics · Physics 2011-09-06 Dipjyoti Das , Sanjib Sabhapandit , Dibyendu Das

The freely rotating chain is one of the classic discrete models of a polymer in dilute solution. It consists of a broken line of N straight segments of fixed length such that the angle between adjacent segments is constant and the N-1…

Probability · Mathematics 2017-11-15 Philip Kilanowski , Peter March , Marko Samara

It is shown that the traditionally accepted "Rouse values" for the critical exponents at the gelation transition do not arise from the Rouse model for gelling polymers. The true critical behaviour of the Rouse model for gelling polymers is…

Statistical Mechanics · Physics 2007-05-23 Peter Müller

The growing importance of microfluidic and nanofluidic devices to the study of biological processes has highlighted the need to better understand how confinement affects the behavior of polymers in flow. In this paper we explore one aspect…

Soft Condensed Matter · Physics 2015-06-05 Pinaki Bhattacharyya , Binny J. Cherayil

We revisit a model of semiflexible Gaussian chains proposed by Winkler \textit{et al}, solve the dynamics of the discrete description of the model and derive exact algebraic expressions for some of the most relevant dynamical observables,…

Soft Condensed Matter · Physics 2022-11-02 Andres R. Tejedor , Jaime R. Tejedor , Jorge Ramirez

Contrary to some expectations, an experimental finding for a polymer that the solution intrinsic viscosity $[\eta]$ or the melt viscosity is linear in the polymer molecular weight $M$ does not indicate that polymer dynamics are Rouselike.…

Soft Condensed Matter · Physics 2021-05-03 George D. J. Phillies

We study the mechanical properties of semiflexible polymers when the contour length of the polymer is comparable to its persistence length. We compute the exact average end-to-end distance and shape of the polymer for different boundary…

Biomolecules · Quantitative Biology 2013-05-29 Yuko Hori , Ashok Prasad , Jane' Kondev

We study the segmental dynamics of poly(ethylene oxide) (PEO) from microscopic simulations in the neat polymer and a polymer electrolyte (PEO/LiBF$_4$) by analyzing the normal modes. We verify the applicability of the Rouse theory,…

Soft Condensed Matter · Physics 2008-04-15 Arijit Maitra , Andreas Heuer

We present Monte Carlo simulations of semidilute solutions of long self-attracting chain polymers near their Ising type critical point. The polymers are modeled as monodisperse self-avoiding walks on the simple cubic lattice with attraction…

Soft Condensed Matter · Physics 2009-10-30 H. Frauenkron , P. Grassberger , HLRZ Juelich , Germany

This study focuses on comparing the individual polymer chain dynamics in an entangled polymeric liquid under different shear and extension rates. Polymer chains under various shear rates and extension rates were simulated using a…

Chemical Physics · Physics 2021-01-15 Behrouz Behdani , Tong Mou , Cody Spratt , Slava Butcovich , Ryan Gettler , Joontaek Park

We present a numerical solution of the Worm-Like Chain (WLC) model for semi-flexible polymers. We display graphs for the end-to-end distance distribution and the force-extension relation expected from the model. We predict the expected…

Soft Condensed Matter · Physics 2009-11-07 Joseph Samuel , Supurna Sinha

Self-avoiding polymers in strictly two-dimensional ($d=2$) melts are investigated by means of molecular dynamics simulation of a standard bead-spring model with chain lengths ranging up to N=2048. % The chains adopt compact configurations…

Soft Condensed Matter · Physics 2015-05-18 H. Meyer , J. P. Wittmer , T. Kreer , A. Johner , J. Baschnagel
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